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硫酸苯胺

产品编号 A108448 | CAS号 542-16-5 | Aladdin
Aniline sulfate
AR,99.0%
组合的产品项目
货号 规格 库存 价格 数量
A108448-100g AR,99.0% 上海(预计4-8周)
北方(预计4-8周)
 
A108448-25g AR,99.0% 上海(>10)
北方(预计3-5个工作日)
 
A108448-500g AR,99.0% 上海(预计4-8周)
北方(预计4-8周)
 
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属性

敏感性 对光敏感
密度 1.3800
熔点 128°C
沸点 400~401°C
存贮条件 密封避光保存。

描述

产品介绍 溶于乙醚,微溶于水,稍溶于热水、乙醇和乙醚。易溶于醋酸和稀盐酸。有致癌可能性。
别名 硫酸苯胺 ;苯胺硫酸盐 ;(1,1'-biphenyl)-4,4'-diamine sulfate (1:1) 4,4′-diamino diphenyl sulfate Benzidine sulfate
应用 测定多种金属的试剂。
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标识符号 GHS05 GHS05, GHS06 GHS06, GHS08 GHS08, GHS09 GHS09
信号词 Danger
风险声明 (欧洲) R40;R41;R43;R50;R23/24/25;R48/23/24/25
安全声明(欧洲) S26;S27;S36/37/39;S45;S61
警示性声明 P280,P273,P305+P351+P338,P361,P304+P340,P310
危害码(欧洲) T,N
危害声明 H301,H311,H331,H317,H372,H341,H351,H318,H400
WGK德国 3
是否危化品 一般危险品
UN代码 2811
参考文献
Regina Ma?eikien?, Gediminas Niaura, Albertas Malinauskas
For the first time, chemical oxidation of aniline and N-methylaniline with dichromate as oxidant has been studied by Raman spectroscopy with 785 nm laser beam excitation, and the suitability of this t...Read More
Aleem Gangjee, Nilesh Zaware, Ravi Kumar Vyas Devambatla, Sudhir Raghavan, Cara D Westbrook, Nicholas F Dybdal-Hargreaves, Ernest Hamel, Susan L Mooberry
A series of fourteen N(4)-(substituted phenyl)-N(4)-alkyl/desalkyl-9H-pyrimido[4,5-b]indole-2,4-diamines was synthesized as potential microtubule targeting agents. The synthesis involved a Fisher indo...Read More
Felix A Westerhaus, Rajenahally V Jagadeesh, Gerrit Wienh?fer, Marga-Martina Pohl, J?rg Radnik, Annette-Enrica Surkus, Jabor Rabeah, Kathrin Junge, Henrik Junge, Martin Nielsen, Angelika Brückner, Matthias Beller
Molecularly well-defined homogeneous catalysts are known for a wide variety of chemical transformations. The effect of small changes in molecular structure can be studied in detail and used to optimiz...Read More
Wen Chen, Gary B Schuster
A series of linear and cyclic, sequence controlled, DNA-conjoined copolymers of aniline (ANi) and 2,5-bis(2-thienyl)pyrrole (SNS) were synthesized. In one approach, linear copolymers were prepared fro...Read More
Rongjun He, Li-Fan Zeng, Yantao He, Li Wu, Andrea Michelle Gunawan, Zhong-Yin Zhang
Mycobacterium protein tyrosine phosphatase B (mPTPB) is essential for the survival and persistence of Mycobacterium in the host. Thus small molecule inhibitors of mPTPB are potential anti-TB agents. W...Read More
Timo Stahl, Hendrik F T Klare, Martin Oestreich
Heterolytic splitting of the Si-H bond mediated by a Ru-S bond forms a sulfur-stabilized silicon cation that is sufficiently electrophilic to abstract fluoride from CF(3) groups attached to selected a...Read More
Xuejian Li, Yanyan Zhao, Haijun Qu, Zhenjun Mao, Xufeng Lin
The first catalytic asymmetric pseudo five-component (AB(2)C(2) type) reaction is reported. A spirocyclic chiral phosphoric acid catalyzed one-pot multicomponent reaction of aromatic aldehydes, anilin...Read More
A Subashini, G Bhagavannarayana, K Ramamurthi
One of the Schiff base 4-bromo-4'dimethylamino benzylideneaniline (BDMABA) compounds was synthesized and single crystal of the material was grown by solvent evaporation method at room temperature...Read More
Ping-Xin Zhou, Zhao-Zhao Zhou, Zi-Sheng Chen, Yu-Ying Ye, Lian-Biao Zhao, Yan-Fang Yang, Xiao-Feng Xia, Jian-Yi Luo, Yong-Min Liang
