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丙烯酰氯

产品编号 A104614 | CAS号 814-68-6 | Aladdin
Acryloyl chloride
96%,含200 ppm MEHQ 稳定剂
组合的产品项目
货号 规格 库存 价格 数量
A104614-100g 96%,含200 ppm MEHQ 稳定剂 上海(>10)
北方(预计3-5个工作日)
 
A104614-25g 96%,含200 ppm MEHQ 稳定剂 上海(>10)
北方(预计3-5个工作日)
 
A104614-500g 96%,含200 ppm MEHQ 稳定剂 上海(7)
北方(2)
 
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属性

敏感性 对光线和热敏感,易吸潮
折光率 1.4343
密度 1.1200
沸点 75-76°C
存贮条件 储存温度2-8℃,充氩保存

描述

产品介绍 易溶于氯仿,遇水和醇分解。有毒。有催泪性和腐蚀性。商品常加吩噻嗪和对苯二酚作稳定剂。
别名 氯化丙烯酸;烯丙酰氯;Propenoyl chloride;2-Propenoyl chloride
应用 有机合成中间体。高分子化合物单体。
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标识符号 GHS02 GHS02, GHS05 GHS05, GHS06 GHS06
信号词 Danger
风险声明 (欧洲) R11;R14;R26;R34
安全声明(欧洲) S7/9;S16;S26;S28;S36/37/39;S45
警示性声明 P210,P260,P280,P284,P305+P351+P338,P310
危害码(欧洲) F,T+
危害声明 H225,H314,H330
WGK德国 3
闪点(摄氏) 16℃
UN代码 3383
参考文献
Steven C Polomoscanik, C Pat Cannon, Thomas X Neenan, S Randall Holmes-Farley, W Harry Mandeville, Pradeep K Dhal
Iron overload is a severe clinical condition and can be largely prevented by the use of iron-specific chelating agents. A successful iron chelator needs to be orally active, nontoxic, and selective. I...Read More
Jie Wang, Song-Dong Ding, Yu-Zhong Wang
We're sorry this abstract is currently not available....Read More
Wen-Fu Lee, Tzu-Shen Cheng
A series of amphiphilic random block co-polymers were synthesized by the condensation of hydrophobic polycaprolactone diol (PCL diol) with hydrophilic dicarboxy poly(ethylene glycol) (PEG-diacid), obt...Read More
Maofa Ge, Chunping Ma, Wei Xue
Acryloyl isocyanate CH(2)=CHC(O)NCO is quantitatively prepared by the metathesis reaction between CH(2)=CHC(O)Cl and AgNCO. Also, jointly with acryloyl chloride, their molecular and electronic structu...Read More
Gang-Long GL Cui, Qian-Song QS Li, Feng F Zhang, Wei-Hai WH Fang, Jian-Guo JG Yu
The potential energy surfaces of isomerization and dissociation reactions for CH2CHCOCl in the S0, T1, T2, and S1 states have been mapped with DFT, CASSCF, MP2, and MR-CI calculations. Rate constants ...Read More
Surendra S Nimesh, Romila R Manchanda, Rupesh R Kumar, Amit A Saxena, Preeti P Chaudhary, Veena V Yadav, Subho S Mozumdar, Ramesh R Chandra
Polymeric nanoparticles of AADG cross-linked with MBA encapsulating water soluble macromolecules such as FITC-Dextran have been prepared in the reverse micellar system. The particles obtained were of ...Read More
Iris I Ben-David, Yulia Y Rozen, Giuseppina G Ortu, Eyal E Mishani
An automated procedure for the radiosynthesis of the labeling synthon [11C]acryloyl chloride was developed and applied for labeling several N-acryl amides with carbon-11. [11C]-6-acrylamido-4-(3,4-dic...Read More
J C JC Tiller, C J CJ Liao, K K Lewis, A M AM Klibanov
Poly(4-vinyl-N-alkylpyridinium bromide) was covalently attached to glass slides to create a surface that kills airborne bacteria on contact. The antibacterial properties were assessed by spraying aque...Read More
F L FL Lau, S Y SY Chu, T S TS Yu
Three university students were exposed to toxic vapours (acryloyl chloride 96% and methacrylic anhydride 94%) in a laboratory accident. They all gave a history of minimal exposure and presented with m...Read More
V B VB Gerasimas, V M VM Chernoglazov, A A AA Klesov
The chemical modification of glucoamylase from Aspergillus niger with acryloylchloride has been studied. It was shown that the first 60--70% of the total amount of available amino groups of the enzyme...Read More
L M LM Iakunitskaia, N V NV Beliakov, M A MA Samartsev, A I AI K?stner
Thin-layer isoelectric focusing of chymotrypsin modified by stepwise acylation with acryloyl chloride or maleic anhydride revealed a high heterogeneity of modification products, with a maximal number ...Read More
V V Bille, D D Plainchamp, J J Remacle
Yeast alcohol dehydrogenase (alcohol:NAD+ oxidoreductase, EC 1.1.1.1), a potentially useful enzyme for cofactor regeneration processes, was covalently immobilized in a multipoint fashion by activation...Read More
V V Fulcrand, R R Jacquier, R R Lazaro, P P Viallefont
Copolymers of acrylated derivatives of alpha-chymotrypsin and polyethylene glycol (PEG) have been prepared and used as biocatalysts for the synthesis of model peptides in organic solvent containing a ...Read More
Jung Im JI Lee, Hye Sung HS Kim, Hyuk Sang HS Yoo
Chitosan/Pluronic hydrogels were prepared to develop injectable depot systems for gene therapy to enhance local transgene expression at injection sites. Water-soluble chitosan and Pluronic were separa...Read More
Kunal K Pal, A K AK Banthia, D K DK Majumdar
The purpose of this work is to prepare a pH-sensitive hydrogel membrane of sodium carboxymethyl cellulose acrylate for drug delivery and other biomedical applications. The hydrogel was made by esterif...Read More
E E Johansson, J J JJ Steffens, Y Y Lindqvist, G G Schneider
Background: The biosynthesis of the essential amino acid lysine in higher fungi and cyanobacteria occurs via the @a-aminoadipate pathway, which is completely different from the lysine biosynthetic pat...Read More
R R Bahulekar, N N Tamura, S S Ito, M M Kodama
Poly(N-alkyl mono and disubstituted) acrylamide derivatives were synthesized from poly(acryloyl chloride) by monomer analogous reaction. The polymers were characterized by FTIR-ATR and GPC. The contac...Read More
R R Peters, R R Sikorski
We're sorry this abstract is currently not available....Read More
M C Lasne, P Cairon, L Barré
We're sorry this abstract is currently not available....Read More
M C MC Lasne, P P Cairon, L L Barre
The reproducible preparation of [1-11C]propenoic acid (acrylic acid) in 45-50% radiochemical yield was made possible by careful control of the temperature and time of the 11C carbonation of ethenylmag...Read More
Jana Becher, Stephanie M?ller, Matthias Schnabelrauch
Glycosaminoglycans and its derivatives have gained increasing attention for the fabrication of hydrogels usable in biomedicine. Starting from high molecular weight hyaluronan, a natural glycosaminogly...Read More