二乙基锌

14篇引用文献

1.0 M in Hexane

CAS编号: 557-20-0
分子式: C₄H₁₀Zn
分子量: 123.51
Beilstein号: 3587207
EC号: 209-161-3
MDL号: MFCD00009021
PubChem编号: 11185

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货号 (SKU)	包装规格	是否现货
D107431-25ml	25ml	现货
D107431-100ml	100ml	现货
D107431-500ml	500ml	现货
D107431-1L	1L	期货

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基本描述

英文别名	AC-1790 \| EINECS 209-161-3 \| (C2H5)2Zn \| DTXSID4052217 \| MFCD00009021 \| HQWPLXHWEZZGKY-UHFFFAOYSA-N \| Zinkdiethyl \| Diethylzinc, purum, >=95.0% (KT) \| Zinc diethyl \| Zn(C2H5)2 \| AKOS009145267 \| Diethylzinc, elec. gr. \| zinc;ethane \| CHEBI:51496 \| UNII-S0W
规格或纯度	1.0 M in Hexane
英文名称	Diethylzinc solution
应用	和Rh (I) 催化剂一起用于从α,β-非饱和酮制备α-三氟甲基酮。 Diethylzinc solution can be used as a reagent to prepare: · α-trifluoromethyl ketones from α, β-unsaturated ketones with Rh (I) catalyst. · Alkynylzinc reagents which are used in cross-coupling reactions. · Chiral secondary alcohols from aromatic and aliphatic aldehydes in presence of camphor-derived β-amino alcohol. · 1, 4 conjugate addition product with enones. · α-fluoroacrylates from aldehydes and ketones.
储存温度	充氩
运输条件	常规运输
产品介绍	和水发生爆炸性剧烈反应，可安全地溶于干燥的饱和脂肪烃及芳烃溶剂。低浓度蒸气在空气中发烟，如产品曝露在空气中则自燃和Rh (I) 催化剂一起用于从α,β-非饱和酮制备α-三氟甲基酮。 Employed together with a Rh (I) catalyst to prepare α-trifluoromethyl ketones from α,β-unsaturated ketones. Diethylzinc solution can be used as a reagent to prepare: • α-trifluoromethyl ketones from α, β-unsaturated ketones with Rh (I) catalyst. • Alkynylzinc reagents which are used in cross-coupling reactions. • Chiral secondary alcohols from aromatic and aliphatic aldehydes in presence of camphor-derived β-amino alcohol. • 1, 4 conjugate addition product with enones. • α-fluoroacrylates from aldehydes and ketones.

AI解读

名称和识别符

EC号	209-161-3
IUPAC Name	zinc;ethane
INCHI	InChI=1S/2C2H5.Zn/c21-2;/h21H2,2H3;/q2*-1;+2
InChi Key	IPSRAFUHLHIWAR-UHFFFAOYSA-N
Canonical SMILES	C[CH2-].C[CH2-].[Zn+2]
Isomeric SMILES	C[CH2-].C[CH2-].[Zn+2]
WGK Germany	2
PubChem CID	11185
UN Number	1366
分子量	123.51
Beilstein号	3587207
Reaxy-Rn	3587207

化学和物理性质

溶解性	可混溶于乙醚、苯、石油醚。
密度	0.726
敏感性	严禁与水接触，对空气敏感，对湿度敏感
折光率	1.5
闪点(℉)	-9.4 °F
闪点(℃)	-18 °C
沸点	124°
熔点	-28°
分子量	123.500 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	2
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	122.007 Da
单同位素质量Monoisotopic Mass	122.007 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	5
形式电荷Formal Charge	0
复杂度Complexity	3.600
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	3

