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乙酰氯

¥ 159.00

产品编号 A108664 | CAS号 75-36-5 | Aladdin
Acetyl chloride
99%,无色
组合的产品项目
货号 规格 库存 价格 数量
A108664-2.5L 99%,无色 上海(5)
北方(预计3-5个工作日)
 
A108664-500ml 99%,无色 上海(>10)
北方(预计3-5个工作日)
 
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属性

敏感性 对热敏感,湿度敏感
折光率 1.3898
密度 1.1000
熔点 -112°C
沸点 52°C
存贮条件 充氩气保存;储存温度2-8°C

描述

产品介绍 能发烟。有吸湿性。溶于乙醚、苯、氯仿、冰乙酸、石油醚、丙酮和乙酸等。遇水或醇引起剧烈分解。有腐蚀性。
别名 氯乙酰,氯化醋酰;氯化乙酰;Ethanoyl chloride
应用 测定胆固醇及有机液体中的水分、测定羟基四乙基铅等,鉴定亚硝基。用作乙酰化试剂。用于制药的染料合成。
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标识符号 GHS02 GHS02, GHS05 GHS05
信号词 Danger
风险声明 (欧洲) R11;R14;R34
安全声明(欧洲) S9;S16;S26;S45
警示性声明 P210,P280,P305+P351+P338,P310
危害码(欧洲) F,C
危害声明 H225,H314
个人防护设备 Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US)
RTECS AO6390000
WGK德国 1
Merck Index 85
闪点(摄氏) (闭杯)4.4℃
是否危化品 一般危险品
UN代码 1717
参考文献
Erik N K Cressman, David A Jahangir
This study aimed to investigate two readily available electrophilic reagents, acetyl chloride (AcCl), and acetic anhydride (Ac(2)O), for their potential in tissue ablation.Reagents were diluted in dig...Read More
Christian Ludwig, Ildefonso Marin-Montesinos, Martin G Saunders, Abdul-Hamid Emwas, Zoe Pikramenou, Stephen P Hammond, Ulrich L Günther
Dynamic nuclear polarization (DNP) has become an attractive technique to boost the sensitivity of NMR experiments. In the case of ex situ polarizations two-dimensional (2D) spectra are limited by the ...Read More
Chia-Ying CY Lee, Chi-Fong CF Lin, Jeng-Lin JL Lee, Ching-Chen CC Chiu, Wen-Der WD Lu, Ming-Jung MJ Wu
Various 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines 1a-g were treated with potassium tert-butoxide or potassium 3-ethylpentanoxide in NMP at 60 degrees C for 2 h to give the corresponding 5-substi...Read More
Hiroki H Mandai, Kyouta K Murota, Koichi K Mitsudo, Seiji S Suga
An efficient and simple protocol for the kinetic resolution of secondary alcohols is presented. The new system is based on a combination of chiral Br?nsted acid, DABCO, and acetyl chloride and gives v...Read More
Stephen Bell
A wide range of ab initio and hybrid density functional methods and basis sets have been employed to calculate the barriers to methyl internal rotation in a range of molecules with the acetyl moiety. ...Read More
Amy K AK Styring, Alison A Kuhl, Timothy D J TD Knowles, Rebecca A RA Fraser, Amy A Bogaard, Richard P RP Evershed
Stable nitrogen isotope (δ(15)N) values of bone collagen are routinely used to inform interpretations of diet and trophic positions within contemporary and ancient ecosystems, yet the underlying phys...Read More
Tatsuki T Takahashi, Takashi T Konno, Kenichi K Ogata, Shin-ichi S Fukuzawa
The stereochemistry of the substitution of the α-dimethylamino group by dimethylzinc in the presence of acetyl chloride in the chiral benzylferrocene backbone was examined. The reaction with the benz...Read More
M R F Lee, J K S Tweed, E J Kim, N D Scollan
When fractionation of meat lipids is not required, procedures such as saponification can be used to extract total fatty acids, reducing reliance on toxic organic compounds. However, saponification of ...Read More
Takuya T Arai
Developments in the Stille cross-coupling of [1-11C]acetyl chloride with tributylphenylstannane mediated by the Pd2(dba)3/P(MeNCH2CH2)3N·HClsystem are reported....Read More
Pavan K Kancharla, Y Suman Reddy, Suresh Dharuman, Yashwant D Vankar
A new reagent system comprising acetyl chloride, silver nitrate, and acetonitrile has been developed for the synthesis of 2-nitroglycals from the corresponding glycals. Under certain conditions, the f...Read More
Yu-Ting YT Liu, Ming-Tsang MT Tsai, Chia-Yun CY Liu, Po-Yu PY Tsai, King-Chuen KC Lin, Y H YH Shih, A H H AH Chang
