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2,5-二甲基苯胺

规格或纯度: 97%
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货号 (SKU) 包装规格 是否现货 价格 数量
D106348-25ml
 25ml 现货 Stock Image
D106348-100ml
 100ml 现货 Stock Image
D106348-500ml
 500ml 现货 Stock Image
D106348-2.5L
 2.5L 现货 Stock Image
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含氮化合物 非杂环砌块
main product photo

基本描述

别名 2,5-二甲苯胺|对二甲苯胺|2-氨基对二甲苯|2-氨基-1,4-二甲苯
英文别名 2,5-Dimethylaniline|95-78-3|2,5-XYLIDINE|p-Xylidine|1-Amino-2,5-dimethylbenzene|2,5-Dimethylbenzenamine|2,5-Dimethylphenylamine|2-Amino-1,4-xylene|Benzenamine, 2,5-dimethyl-|5-Methyl-o-toluidine|6-Methyl-m-toluidine|2,5-Xylidene|p-Dimethylaniline|2-Amino-
规格或纯度 97%
英文名称 2,5-Dimethylaniline
应用 It was used in the synthesis of nanocomposite of multi-walled carbon nanotubes embedded in poly(2,5-dimethylaniline). 2,5-Dimethylaniline was used to study the effect of metabolites formed from 2,5-xylidine by fungi on laccase activity.
储存温度 充氩
运输条件 常规运输
产品介绍

It is a colorless to dark yellow and colorless to brown liquid. It is a substrate for fungal laccases. 2,5-Dimethylaniline undergoes electrochemical oxidation in anhydrous NH4F·2.35 HF medium to form conducting polymer, poly(2,5-dimethylaniline). Poly(2,5-dimethylaniline) coating on copper substrate protects the Cu against corrosion. The Fourier transform infrared (FTIR) and Raman spectra of 2,5-dimethylaniline was studied. It induced transcription of lccIV.


产品介绍：

2,5-二甲基苯胺是一种无色至暗黄色、无色至棕色的液体。它是真菌漆酶的底物。2,5-二甲基苯胺可在无水NH4F·2.35 HF介质中进行电化学氧化，形成导电聚合物，聚（2,5-二甲基苯胺）。铜基材上的聚（2,5-二甲基苯胺）涂层可保护铜免受腐蚀。2,5-二甲基苯胺的傅里叶变换红外光谱（FTIR）和拉曼光谱已有研究。它可诱导lccIV的转录。

 

应用：

2,5-二甲基苯胺可用于合成嵌入聚（2,5-二甲基苯胺）中的多壁碳纳米管的纳米复合材料。 2,5-二甲基苯胺可用于研究真菌通过2,5-二甲苯胺形成的代谢产物对漆酶活性的影响。

It is a colorless to dark yellow and colorless to brown liquid. It is a substrate for fungal laccases. 2,5-Dimethylaniline undergoes electrochemical oxidation in anhydrous NH4F·2.35 HF medium to form conducting polymer, poly(2,5-dimethylaniline). Poly(2,5-dimethylaniline) coating on copper substrate protects the Cu against corrosion. The Fourier transform infrared (FTIR) and Raman spectra of 2,5-dimethylaniline was studied. It induced transcription of lccIV.
It was used in the synthesis of nanocomposite of multi-walled carbon nanotubes embedded in poly(2,5-dimethylaniline). 2,5-Dimethylaniline was used to study the effect of metabolites formed from 2,5-xylidine by fungi on laccase activity.

名称和标识符

PubChem SID 488180360
EC号 202-451-0
IUPAC Name 2,5-dimethylaniline
INCHI InChI=1S/C8H11N/c1-6-3-4-7(2)8(9)5-6/h3-5H,9H2,1-2H3
InChi Key VOWZNBNDMFLQGM-UHFFFAOYSA-N
Canonical SMILES CC1=CC(=C(C=C1)C)N
Isomeric SMILES CC1=CC(=C(C=C1)C)N
WGK Germany 3
RTECS ZE9100000
PubChem CID 7259
UN Number 1711
Packing Group II
分子量 121.18
Beilstein号 2205178
Reaxy-Rn 2205178

化学和物理性质

溶解性 Soluble in water <0.1 g/100 mL at 18°C.
密度 0.977
敏感性 空气及光线敏感
折光率 1.559
闪点(℉) 204.8 °F
闪点(℃) 96°C
沸点 218°C
熔点 11.5°C

