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氯丙烯

产品编号 A103822 | CAS号 107-05-1 | Aladdin
Allyl chloride
分析标准品,>99.5%(GC)
组合的产品项目
货号 规格 库存 价格 数量
A103822-1g 分析标准品,>99.5%(GC) 上海(>10)
北方(预计3-5个工作日)
 
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属性

折光率 1.4154
密度 0.9390
熔点 134.5°C
沸点 44.96°C
溶解性 不溶于水,可混溶于乙醇、乙醚、氯仿、石油醚等多数有机溶剂。
存贮条件 储存温度2-8℃

描述

产品介绍 易挥发、可燃,具有腐蚀性和刺激性气味,既具有有机氯化物的性质,又表现出烯烃的性质。能与乙醇、氯仿、乙醚和石油醚混溶,微溶于水。
别名 氯丙烯 ;烯丙基氯,α-氯丙烯,3-氯-1-丙烯,3-氯丙烯;3-chloropropene 3-Chloro-1-propene
应用 由于它具有活泼的化学特性,使其成为有机合成的一个重要中间体,除作为制造环氧氯丙烷、甘油的原料外,也可用作合成丙烯醇、医药、染料、农药及合成树脂的原料。
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标识符号 GHS02 GHS02, GHS07 GHS07, GHS08 GHS08, GHS09 GHS09
信号词 Danger
风险声明 (欧洲) R11;R40;R50;R20/21/22;R36/37/38;R48/20
安全声明(欧洲) S16;S25;S26;S36/37;S46;S61
警示性声明 P210,P261,P273,P281,P305+P351+P338
危害码(欧洲) F,Xn,N
危害声明 H225,H302,H312,H315,H319,H332,H335,H341,H351,H373,H400
个人防护设备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US)
RTECS UC7350000
WGK德国 2
Merck Index 289
闪点(摄氏) -31℃
是否危化品 一般危险品
UN代码 1100
参考文献
Kai K Abersfelder, David D Scheschkewitz
The rearrangements of (chlorosilyl)disilenes R2(Cl)Si-(Tip)Si=SiTip2 (5a,b: Tip = 2,4,6-iPr3C6H2, a: R = Me, b: R = Ph) quantitatively yield the isomeric chlorocyclotrisilanes (6a,b). The disilene pre...Read More
Kiyotaka K Onitsuka, Haruki H Okuda, Hiroaki H Sasai
We're sorry this abstract is currently not available....Read More
Qing-shan QS Wang, Ying-jian YJ Zhu, Li-ping LP Zhang, Xin X Guo, Ke-qin KQ Xie
To compare the results of in vivo and in vitro in determination of the changes of allyl chloride (AC)-induced electrophysiology in rats sciatic nerve....Read More
Qing-Shan Wang, Fuyong Song, Xiulan Zhao, Li-yan Hou, Ke-Qin Xie
Allyl chloride (AC) is widely used in industries as raw material and has been reported to produce occupational peripheral neuropathies in man chronically exposure to it. Although many studies have bee...Read More
Qing-Shan QS Wang, Cui-Li CL Zhang, Xiu-Lan XL Zhao, Su-Fang SF Yu, Ke-Qin KQ Xie
Chronic exposure to allyl chloride (AC) is known to produce a central-peripheral distal axonopathy. To access the biomarker of exposure and elucidate the mechanism of neuropathy induced by AC, we perf...Read More
Ti Ouyang, Xingyu Gao, Dongchen Qi, Andrew Thye Shen Wee, Kian Ping Loh
The adsorption of allyl alcohol, acrylic acid, and allyl chloride, as well as unsaturated organic molecules such as acetylene and 1,3 butadiene, on reconstructed diamond (100) 2 x 1 have been investig...Read More
Qing-Shan QS Wang, Ke-Qin KQ Xie, Cui-li CL Zhang, Ying-Jian YJ Zhu, Li-Ping LP Zhang, Xin X Guo, Su-fang SF Yu
To accurately know the time-dependent changes of the lipid peroxidation and antioxidative status for elucidating the mechanism of neuropathy induced by allyl chloride (AC), the malondialdehyde (MDA), ...Read More
K K Xie, K K Sun, S S Gao, L L Zhang, M M Zhang
To dissect the molecular mechanism of toxic neuropathy induced by allyl chloride (AC)....Read More
We're sorry this abstract is currently not available....Read More
M M Zhao
In this study, 124 mg/kg of allyl chloride (one-fifth of LD50) was administered to mice by a single subcutaneous injection and its effects on the male reproductive system were evaluated at 4 days, 9 d...Read More
Yan-Bo Yu, Shilu Fan, Xingang Zhang
Simply id(all)ylic: a copper- and phosphine-ligand-free Pd-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides and the reaction mechanism are described. The simpl...Read More
