|别名||甲基苯基醚;甲氧基苯;茴香醚 ;Methoxybenzene; Phenyl methyl ether; Methyl phenyl ether|
|应用||A biochemical for proteomics research.|
|个人防护设备||Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter|
Discovery of estrogen receptor α modulators from natural compounds in Si-Wu-Tang series decoctions using estrogen-responsive MCF-7 breast cancer cells.
The binding between the estrogen receptor α (ER-α) and a variety of compounds in traditional Chinese formulae, Si-Wu-Tang (SWT) series decoctions, was studied using a stably-transfected human breast...Read More
Transdermal penetration was studied as a function of selected descriptors in QSPR using CART, boosted CART and MLR models....Read More
Resonance-enhanced two-photon ionization spectroscopy and theoretical calculations of 3,5-difluoroanisole and its Ar-containing complex.
The structure and vibrations of 3,5-difluoroanisole (3,5-DFA) in the first electronically excited (S(1)) state were studied by mass-analyzed resonant two-photon ionization (R2PI) technique as well as ...Read More
Folding-promoted TBAX-mediated selective demethylation of methoxybenzene-based macrocyclic aromatic pentamers.
Described in this study is the ability of tetrabutylammonium salts (TBAX) to mediate an efficient mono- or di-demethylation removing one or two out of five aromatic methoxy methyl groups situated in s...Read More
High-resolution NMR spectroscopy in inhomogeneous fields via Hadamard-encoded intermolecular double-quantum coherences.
A new pulse sequence based on intermolecular double-quantum coherences was proposed to obtain one-dimensional high-resolution liquid NMR spectra in inhomogeneous magnetic fields via Hadamard encoding....Read More
QSPR models of n-octanol/water partition coefficients and aqueous solubility of halogenated methyl-phenyl ethers by DFT method.
The possible molecular geometries of 134 halogenated methyl-phenyl ethers were optimized at B3LYP/6-31G(*) level with Gaussian 98 program. The calculated structural parameters were taken as theoretica...Read More
3,4,4'-Trihydroxy-trans-stilbene, an analogue of resveratrol, is a potent antioxidant and cytotoxic agent.
Resveratrol (3,5,4'-trihydroxy-trans-stilbene) is a naturally occurring polyphenol widely distributed in food and dietary plants. This phytochemical has been intensively studied as an efficient a...Read More
Various carotenoids were analyzed by ultra-high-pressure liquid chromatography with tandem mass spectrometry detection (UHPLC-MS/MS). Three different techniques to ionize the carotenoids were compared...Read More
Air-water exchange of anthropogenic and natural organohalogens on International Polar Year (IPY) expeditions in the Canadian Arctic.
Shipboard measurements of organohalogen compounds in air and surface seawater were conducted in the Canadian Arctic in 2007-2008. Study areas included the Labrador Sea, Hudson Bay, and the southern Be...Read More
Development and optimisation of a dopant assisted liquid chromatographic-atmospheric pressure photo ionisation-tandem mass spectrometric method for the determination of 15+1 EU priority PAHs in edible oils
European food legislation defines a set of 16 polycyclic aromatic hydrocarbons (PAHs) as of high concern for human health. The EU set contains structurally very similar PAHs with ring numbers between ...Read More
A CuI-catalyzed direct access to sulfides from disulfides via C-H bond cleavage of di- or trimethoxybenzene is described. The procedure utilizes O(2) as a clean and cheap oxidant. Direct selenation of...Read More
Cyano bonded silica monolith-Development of an in situ modification method for analytical scale columns
This study investigates the synthesis and chromatographic behaviour of an analytical size cyanopropyl ''cyano'' bonded silica monolith. Surface modification was undertaken by treat...Read More
A GPI anchor bearing unsaturated fatty acid lipid chains (1) was synthesized by a highly convergent strategy employing the para-methoxybenzyl group for permanent hydroxyl protection. The final global ...Read More
Unusual ipso Substitution of Diaryliodonium Bromides Initiated by a Single-Electron-Transfer Oxidizing Process.
We're sorry this abstract is currently not available....Read More
Low-cost fluorimetric determination of radicals based on fluorogenic dimerization of the natural phenol sesamol.
A novel fluorimetric method for determining radicals using the natural phenol sesamol as a fluorogenic reagent is reported. In this assay, sesamol was reacted with aqueous radicals to yield one isomer...Read More
Second-order reaction rate constants of micropollutants with ozone (k(O3)) and hydroxyl radicals (k(OH)) are essential for evaluating their removal efficiencies from water during ozonation and advance...Read More
Transforming frozen self-assemblies of amphiphilic block copolymers into dynamic pH-sensitive micelles.
The self-assembly in water of an amphiphilic P(nBMA(50%) -stat-DMAEMA(50%) )(100)-b-PDMAEMA(235) diblock copolymer based on hydrophilic dimethylaminoethylmethacrylate (DMAEMA) units and hydrophobic n-...Read More
In this paper we introduce laser ablation atmospheric pressure photoionization (LAAPPI), a novel atmospheric pressure ion source for mass spectrometry. In LAAPPI the analytes are ablated from water-ri...Read More
The present paper reports on an integrated spectroscopic study of the anisole-phenol complex in a molecular beam environment. Combining REMPI and HR-LIF spectroscopy experimental data with density fun...Read More
Evaluation of dispersive liquid-liquid microextraction for the simultaneous determination of chlorophenols and haloanisoles in wines and cork stoppers using gas chromatography-mass spectrometry
Dispersive liquid-liquid microextraction (DLLME) coupled with gas chromatography-mass spectrometry (GC-MS) was evaluated for the simultaneous determination of five chlorophenols and seven haloanisoles...Read More
Size-controlled, catalytically active PVP-stabilised Pd nanoparticles have been studied by operando liquid phase XAS during the Suzuki cross-coupling of iodonanisole and phenylboronic acid in MeOH-tol...Read More
We report on a dyad in which photoinduced hole transfer through a non-uniform molecular double barrier is more than one order of magnitude more rapid than hole transfer across a comparable uniform (re...Read More
The NMR and fluorescence quenching of benzene, chlorobenzene and methoxybenzene in acetonitril and 2-propanol solvents have been carried out with a view to understand the quenching mechanisms. The que...Read More
Structure and vibrational frequencies of 6,7-dimethoxy-1,4-dihydro-1,3-quinoxalinedione based on density functional theory calculations: The role of @p-electron conjugation and back-donation
This work deals with the vibrational spectroscopy of 6,7-dimethoxy-1,4-dihydro-1,3-quinoxalinedione by means of quantum chemical calculations. The mid and far FT-IR and FT-Raman spectra are recorded i...Read More
Application of response surface method using rapid screening, support vector machine, and multiple regression on the acidity and activity of Si-Al-Zr ternary oxide.
To study the synergistic effect on the acidity and activity of Si-Al-Zr ternary oxide system, the mixture design of experiments was applied to prepare the ternary oxides by a sol-gel method, and rapid...Read More
The sulfonation of phenyl ether decorated self-assembled monolayers (SAMs) was studied with an eye toward creating surfaces with a particularly high negative charge density based on a close-packed arr...Read More
Convenient QSAR model for predicting the complexation of structurally diverse compounds with @b-cyclodextrins
This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with @b-cyclodextrins (@b-CDs). Several different theoretical...Read More