安全和危险性（GHS）

一般危化品 一般危化品
象形图
ghs06

Toxic

ghs08

Health Hazard

ghs09

Environmental Hazard
信号词 Danger
危险声明 H301: Toxic if swallowed
H311: Toxic in contact with skin
H331: Toxic if inhaled
H373: Causes damage to organs through prolonged or repeated exposure
H411: Toxic to aquatic life with long lasting effects
预防措施声明 P261,P273,P280,P302+P352,P321,P405,P501,P264,P260,P271,P270,P304+P340,P403+P233,P391,P330,P361+P364,P301+P316,P316,P319
WGK Germany 3
RTECS ZE9100000
Reaxy-Rn 2205178
Class 6.1
Merck Index 10084
个人防护装备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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参考文献

1. Thomas Bertrand,Claude Jolivalt,Pierre Briozzo,Eliane Caminade,Nathalie Joly,Catherine Madzak,Christian Mougin.  (2002-06-05)  Crystal structure of a four-copper laccase complexed with an arylamine: insights into substrate recognition and correlation with kinetics..  Biochemistry,  41  ((23)):  (7325-7333).  [PMID:12044164]
2. C Madzak,M C Mimmi,E Caminade,A Brault,S Baumberger,P Briozzo,C Mougin,C Jolivalt.  (2005-12-22)  Shifting the optimal pH of activity for a laccase from the fungus Trametes versicolor by structure-based mutagenesis..  Protein engineering, design & selection : PEDS,  19  ((2)):  (77-84).  [PMID:16368720]
3. Robert J Strife,Michele L Mangels,Julie A Skare.  (2009-09-08)  Separation and analysis of dimethylaniline isomers by supercritical fluid chromatography--electrospray ionization tandem mass spectrometry..  Journal of chromatography. A,  1216  ((41)):  (6970-6973).  [PMID:19733358]
4. Maria Teresa Cambria,Daniele Di Marino,Mattia Falconi,Silvia Garavaglia,Antonio Cambria.  (2009-11-18)  Docking simulation and competitive experiments validate the interaction between the 2,5-xylidine inhibitor and Rigidoporus lignosus laccase..  Journal of biomolecular structure & dynamics,  27  ((4)):  (501-510).  [PMID:19916571]
5. Akito Takeuchi,Shinobu Yamamoto,Warren Hendricks,Yasuki Nishimura,Tsutoshi Imanaka,Yuichiro Kaifuku,Norihiro Sakui,Shuichiro Natsumeda,Hirokazu Ota,Shu Yamada,Ichiro Kurotani,Kimiaki Sumino,Seiichiro Kanno.  (2011-03-23)  Determination method for xylidines in workplace air..  Journal of occupational health,  53  ((3)):  (230-233).  [PMID:21422722]
6. Jai Kishan Ojha,B Venkatram Reddy,G Ramana Rao.  (2012-08-08)  Vibrational analysis and valence force field for nitrotoluenes, dimethylanilines and some substituted methylbenzenes..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  96  ():  (632-643).  [PMID:22868336]
7. Soumya Mukherjee, Zhixin Zeng, Mandar M Shirolkar, Partha Samanta, Abhijeet K Chaudhari, Jin-Chong Tan, Sujit K Ghosh,.  (2018-05-29)  Self-Assembled, Fluorine-Rich Porous Organic Polymers: A Class of Mechanically Stiff and Hydrophobic Materials..  Chemistry (Weinheim an der Bergstrasse, Germany),  24  ((45)):  ( 11771-11778 ).  [PMID:29808943]
8. E Ong,W B Pollock,M Smith.  (1997-10-10)  Cloning and sequence analysis of two laccase complementary DNAs from the ligninolytic basidiomycete Trametes versicolor..  Gene,  196  ((1-2)):  (113-119).  [PMID:9322748]
9. Albert Kollmann,François-Didier Boyer,Paul-Henri Ducrot,Lucien Kerhoas,Claude Jolivalt,Isabelle Touton,Jacques Einhorn,Christian Mougin.  (2005-01-14)  Oligomeric compounds formed from 2,5-xylidine (2,5-dimethylaniline) are potent enhancers of laccase production in Trametes versicolor ATCC 32745..  Applied microbiology and biotechnology,  68  ((2)):  (251-258).  [PMID:15647931]
10. Luane Ferreira Garcia,Ana Claudia Rodrigues Siqueira,Germán Sanz Lobón,Jossano Saldanha Marcuzzo,Benevides Costa Pessela,Eduardo Mendez,Telma Alves Garcia,Eric de Souza Gil.  (2017-08-16)  Bio-electro oxidation of indigo carmine by using microporous activated carbon fiber felt as anode and bioreactor support..  Chemosphere,  186  ():  (519-526).  [PMID:28810222]
11. Meng-Hsuan Wu,Cheng-Chung Lee,An-Shan Hsiao,Su-May Yu,Andrew H-J Wang,Tuan-Hua David Ho.  (2018-08-09)  Kinetic analysis and structural studies of a high-efficiency laccase from Cerrena sp. RSD1..  FEBS open bio,  8  ((8)):  (1230-1246).  [PMID:30087829]
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