Vikas V Sikervar, James C JC Fleet, Philip L PL Fuchs
A coupling strategy for the synthesis of 2,4-dimethyl-1α,25(OH)(2)D(3) is achieved which involves methylation of a pro-A ring vinyl sulfone and in situ traping of the allyl sulfonyl anion with a CD r...Read More
Laura A Brozek, Michael J Ardolino, James P Morken
Palladium-catalyzed allyl-allyl cross-coupling was investigated with substituted prochiral allylic boronates. These reactions deliver products bearing adjacent stereocenters, and the issue of diastere...Read More
Heike Burghart-Stoll, Reinhard Bru?ckner
A (DHQN)(2)AQN-promoted asymmetric dihydroxylation (92% ee) of the allyl chloride derived from enynol (E)-13 and an 8-step sequence provided access to the hydroxyethylated furanone (R)-21. Oxidation w...Read More
Justin M JM Chalker, Yuya A YA Lin, Omar O Boutureira, Benjamin G BG Davis
Multiple, complementary methods are reported for the chemical conversion of cysteine to S-allyl cysteine on protein surfaces, a useful transformation for the exploration of olefin metathesis on protei...Read More
I V IV Kudaeva, L A LA Budarina, L B LB Masnavieva
The article covers results of examination of workers engaged into chemical production and contacting neurotoxic factors varying in nature. Findings are disorders of cholesterol metabolism in individua...Read More
Shirong Lu, Zhanwei Xu, Ming Bao, Yoshinori Yamamoto
We're sorry this abstract is currently not available....Read More
Fumihiro Amemiya, Hideyuki Matsumoto, Keishi Fuse, Tsuneo Kashiwagi, Chiaki Kuroda, Toshio Fuchigami, Mahito Atobe
Product selectivity control based on a liquid-liquid parallel laminar flow has been successfully demonstrated by using a microreactor. Our electrochemical microreactor system enables regioselective cr...Read More
Richard M RM Lopachin, David S DS Barber, Brian C BC Geohagen, Terrence T Gavin, Deke D He, Soma S Das
Acrylamide (ACR) is a conjugated type-2 alkene that produces synaptic toxicity presumably by sulfhydryl adduction. The alpha,beta-unsaturated carbonyl of ACR is a soft electrophile and, therefore, add...Read More
Shin-ichi S Ikeda, Kaori K Suzuki, Kazunori K Odashima
The Ni-catalyzed coupling of allyl chlorides and enynes has been developed; the cyclization of enynes was triggered by the addition of pi-allylnickel species to the alkyne part, followed by the incorp...Read More
M M Zhao, M M Omura, S S Tokunaga, Y Y Romero, N N Inoue
We're sorry this abstract is currently not available....Read More
B M BM de Rooij, P J PJ Boogaard, J N JN Commandeur, N J NJ van Sittert, N P NP Vermeulen
To evaluate the use of urinary mercapturic acids as a biomarker of human exposure to allyl chloride (3-chloropropene) (AC). During three regular shut down periods in a production factory for AC, both ...Read More
B M de Rooij, J N Commandeur, E J Groot, P J Boogaard, N P Vermeulen
Allyl chloride (AC) is used as intermediate in the synthesis of epichlorohydrin (ECH). We investigated the biotransformation of AC in rats to select potential urinary biomarkers of exposure. For this ...Read More
Y Y He, M M Nagano, H H Yamamoto, E E Miyamoto, M M Futatsuka
Chronic exposure to allyl chloride (ALL) is known to produce a central-peripheral distal axonopathy. In relation to the mechanism(s), the present study was conducted to examine the abilities of ALL an...Read More
Alfonso Pérez-Garrido, Maykel Pérez González, Amalio Garrido Escudero
We're sorry this abstract is currently not available....Read More