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N-乙酰-D-苯丙氨酸

产品编号 A109364 | CAS号 10172-89-1 | 阿拉丁
N-Acetyl-D-Phenylalanine
98%
组合的产品项目
货号 规格 库存 价格 数量
A109364-100g 98% 上海(预计3-5个工作日)
北方(预计3-5个工作日)
 
A109364-1g 98% 上海(>10)
北方(预计3-5个工作日)
 
A109364-25g 98% 上海(预计3-5个工作日)
北方(预计3-5个工作日)
 
A109364-5g 98% 上海(5)
北方(预计3-5个工作日)
 
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属性

旋光率 -41 ° (C=5, MeOH)
密度 1.1990
熔点 171-173°C
存贮条件 储存温度-20°C

描述

别名 N-乙酰-D-苯丙氨酸;
应用 手性化工原料和医药中间体
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个人防护设备 Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
WGK德国 3
参考文献
Jennifer A Cummings, Alexander A Fedorov, Chengfu Xu, Shoshana Brown, Elena Fedorov, Patricia C Babbitt, Steven C Almo, Frank M Raushel
The catalytic activities of three members of the amidohydrolase superfamily were discovered using amino acid substrate libraries. Bb3285 from Bordetella bronchiseptica, Gox1177 from Gluconobacter oxid...Read More
Y C Tsai, C P Tseng, K M Hsiao, L Y Chen
A d-aminoacylase-producing microorganism, strain DA181, isolated from soil was identified as Alcaligenes denitrificans subsp. denitrificans. This strain produced about 29,300 units (micromoles of prod...Read More
Jennifer M Alexander, Joanna L Clark, Tom J Brett, John J Stezowski
In a systematic study of molecular recognition of amino acid derivatives in solid-state beta-cyclodextrin (beta-CD) complexes, we have determined crystal structures for complexes of beta-cyclodextrin/...Read More
Geok-Yong Yow, Takuma Uo, Tohru Yoshimura, Nobuyoshi Esaki
Saccharomyces cerevisiae is sensitive to D-amino acids: those corresponding to almost all proteinous L-amino acids inhibit the growth of yeast even at low concentrations (e.g. 0.1 mM). We have determi...Read More
Akitaka A Ito, Shoji S Ishizaka, Noboru N Kitamura
A novel ratiometric fluorescent sensor 1 having the 4-(N,N-dimethylamino)benzoate (DMAB) group as a twisted intramolecular charge transfer (TICT) dual fluorescence site and the guanidinium group as a ...Read More
Edward A Lemke
Studies of protein structure and function using single-molecule fluorescence resonance energy transfer (smFRET) benefit dramatically from the ability to site-specifically label proteins with small flu...Read More
Emilio J EJ Cocinero, Pierre P ?ar?abal, Timothy D TD Vaden, Benjamin G BG Davis, John P JP Simons
The physical basis of carbohydrate-peptide interactions has been explored by probing the structures of a series of complexes generated in a solvent-free environment under molecular beam conditions. A ...Read More
Nada N Dosli?, Goran G Kovacevi?, Ivan I Ljubi?
An extensive computational study of the conformational preferences of N-acetylphenylalaninylamide (NAPA) is reported, including conformational and anharmonic frequency analyses, as well as calculation...Read More
Youngjin Y Choi, Seunho S Jung
Molecular dynamics (MD) simulations were performed for the prediction of chiral discrimination of N-acetylphenylalanine enantiomers by cyclomaltoheptaose (@b-cyclodextrin, @b-CD). Binding free energie...Read More
Magnus M St?deman, Frederick P FP Schwarz
The rates of the hydrolysis of N-acetylglycine, N-acetyl-l-methionine, and N-acetyl-l-phenylalanine by porcine acylase I in 0.1M phosphate buffer, which is inhibited by acetate product formation, were...Read More
Lei L Wang, Zhiwen Z Zhang, Ansgar A Brock, Peter G PG Schultz
Although the keto group is the most versatile of the functional groups in organic chemistry, it is absent in the genetically encoded amino acids. To overcome this natural limitation on protein biosynt...Read More
