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2-甲基-1-吡咯啉

2-甲基-1-吡咯啉

规格或纯度: 96%

CAS编号: 872-32-2
分子式: C₅H₉N
分子量: 83.1
MDL号: MFCD00128806
PubChem编号: 70103

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货号 (SKU)	包装规格	是否现货	价格	数量
M187405-1g	1g	现货
M187405-5g	5g	现货
M187405-10g	10g	期货
M187405-25g	25g	现货
M187405-100g	100g	现货

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基本描述

英文别名	2-Methyl-1-pyrroline\|872-32-2\|5-methyl-3,4-dihydro-2H-pyrrole\|3,4-Dihydro-5-methyl-2H-pyrrole\|2H-pyrrole, 3,4-dihydro-5-methyl-\|MFCD00128806\|PUN2A487KL\|EINECS 212-822-9\|UNII-PUN2A487KL\|FMOC-L-PROLYLCHLORIDE\|2-Methyl-1-pyrroline, 95%\|AMY886\|CHEBI:78856\|DTX
规格或纯度	96%
英文名称	2-Methyl-1-pyrroline
应用	2-Methyl-1-pyrroline (2-MPN) may be used in the enantioselective enzymatic synthesis of (R)- and (S)-2-methylpyrroline in the presence of whole-cells catalysts isolated from Strptomyces sp. strains GF3587 and GF3546 respectively.
储存温度	室温
运输条件	常规运输
产品介绍	2-Methyl-1-pyrroline, a monocyclic imine, is a pyrroline derivative. It is a five-membered heterocyclic compound having various biological and pharmacological applications. It is formed during the Rh(I) complexes (containing N,N-donor ligands and N,P-donor ligand) immobilized on glassy carbon electrode surfaces catalyzed intramolecular hydroamination of 4-pentyn-1-amine. It reacts with with 2-oxopropanal to afford acetyl-1-pyrroline (AP).2-Methyl-1-pyrroline (2-MPN) may be used in the enantioselective enzymatic synthesis of (R)- and (S)-2-methylpyrroline in the presence of whole-cells catalysts isolated from Strptomyces sp. strains GF3587 and GF3546 respectively. 2-Methyl-1-pyrroline, a monocyclic imine, is a pyrroline derivative. It is a five-membered heterocyclic compound having various biological and pharmacological applications. It is formed during the Rh(I) complexes (containing N,N-donor ligands and N,P-donor ligand) immobilized on glassy carbon electrode surfaces catalyzed intramolecular hydroamination of 4-pentyn-1-amine. It reacts with with 2-oxopropanal to afford acetyl-1-pyrroline (AP).

名称和标识符

IUPAC Name	5-methyl-3,4-dihydro-2H-pyrrole
INCHI	InChI=1S/C5H9N/c1-5-3-2-4-6-5/h2-4H2,1H3
InChi Key	CTSZPNIMMLSKDV-UHFFFAOYSA-N
Canonical SMILES	CC1=NCCC1
Isomeric SMILES	CC1=NCCC1
WGK Germany	3
PubChem CID	70103
分子量	83.1

数据库链接

PubChem SID	488184474

化学和物理性质

溶解性	Soluble in water.
密度	0.878
折光率	1.444
闪点(℉)	20 °F
闪点(℃)	10 °C
沸点	104-105 °C

安全和危险性（GHS）

象形图	Harmful Flammable
信号词	Danger
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation H225: Highly Flammable liquid and vapor
预防措施声明	P261,P305+P351+P338,P280,P370+P378,P210,P302+P352,P321,P405,P501,P233,P240,P264,P403+P235,P303+P361+P353,P271,P241,P304+P340,P403+P233,P362+P364,P242,P243,P264+P265,P337+P317,P332+P317,P319
WGK Germany	3
个人防护装备	Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

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参考文献

1. M Bertoldi,V Carbone,C Borri Voltattorni. (1999-09-08) Ornithine and glutamate decarboxylases catalyse an oxidative deamination of their alpha-methyl substrates.. The Biochemical journal, 342 Pt 3 (): (509-512). [PMID:10477260]
2. María Rodríguez-Mata,Annika Frank,Elizabeth Wells,Friedemann Leipold,Nicholas J Turner,Sam Hart,Johan P Turkenburg,Gideon Grogan. (2013-07-03) Structure and activity of NADPH-dependent reductase Q1EQE0 from Streptomyces kanamyceticus, which catalyses the R-selective reduction of an imine substrate.. Chembiochem : a European journal of chemical biology, 14 ((11)): (1372-1379). [PMID:23813853]
3. Andrey A Tregubov,Khuong Q Vuong,Erwann Luais,J Justin Gooding,Barbara A Messerle. (2013-10-04) Rh(I) complexes bearing N,N and N,P ligands anchored on glassy carbon electrodes: toward recyclable hydroamination catalysts.. Journal of the American Chemical Society, 135 ((44)): (16429-16437). [PMID:24087972]
4. Shankar S Iyer, Thomas Gensollen, Amit Gandhi, Sungwhan F Oh, Joana F Neves, Frederic Collin, Richard Lavin, Carme Serra, Jonathan Glickman, Punyanganie S A de Silva, R Balfour Sartor, Gurdyal Besra, Russell Hauser, Anthony Maxwell, Amadeu Llebaria, Richard S Blumberg,. (2018-05-19) Dietary and Microbial Oxazoles Induce Intestinal Inflammation by Modulating Aryl Hydrocarbon Receptor Responses.. Cell, 173 ((5)): ( 1123-1134 ). [PMID:29775592]
5. Koichi Mitsukura,Mai Suzuki,Sho Shinoda,Tatsuya Kuramoto,Toyokazu Yoshida,Toru Nagasawa. (2011-09-08) Purification and characterization of a novel (R)-imine reductase from Streptomyces sp. GF3587.. Bioscience, biotechnology, and biochemistry, 75 ((9)): (1778-1782). [PMID:21897027]

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