|别名||高氯酸镁;无水过氯酸镁;Magnesium perchlorate; Perchloric acid magnesium salt; Anhydrone|
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Ultrafast two-dimensional infrared spectroscopy resolves the conformational change of an Evans auxiliary induced by Mg(ClO4)2.
Structure determination of reactive species is a key step in understanding reaction mechanisms. We demonstrate the application of polarization-dependent two-dimensional infrared spectroscopy (P2D-IR) ...Read More
Notable effects of the metal salts on the formation and decay reactions of α-tocopheroxyl radical in acetonitrile solution. The complex formation between α-tocopheroxyl and metal cations.
The measurement of the UV-vis absorption spectrum of α-tocopheroxyl (α-Toc(?)) radical was performed by reacting aroxyl (ArO(?)) radical with α-tocopherol (α-TocH) in acetonitrile solution includi...Read More
We have used time-resolved multidimensional vibrational spectroscopy, generally termed 2DIR spectroscopy, to study the equilibrium dynamics of ligand exchange in an aqueous solution containing 3.4 M M...Read More
Zinc phthalocyanine-perylenebisimide pentameric arrays, ZnPc(PDI)(4) 1 and 2, have been synthesized. ZnPc(PDI)(4) 1 has no substituents in the PDI bay positions, while ZnPc(PDI)(4) 2 presents four phe...Read More
Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction.
Starting from D-(-)-ribose, a tricyclic natural product-like scaffold suitable for combinatorial derivatization was synthesized via an intramolecular hetero-Diels-Alder reaction. Lithium perchlorate w...Read More
The interaction of Mg2+ cations in biological systems is studied by using nucleic acid bases as the biological system. Magnesium salts, such as, MgCl2 6H2O, MgSO4. 7H2O and Mg(ClO4). XH2O have been em...Read More
In experiments on rats it was established that the compound CAM-300 in a dose of 2 mg/kg did not induce body mass growth, protein biological value increase or pepsinogen concentration change in the ga...Read More
The mechanism of the gamma-radiolysis of the nucleotide guanosine-5'-monophosphate (5'-GMP) in the presence of Mg++ ions and cis-platinum was investigated. From high performance liquid chrom...Read More
The dose rate effects on the in vitro radiolysis products of magnesium-guanosine-5'-monophosphate complexes in aqueous solutions.
This study examined the effects on the radiolysis of magnesium-guanosine-5'-monophosphate complexes in deaerated aqueous solutions, investigated by Fourier transform infrared (FT-IR) spectroscopy...Read More
Chloranil-photosensitized monomerization of dimethylthymine cyclobutane dimers and effect of magnesium perchlorate.
The photosensitized monomerization of the cyclobutane dimers of 1,3-dimethylthymine by p-chloranil was investigated by means of steady-state irradiation and laser-flash photolysis. Quantum yields for ...Read More