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丙酮肟

产品编号 A112746 | CAS号 127-06-0 | 阿拉丁
Acetoxime
98%
组合的产品项目
货号 规格 库存 价格 数量
A112746-100g 98% 上海(>10)
北方(预计3-5个工作日)
 
A112746-25g 98% 上海(>10)
北方(>10)
 
A112746-500g 98% 上海(9)
北方(预计3-5个工作日)
 
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属性

折光率 1.4156
密度 0.9010
熔点 60°C
沸点 134.8°C
存贮条件 密封阴凉干燥保存。

描述

产品介绍 有似水合氯醛气味。对湿敏感。在中挥发很快。中性反应。 易溶于水、乙醇、乙醚、石油醚。在稀酸中易水解。半数致死量(小鼠,腹腔)4000mg/kg。水溶性:320g/l(21℃),易溶于醇、醚、酮、烃等有机溶剂。
别名 2-丙酮肟;二甲基酮肟;Acetone oxime; 2-Propanone oxime
应用 检验钴的试剂,有机合成,新型锅炉水除氧剂,医药、农药中间体等。
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安全声明(欧洲) S22;S24/25;
个人防护设备 Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter
RTECS AL6825000
WGK德国 3
参考文献
Stefanie S Zorbas-Seifried, Michael A MA Jakupec, Nikolay V NV Kukushkin, Michael M Groessl, Christian G CG Hartinger, Olga O Semenova, Haralabos H Zorbas, Vadim Yu VY Kukushkin, Bernhard K BK Keppler
The presence of cis-configured exchangeable ligands has long been considered a prerequisite for antitumor activity of platinum complexes, but over the past few years, several examples violating this s...Read More
A A AA Caro, A I AI Cederbaum, D A DA Stoyanovsky
Ketoximes undergo a cytochrome P450-catalyzed oxidation to nitric oxide and ketones in liver microsomes. In addition, nitric oxide synthase (NOS) can catalyze the oxidative denitration of the >C@?N...Read More
P Kreis, S Brandner, M W Coughtrie, U Pabel, W Meinl, H Glatt, U Andrae
The industrial solvent 2-nitropropane (2-NP) is a genotoxic hepatocarcinogen in rats. The genotoxicity of the compound in rats has been attributed to sulfotransferase-mediated formation of DNA-reactiv...Read More
W W V?lkel, N N Wolf, M M Derelanko, W W Dekant
Acetoxime and methylethyl ketoxime (MEKO) are tumorigenic in rodents, inducing liver tumors in male animals. The mechanisms of tumorigenicity for these compounds are not well defined. Oxidation of the...Read More
M M Rysková, K K Chroust, M M Trbusek, J J Benedík, T T Jowett
The genotoxic effects of N-nitroso-N-methylurea (MNU) and acetone oxime (ACOX) were tested in the Somatic Mutation and Recombination Test (SMART) in Drosophila melanogaster. We have performed the same...Read More
U S US Ryan, R R Zhong, B A BA Hayes, G G Visner, M L ML Sauther
Calcium phosphate precipitation and retrovirus-mediated infection methods were used to stably infect bovine pulmonary artery endothelial cells (BPAECs) with mammalian expression vectors bearing human ...Read More
S S SS Mirvish, S S Salmasi, R G RG Runge
Acetoxime was tested for carcinogenicity by chronic administration in the drinking water to male and female outbred MRC-Wistar rats. The dose of 1.0 g/liter was administered 5 days/week for 18 months ...Read More
N N Guo, C C CC Conaway, N S NS Hussain, E S ES Fiala
The hepatocarcinogens 2-nitropropane and acetoxime have previously been found to induce a specific and qualitatively identical pattern of base damage in rat liver DNA and RNA, including the induction ...Read More
C C Kohl, C D CD Schiller, A A Gescher, P B PB Farmer, E E Bailey
The hepatocarcinogenicity of acetoxime has been tentatively linked with its metabolic oxidation to the potent genotoxicant and carcinogen propane 2-nitronate (P2-N). In order to test the hypothesis th...Read More
R S RS Sodum, E S ES Fiala
Previously, the secondary nitroalkane 2-nitropropane, a strong hepatocarcinogen in rats, had been shown to induce the formation of 8-aminoguanine in both DNA and RNA of rat liver through a sulfotransf...Read More
J J Torreilles, M C MC Guérin, D D Dussossoy, A A Crastes de Paulet
Preparation of adducts from nicotinamide adenine dinucleotide and a number of oximes is described; these include acetoxime, pyruvatoxime, cyclohexanoxime, cyclopentanoxime. These adducts are closely r...Read More
N S NS Hussain, C C CC Conaway, N N Guo, W W Asaad, E S ES Fiala
Acetoxime (ACO) and 2-nitropropane (2-NP), both industrially important chemicals and known hepatocarcinogens in rats, induced increased levels of 8-hydroxy-guanine in liver DNA and RNA of male Sprague...Read More