Laura Siracusa, Fionn M Hurley, Stefan Dresen, Laurence J Lawless, M Nieves Pérez-Payán, Anthony P Davis
[reaction: see text] Cholic acid has been elaborated into three regioisomeric bis-carbamoylureas, which have been investigated as enantioselective receptors for N-acetyl phenylalanine. L/D selectiviti...Read More
Sanghoo Lee, Seunho Jung
Cyclosophoraoses (cyclic-(1-->2)-beta-D-glucans) produced by Rhizobium meliloti were used as a novel chiral NMR solvating agent. 13C NMR spectroscopic analysis as an enantiodiscriminating tool was ...Read More
D Meredith, C S Temple, N Guha, C J Sword, C A Boyd, I D Collier, K M Morgan, P D Bailey
The binding affinities of a number of amino-acid and peptide derivatives by the mammalian intestinal peptide transporter PepT1 were investigated, using the Xenopus laevis expression system. A series o...Read More
R R Hirschmann, A B AB Smith, C M CM Taylor, P A PA Benkovic, S D SD Taylor, K M KM Yager, P A PA Sprengeler, S J SJ Benkovic
Monoclonal antibodies, induced with a phosphonate diester hapten, catalyzed the coupling of p-nitrophenyl esters of N-acetyl valine, leucine, and phenylalanine with tryptophan amide to form the corres...Read More
E Jellum, L Horn, O Thoresen, E A Kvittingen, O Stokke
Urinary organic acid profiles of patients with Maple Syrup Urine Disease (MSUD), hereditary tyrosinemia and phenylketonuria (PKU) have been studied by means of capillary GC-MS-computer technique. In a...Read More
K Y KY Xu
A combination of competitive labeling with [3H]acetic anhydride [Kaplan, H., Stevenson, K. J., & Hartley, B. S. (1971) Biochem. J. 124, 289-299] and immunoaffinity chromatography is described that...Read More
J C JC Lacey, R D RD Thomas, M P MP Staves, C L CL Watkins
In the biosynthesis of proteins, each amino acid passes from the aminoacyl adenylate to become an amino acid ester and finally a 2' (3') peptidyl ester of the AMP residue at the end of a tRN...Read More
Anton V AV Yakovenko, Vyacheslav I VI Boyko, Vitaly I VI Kalchenko, Laura L Baldini, Alessandro A Casnati, Francesco F Sansone, Rocco R Ungaro
Bisurea calix[4]arenes 1 and 2 possessing L-amino acid moieties at the lower rim were synthesized by reaction of the methyl esters of glycine, L-alanine, or L-isoleucine with the appropriate isocyanat...Read More
Christine Hellriegel, Urban Skogsberg, Klaus Albert, Michael L?¤mmerhofer, Norbert M Maier, Wolfgang Lindner
The surface chemistry of a chiral stationary phase (CSP) with a (tert-butyl carbamoyl) quinine selector immobilized on thiol-modified silica has been characterized by (1)H HR/MAS NMR and (29)Si CP/MAS...Read More
Sanghoo Lee, Seunho Jung
Cyclosophoraoses, cyclic beta-(1-->2)-D-glucans produced by Rhizobium meliloti 2011, were used as a novel chiral additive for the separation of terbutaline, amethopterin, thyroxine and N-acetylphen...Read More
J K JK Park, S J SJ Cho, S S Lee, K S KS Kim, D H DH Kim
Because of the complexity involved in binding of a ligand to an enzyme the conformational preference of the bound ligand has not been well understood yet. We have examined the conformational energies ...Read More
K Okajima, M Inoue, Y Morino
To elucidate the mechanism and biologic significance of urinary occurrence of N-acetylphenylalanine in phenylketonuria, the metabolic fate of N-acetylphenylalanine was studied in rats. In vivo and in ...Read More
Magnus M St?deman, Frederick P FP Schwarz
The hydrolysis of N-acetyl-L-methionine, N-acetylglycine, N-acetyl-L-phenylalanine, and N-acetyl-L-alanine at 298.35K by porcine kidney acylase I (EC 3.5.1.14) was monitored by the heat released upon ...Read More