Two different cyclic amino esters are synthesized by palladium-catalyzed cross-coupling reaction of diazoesters with N-substituted-2-iodoanilines. Aryldiazoacetates lead to cyclic α-amino esters with...Read More
Mitsuhiro Arisawa, Yuki Fujii, Hiroshige Kato, Hayato Fukuda, Takashi Matsumoto, Mika Ito, Hiroshi Abe, Yoshihiro Ito, Satoshi Shuto
We're sorry this abstract is currently not available....Read More
Huihui Yang, Yingzhuang Chen, Yixuan Liu, Lihua Nie, Shouzhuo Yao
A novel (3-sulfopropyl methacrylate potassium)-silica hybrid monolithic column for CEC has been prepared by a simple one-pot approach based on efficient thiol-ene click chemistry. In this process, the...Read More
David Bonnel, Julien Franck, Céline Mériaux, Michel Salzet, Isabelle Fournier
In the current study, we compared plastic matrix-assisted laser desorption/ionization (MALDI) plates pre-spotted with different solid ionic matrices. Data reflect that after 3months of storage, the st...Read More
Hannelore Jasch, Julia Scheumann, Markus R Heinrich
Substituted 2-aminobiphenyls have been prepared from arylhydrazines and anilines via radical arylation reactions under simple oxidative conditions. The strong directing effect of the free and unproton...Read More
Ping-Xin Zhou, Jian-Yi Luo, Lian-Biao Zhao, Yu-Ying Ye, Yong-Min Liang
Isoindolines are synthesized by palladium-catalyzed coupling reaction of N-(2-iodobenzyl) anilines with α,β-unsaturated N-tosylhydrazones. The reaction has several potential advantages: (1) tolerati...Read More
Milena Trm?i?, Frances L Chadbourne, Paul M Brear, Paul W Denny, Steven L Cobb, David R W Hodgson
We recently reported the use of PSCl3 for the thiophosphorylation of alkylamines where the resulting N-thiophosphoramidate ions could be readily S-alkylated (Chem. Commun., 2011, 47, 6156-6158.). Here...Read More
Yu Qian, Changcheng Jing, Shunying Liu, Wenhao Hu
An enantioselective four-component reaction of a diazoketone, water, an aniline and ethyl glyoxylate in the presence of catalytic Rh(OAc) and a chiral Br?nsted acid was developed to efficiently produc...Read More
Laya Siroos Rezaei, Bita Ayati, Hossein Ganjidoust
Aerobic granules can be formed in sequencing batch airlift reactors (SBAR) and sequencing batch reactors (SBR). Comparing these two systems, the SBAR has excellent mixing condition, but due to a high ...Read More
Huaxian Ma, Jianling Wang, Sherif Z Abdel-Rahman, Paul J Boor, M Firoze Khan
Mechanisms by which aniline exposure elicits splenotoxicity, especially a tumorigenic response, are not well-understood. Earlier, we have shown that aniline exposure leads to oxidative DNA damage and ...Read More
Roman Spesyvtsev, Oliver M Kirkby, Helen H Fielding
Femtosecond time-resolved photoelectron imaging is employed to investigate ultrafast electronic relaxation in aniline, a prototypical aromatic amine. The molecule is excited at wavelengths between 269...Read More
B V Subba Reddy, Manisha Swain, S Madhusudana Reddy, J S Yadav, B Sridhar
A domino cycloisomerization/Pictet-Spengler reaction of 2-(4-aminobut-1-yn-1-yl)aniline with aldehydes has been achieved using a AuIPrCl (5 mol %)/AgSbF(6) (10 mol %) catalytic system to produce the c...Read More
Dongdong Liang, Ziwei Hu, Jiangling Peng, Jinbo Huang, Qiang Zhu
An efficient synthesis of free (NH)-phenanthridinones through Pd-catalyzed C(sp(2))-H aminocarbonylation of unprotected o-arylanilines under an atmospheric pressure of CO has been developed. Some orth...Read More
Conghui Tang, Ning Jiao
A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the me...Read More