In one-photon dissociation of gaseous acetyl chloride at 248 nm, time-resolved Fourier-transform infrared emission spectroscopy is used to detect the fragments of HCl, CO, and CH(2) in the presence of...Read More
Jacob J Bart, Ard J AJ Kolkman, Anna Jo AJ Oosthoek-de Vries, Kaspar K Koch, Pieter J PJ Nieuwland, Hans J W G HJ Janssen, Jan P J M JP van Bentum, Kirsten A M KA Ampt, Floris P J T FP Rutjes, Sybren S SS Wijmenga, Han J G E HJ Gardeniers, Arno P M AP Ken
A microfluidic high-resolution NMR flow probe based on a novel stripline detector chip is demonstrated. This tool is invaluable for the in situ monitoring of reactions performed in microreactors. As a...Read More
Takuya Arai, Ming-Rong Zhang, Masanao Ogawa, Toshimitsu Fukumura, Koichi Kato, Kazutoshi Suzuki
[1-^1^1C]Acetyl chloride ([^1^1C]AcCl), an important [^1^1C]acylating agent, was synthesized by reacting [^1^1C]CO"2 with methylmagnesium bromide coated on the inner surface of a polyethylene loo...Read More
Ernesto J EJ Méndez Antolín, Víctor L VL González Canavaciolo, Roxana R Sierra Pérez
A new validated gas chromatographic (GC) method using acetyl chloride as a derivatizing agent for determining policosanol's high molecular weight alcohols (policosanol's fatty alcohols; PFAs...Read More
Pallavi P Sethi, Amar A Jyoti, Rameshwar R Singh, Ejaz E Hussain, Deepak D Sharma
Aluminium (Al) is the most abundant metal known for its neurotoxicity in humans. It gains easy access to the central nervous system under normal physiological conditions and accumulates in different b...Read More
Jennifer L JL Lapierre, Peter O PO Kosenko, Oleg I OI Lyamin, Tohru T Kodama, Lev M LM Mukhametov, Jerome M JM Siegel
Fur seals are unique in that they display both bilateral slow-wave sleep (BSWS), as seen in all terrestrial mammals, and slow-wave sleep with interhemispheric electroencephalogram (EEG) asymmetry, res...Read More
Gerhard G Bringmann, Torsten F TF Noll, Tanja T Gulder, Michael M Dreyer, Matthias M Grüne, Detlef D Moskau
The biosynthesis of knipholone, as an axially chiral phenylanthraquinone, in higher plants was examined by feeding experiments with [13C2]-labeled precursors. [13C2]-Acetate and advanced synthetic int...Read More
Le-Ling LL Gan, Min-Wei MW Wang, Mao-Sheng MS Cheng, Li L Pan
In this paper we evaluated the bronchodilator effects of SPFF [2-(4-amino-3-chloro-5-trifluomethyl-phenyl)-2-tert-butylamino-ethanol chloride], a newly synthesized beta(2) adrenergic agonist in guinea...Read More
Sophon S Roengsumran, Nattaya N Ngamrojnavanich, Nongnuj N Jaiboon, Santi S Tungprapa, Narongsak N Chaichit, Amorn A Petsom
We're sorry this abstract is currently not available....Read More
Puja Kumari, C R K Reddy, Bhavanath Jha
A comparative evaluation of Bligh and Dyer, Folch, and Cequier-Sánchez methods for quantitative determination of total lipids (TLs) and fatty acids (FAs) was accomplished in selective green (Ulva fas...Read More
Jennifer L Frahm, Ibrahim D Bori, Daniel L Comins, Adam M Hawkridge, David C Muddimana
The wide range of protein concentrations found in biological matrixes presents a formidable analytical challenge in proteomics experiments. It is predicted that low-abundance proteins are the likely c...Read More
Tetsuji T Yamashita, Tadashi T Isa
Nicotinic acetylcholine receptors (nAChRs) exhibit high Ca(2+) permeabilities and the Ca(2+)-influx through the nAChRs may be involved in regulation of a variety of signal processing in the postsynapt...Read More
Gerhard Hobe, Renate Sch?n, Nikolai Goncharov, Gulnara Katsiya, Mikhail Koryakin, Isabelle Gesson-Cholat, Michael Oettel, Holger Zimmermann
17Alpha-estradiol (1,3,5(10)-estratriene-3,17alpha-diol) together with a tracer dose of the tritium-labeled compound was administered orally and sublingually to male volunteers. The serum concentratio...Read More