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氯化烯丙基钯(II)二聚物

产品编号 A101182 | CAS号 12012-95-2 | Aladdin
Allylpalladium(II) chloride dimer
Pd 58.2%
组合的产品项目
货号 规格 库存 价格 数量
A101182-1g Pd 58.2% 上海(4)
北方(预计3-5个工作日)
 
A101182-5g Pd 58.2% 上海(2)
北方(预计3-5个工作日)
 
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属性

密度 6.6800
熔点 120°C
存贮条件 充氮密闭冷藏,置于阴凉干燥处。

描述

产品介绍 溶于氯仿、二氯甲烷,水中分解。对空气和潮湿敏感。
别名 二-μ-氯双[(η-烯丙基)钯(II)];烯丙基氯化钯(II)二聚体,二(烯丙基)二氯二钯(II);Di-μ-chlorobis[(η-allyl)palladium(II)]
应用 1.烯烃对映选择性氢化硅烷化的预催化剂。
2.环丙烯基醋酸盐不对称烷化和氨化的预催化剂。
3.交叉耦联反应催化剂。
4.二聚体可以用作Trost配体。
5.作为高对映选择性烯丙基烷化和氨化的有用前体。
6.烯烃甲锡烷基化催化剂。
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标识符号 GHS08 GHS08
信号词 Warning
风险声明 (欧洲) R36/37/38;
安全声明(欧洲) S26;S36;
警示性声明 P281
危害码(欧洲) Xn
危害声明 H351
个人防护设备 dust mask type N95 (US),Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
WGK德国 3
参考文献
Karsten K Menzel, Gregory C GC Fu
This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a varie...Read More
M M Feuerstein, H H Doucet, M M Santelli
We're sorry this abstract is currently not available....Read More
O O L?ber, M M Kawatsura, J F JF Hartwig
We're sorry this abstract is currently not available....Read More
Matthew R Netherton, Gregory C Fu
We're sorry this abstract is currently not available....Read More
Matthias M Eckhardt, Gregory C GC Fu
A Pd/N-heterocyclic carbene-based catalyst achieves the Sonogashira coupling of an array of functionalized, beta-hydrogen-containing alkyl bromides and iodides under mild conditions. By furnishing the...Read More
Lin L Feng, Zhenglong Z Yang, Jin J Zhai, Yanlin Y Song, Biqian B Liu, Yongmei Y Ma, Zhenzhong Z Yang, Lei L Jiang, Daoben D Zhu
We're sorry this abstract is currently not available....Read More
Yasuyuki Y Harada, Yoshiya Y Fukumoto, Naoto N Chatani
[reaction: see text] The reaction of yne esters with carbon monoxide (1 atm) in the presence of palladium complexes gives bicyclic unsaturated lactone derivatives in good to high yields. The 2-pyridin...Read More