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS09, GHS05, GHS02
信号词	Danger
危险声明	H260: 与水接触会释放出可自燃的易燃气体 H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤 H225: 高度易燃的液体和蒸气 H400: 对水生生物有剧毒 H410: 对水生生物有剧毒并具有长期持续影响 H250: 暴露在空气中会自燃
预防措施声明	P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P223: 不允许与水接触 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P222: 不允许接触空气 P231: 在惰性气体下处理 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P391: 收集溢出物 P402+P404: 存放于干燥处。存放于密闭的容器中。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P302+P335+P334: 刷掉皮肤上的松散颗粒。浸入冷水中（或用湿绷带包扎）。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。
WGK Germany	2
Reaxy-Rn	3587207
Class	4.3
Merck Index	3131
个人防护装备	Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
RIDADR	UN3399 - class 4.3 - PG 1 - EHS - Organometallic substance, liquid, water-reactive, flammable, HI: all (not BR)

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26. Linfeng Li, Yaoqi Huang, Wenbin Li, Liyi Zou, Xi Wu, Yuanyuan Li, Xiaomin Cheng. (2023) Regulation of thermal conductivity of microencapsulated phase change materials via atomic layer deposition. Journal of Energy Storage, 68 (107668). [10.1016/j.est.2023.107668]
27. Xingfang Xiao, Bowen Zhang, Pei Lyu, Fengxiang Chen, Qian Zhang, Jiuxiao Sun, Zhan Jiang, Xin Liu, Weilin Xu. (2023) Controllable coating of zinc oxide on protein-based fibers/fabrics for superior antibacterial performance preserving wearable abilities. APPLIED SURFACE SCIENCE, 610 (155487). [10.1016/j.apsusc.2022.155487]
28. Linfeng Li, Xi Wu, Xiaomeng Zhu, Yuanyuan Li, Liyi Zou, Xiuli Wang, Wenbin Li, Xiaomin Cheng. (2022) ZnO-Reinforced Thermal Regulating Microcapsules with Double-Layer Shell via Atomic Layer Deposition. Advanced Materials Interfaces, 9 (17): (2200541). [10.1002/admi.202200541]
29. Linfeng Li, Pengju Yu, Yuanyuan Li, Xi Wu, Wenbin Li, Xiaomin Cheng. (2021) A Facile Approach to Fabricating Antibacterial Textile with High Efficiency and Compact Process. Advanced Materials Interfaces, 8 (21): (2101197). [10.1002/admi.202101197]
30. Chi Ma, Chengxiang Shi, Yakun Liu, Lun Pan, Xiangwen Zhang, Ji-Jun Zou. (2021) Synthesis and Performance of Strained Multicyclic Hydrocarbons as Highly Potential High-Energy-Density Fuels. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60 (30): (10978–10987). [10.1021/acs.iecr.1c00734]
31. Hongcheng Yang, Yizun Liu, Junjie Hao, Haodong Tang, Shihao Ding, Zhaojin Wang, Fan Fang, Dan Wu, Wenda Zhang, Haochen Liu, Bing Xu, Rui Lu, Lei Yang, Pai Liu, Kai Wang, Xiao Wei Sun. (2021) Alloyed Green-Emitting CdZnSeS/ZnS Quantum Dots with Dense Protective Layers for Stable Lighting and Display Applications. ACS Applied Materials & Interfaces, 13 (27): (32217–32225). [PMID:34184525] [10.1021/acsami.1c07647]
32. Li Yunxia, Du Wenjuan, Fu Zhiguang, Wang Huanhuan, Wang Jiexin, Le Yuan, Zhang Jianjun, Wen Ning. (2018) pH-Responsive Polycarbonate Copolymer-based Nanoparticles for Targeted Anticancer Drug Delivery. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 34 (6): (1041-1050). [10.1007/s40242-018-8147-5]
33. Ning Li, Yu Tian, Jianhui Zhao, Wei Zhan, Jinying Du, Lingchao Kong, Jun Zhang, Wei Zuo. (2018) Ultrafast selective capture of phosphorus from sewage by 3D Fe3O4@ZnO via weak magnetic field enhanced adsorption. CHEMICAL ENGINEERING JOURNAL, 341 (289). [10.1016/j.cej.2018.02.029]
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溶液计算器

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计算溶液所需的质量、体积或浓度。

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计算配制储备溶液所需的稀释度。

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复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

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所需的复溶浓度

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库存信息

库存信息

库存信息

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溶液计算器

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