基本描述

别名	(S)-联萘酚磷酸酯 \| (S)-(+)-1,1'-联萘基-2,2'-双磷酸氢酯 \| (S)-(+)-2,2'-二羟基-1,1'-联萘磷酸酯 \| (S)-4-羟基二萘并2,1-d:1',2'-f1,3,2二噁磷杂庚英-4-氧化物
英文别名	(R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, >=98% \| (S)-(+)-2,2'-Dihydroxy-1,1'-binaphthyl Hydrogen Phosphate \| Dinaphtho[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-ol 4-oxide # \| FT-0604445 \| J-019988 \| AC-26903 \| B1144 \| EINECS 252-425-8 \| AC7768 \| (
规格或纯度	≥97%
英文名称	(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate
运输条件	常规运输
产品介绍	在异构体选择性的mannich反应中，用作手性bronsted酸催化剂。 Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction

AI解读

名称和识别符

分子类型	小分子
IUPAC Name	13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
INCHI	InChI=1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChi Key	JEHUZVBIUCAMRZ-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C2C(=C1)C=CC3=C2C4=C(C=CC5=CC=CC=C54)OP(=O)(O3)O
Isomeric SMILES	C1=CC=C2C(=C1)C=CC3=C2C4=C(C=CC5=CC=CC=C54)OP(=O)(O3)O
WGK Germany	3
PubChem CID	99589
分子量	348.29
Beilstein号	4787775
Reaxy-Rn	2014273

化学和物理性质

溶解性	Soluble in DMSO and methanol (hot).
密度	1.49
比旋光度	595 ° (C=1, MeOH)
分子量	348.300 g/mol
XLogP3	4.800
氢键供体数Hydrogen Bond Donor Count	1
氢键受体数Hydrogen Bond Acceptor Count	4
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	348.055 Da
单同位素质量Monoisotopic Mass	348.055 Da
拓扑极表面积Topological Polar Surface Area	55.800 Å²
重原子数Heavy Atom Count	25
形式电荷Formal Charge	0
复杂度Complexity	508.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
Reaxy-Rn	2014273
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

技术规格说明书

Specific Rotation [a]20/D(c=1 in MeOH)	580-605（°）
Purity(HPLC)	97-100（%）
Purity (Titration by NaOH)	96.5-103.5（%）
Appearance（B117618)	Solid particle or powder
Infrared spectrum	Conforms to Structure
Solubility in Pyridine，Colorless to Faint Yellow,Clear to Slightly Hazy5%	pass

技术规格说明书

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找到13个结果

批号(Lot Number)	证书类型	日期	货号
E1314085	分析证书	24-08-13	B117618
G2426614	分析证书	24-06-24	B117618
G2426615	分析证书	24-06-24	B117618
G2426616	分析证书	24-06-24	B117618
G2426617	分析证书	24-06-24	B117618
I2410053	分析证书	24-06-12	B117618
K1520094	分析证书	23-09-11	B117618
I2113060	分析证书	23-06-16	B117618
I2113062	分析证书	23-06-16	B117618
I2113061	分析证书	23-06-16	B117618
D2403033	分析证书	22-07-19	B117618
I2207314	分析证书	22-07-19	B117618
I2207315	分析证书	22-07-19	B117618

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此产品的引用文献

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1. Xu Xu, Chaonan Jiao, Hao Yang, Hao Chen, Jing Wang. (2022) Oxidation of sodium cholate catalyzed by Au NPs and chiral selective binding of R- and S-binaphthyl derivatives. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 648 (129209). [10.1016/j.colsurfa.2022.129209]

