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二异丁基氢化铝

¥ 149.00

产品编号 D107997 | CAS号 1191-15-7 | 阿拉丁
Diisobutylaluminum hydride
1.0 M 已烷溶液
组合的产品项目
货号 规格 库存 价格 数量
D107997-100ml 1.0 M 已烷溶液 上海(>10)
北方(预计3-5个工作日)
 
D107997-1l 1.0 M 已烷溶液 上海(预计3-7周)
北方(预计3-7周)
 
D107997-25ml 1.0 M 已烷溶液 上海(>10)
北方(预计3-5个工作日)
 
D107997-500ml 1.0 M 已烷溶液 上海(1)
北方(预计3-5个工作日)
 
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属性

敏感性 易吸潮
密度 0.7010
沸点 116-118°C
存贮条件 充氩保存

描述

别名 DIBAL-H;DIBAL;DIBAL-H;DIBAL
应用 Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.
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标识符号 GHS02 GHS02, GHS05 GHS05, GHS07 GHS07, GHS08 GHS08, GHS09 GHS09
信号词 Danger
风险声明 (欧洲) R17;R35;R14/15
安全声明(欧洲) S16;S26;S36/37/39;S43;S45
警示性声明 P210,P222,P231+P232,P261,P273,P422
危害码(欧洲) F,C
危害声明 H225,H250,H261,H304,H314,H336,H410
个人防护设备 Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
WGK德国 NWG
闪点(摄氏) -18 °C
是否危化品 一般危险品
参考文献
Kenji K Sugimoto
Domino reactions, which enable formations of several chemical bonds and multi-step transformation in one-pot process, have received much attention as an efficient synthetic methodology to preserve che...Read More
Damien D Webb, Timothy F TF Jamison
A continuous flow system for the multiparameter (flow rate, temperature, residence time, stoichiometry) optimization of the DIBALH reduction of esters to aldehydes is described. Incorporating an in-li...Read More
Ramprasad R Ghosh, Ping P Zhang, Aixia A Wang, Chang-Chun CC Ling
We're sorry this abstract is currently not available....Read More
Takashi Tomioka, Yuki Yabe, Tohru Takahashi, Tracy K Simmons
Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by the Horner-Emmons reaction effectively provided desymmetrized hydroxy mono-olefination products in a...Read More
Kenji Shirokane, Yusuke Kurosaki, Takaaki Sato, Noritaka Chida
We're sorry this abstract is currently not available....Read More
Hidetsura H Cho, Yusuke Y Iwama, Kenji K Sugimoto, Seiji S Mori, Hidetoshi H Tokuyama
A systematic investigation of the reductive ring-expansion reaction of cyclic ketoximes fused to aromatic rings with diisobutylaluminum hydride (DIBALH) is described. This reaction regioselectively af...Read More
Nobuo N Tanaka, Izumi I Ogawa, Shigeki S Yoshigase, Junzo J Nokami
We're sorry this abstract is currently not available....Read More
Hideki H Ishii, Sergei V SV Dzyuba, Koji K Nakanishi
The lactone rings of ginkgolide A are converted into corresponding tetrahydrofuran moieties via DIBAL-H reduction followed by deoxygenation of the formed lactols with Et3SiH-BF3.Et2O to produce a seri...Read More
Thomas Lecourt, Alexandre Herault, Alan J Pearce, Matthieu Sollogoub, Pierre Sina??
To explain the remarkable regioselective de-O-benzylating properties of diisobutylaluminium hydride (DIBAL-H) and triisobutylaluminium (TIBAL) towards polybenzylated sugars or cyclodextrins, we propos...Read More
V V Constantinou-Kokotou, V V Magrioti, T T Markidis, G G Kokotos
A general method for the synthesis of enantiopure non-natural alpha-amino acids is described. The key intermediate tert-butyl (2S)-2-[bis(tert-butoxycarbonyl)amino]-5-oxopentanoate was obtained from l...Read More
K K Hirota, Y Y Monguchi, M M Sako, Y Y Kitade
It is reported that the diisobutylaluminum hydride (DIBALH) reduction of inosine and adenosine derivatives (1a and 1d) causes cleavage of the ribose moiety to give the corresponding 9-ribitylhypoxanth...Read More
Z Y Liu, X R Wu
We're sorry this abstract is currently not available....Read More
Y Y Kitade, K K Hirota, Y Y Maki
Reaction of purine nucleosides, such as 2',3'-isopropylideneinosine (1a) and 2',3'-isopropylideneadenosine (1c), with diisobutylaluminum hydride (DIBAL) in dry tetrahydrofurane res...Read More
Nora Heinrich, Anthony C Willis, Ian A Cade, Junming Ho, Michelle L Coote, Martin G Banwell
Opening and closing a chemical window: oxidation of the etheno-bridged [4.3.1]propelladienol 1 with pyridinium chlorochromate (PCC) affords oxa[5.6.5.6]fenestratetraene 2. The reduction of 2 with diis...Read More
Kevin W Hunt, Paul A Grieco
[reaction: see text] An efficient strategy for transforming meso-oxabicyclo[3.2.1]octenone 1 into optically active intermediates for macrolide synthesis has been developed. The direct bridgehead openi...Read More
J Marco-Contelles, J Ruiz-Caro
We're sorry this abstract is currently not available....Read More

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