参考文献

1. Y Mechref,Z El Rassi. (1997-06-01) Comparison of alkylglycoside surfactants in enantioseparation by capillary electrophoresis.. Electrophoresis, 18 ((6)): (912-918). [PMID:9221877]
2. M E McCarroll,F H Billiot,I M Warner. (2001-07-18) Fluorescence anisotropy as a measure of chiral recognition.. Journal of the American Chemical Society, 123 ((13)): (3173-3174). [PMID:11457044]
3. Tom M H Choy,Wing-Hong Chan,Albert W M Lee,Carmen W Huie. (2003-10-01) Stacking and separation of enantiomers by acetonitrile-salt mixtures in micellar electrokinetic chromatography.. Electrophoresis, 24 ((18)): (3116-3123). [PMID:14518033]
4. Ulrich Schmitt,Mevlut Ertan,Ulrike Holzgrabe. (2004-09-08) Chiral capillary electrophoresis: facts and fiction on the reproducibility of resolution with randomly substituted cyclodextrins.. Electrophoresis, 25 ((16)): (2801-2807). [PMID:15352012]
5. Kevin F Morris,Bridget A Becker,Bertha C Valle,Isiah M Warner,Cynthia K Larive. (2006-09-01) Use of NMR binding interaction mapping techniques to examine interactions of chiral molecules with molecular micelles.. The journal of physical chemistry. B, 110 ((35)): (17359-17369). [PMID:16942071]
6. Dorothee Wistuba,Anja Bogdanski,Kim L Larsen,Volker Schurig. (2006-10-06) Delta-cyclodextrin as novel chiral probe for enantiomeric separation by electromigration methods.. Electrophoresis, 27 ((21)): (4359-4363). [PMID:17022018]
7. Alicia A Williams,Sayo O Fakayode,Xiaodong Huang,Isiah M Warner. (2006-11-01) Use of multivariate analysis for optimization of separation parameters and prediction of migration time, resolution, and resolution per unit time in micellar electrokinetic chromatography.. Electrophoresis, 27 ((21)): (4127-4140). [PMID:17075942]
8. Masahiro Yamanaka,Junji Itoh,Kohei Fuchibe,Takahiko Akiyama. (2007-05-05) Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.. Journal of the American Chemical Society, 129 ((21)): (6756-6764). [PMID:17477527]
9. Simon M Mwongela,Noreen Siminialayi,Kristin A Fletcher,Isiah M Warner. (2007-07-12) A comparison of ionic liquids to molecular organic solvents as additives for chiral separations in micellar electrokinetic chromatography.. Journal of separation science, 30 ((9)): (1334-1342). [PMID:17623476]
10. Eugene Billiot,Fereshteh Billiot,Isiah M Warner. (2008-11-15) Optimization of 12 chiral analytes with 8 polymeric surfactants.. Journal of chromatographic science, 46 ((9)): (757-763). [PMID:19007474]
11. Jun He,Shahab A Shamsi. (2008-12-27) Multivariate approach for the enantioselective analysis in micellar electrokinetic chromatography-mass spectrometry. I. Simultaneous optimization of binaphthyl derivatives in negative ion mode.. Journal of chromatography. A, 1216 ((5)): (845-856). [PMID:19110258]
12. Ke Shen,Xiaohua Liu,Yunfei Cai,Lili Lin,Xiaoming Feng. (2009-05-07) Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate.. Chemistry (Weinheim an der Bergstrasse, Germany), 15 ((24)): (6008-6014). [PMID:19418513]
13. Stephanie A Kingsbury,Curtis J Ducommun,Bryan M Zahakaylo,Elizabeth H Dickinson,Kevin F Morris. (2010-01-06) NMR characterization of 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate binding to chiral molecular micelles.. Magnetic resonance in chemistry : MRC, 48 ((3)): (184-191). [PMID:20049749]
14. Yingying Dong,Linda B McGown. (2011-06-28) Chiral selectivity of guanosine media in capillary electrophoresis.. Electrophoresis, 32 ((13)): (1735-1741). [PMID:21706497]
15. Ioannis J Stavrou,Constantina P Kapnissi-Christodoulou. (2012-12-05) Use of chiral amino acid ester-based ionic liquids as chiral selectors in CE.. Electrophoresis, 34 ((4)): (524-530). [PMID:23208781]
16. B Chankvetadze,M Saito,E Yashima,Y Okamoto. (1997-06-27) Enantioseparation using selected polysaccharides as chiral buffer additives in capillary electrophoresis.. Journal of chromatography. A, 773 ((1-2)): (331-338). [PMID:9228803]
17. Xu Xu, Chaonan Jiao, Hao Yang, Hao Chen, Jing Wang. (2022) Oxidation of sodium cholate catalyzed by Au NPs and chiral selective binding of R- and S-binaphthyl derivatives. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 648 (129209). [10.1016/j.colsurfa.2022.129209]

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货号 (SKU)	包装规格	是否现货
B117618-250mg	250mg	现货
B117618-1g	1g	现货
B117618-5g	5g	期货
B117618-25g	25g	现货
B117618-100g	100g	期货

(S)-(+)-联萘酚磷酸酯

库存信息

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基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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相关文档

此产品的引用文献

参考文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器

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