|应用||Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.|
|标识符号||GHS02, GHS05, GHS07, GHS08|
Domino reactions, which enable formations of several chemical bonds and multi-step transformation in...Read More
Diisobutylaluminum hydride reductions revitalized: a fast, robust, and selective continuous flow system for aldehyde synthesis.
A continuous flow system for the multiparameter (flow rate, temperature, residence time, stoichiomet...Read More
Diisobutylaluminum hydride mediated regioselective O desilylations: access to multisubstituted cyclodextrins.
DIBAL-mediated reductive transformation of trans-dimethyl tartrate acetonide into ε-hydroxy α,β-unsaturated ester and its derivatives.
Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by ...Read More
Regioselective synthesis of heterocycles containing nitrogen neighboring an aromatic ring by reductive ring expansion using diisobutylaluminum hydride and studies on the reaction mechanism.
A systematic investigation of the reductive ring-expansion reaction of cyclic ketoximes fused to aro...Read More
Regioselective ring opening of benzylidene acetal protecting group(s) of hexopyranoside derivatives by DIBAL-H
The lactone rings of ginkgolide A are converted into corresponding tetrahydrofuran moieties via DIBA...Read More
Triisobutylaluminium and diisobutylaluminium hydride as molecular scalpels: the regioselective stripping of perbenzylated sugars and cyclodextrins.
To explain the remarkable regioselective de-O-benzylating properties of diisobutylaluminium hydride ...Read More
Synthesis of enantiopure non-natural alpha-amino acids using tert-butyl (2S)-2-[bis-(tert-butoxycarbonyl)amino]-5-oxopentanoate as key-intermediate:the first synthesis of(S)-2-amino-oleic acid.
A general method for the synthesis of enantiopure non-natural alpha-amino acids is described. The ke...Read More
It is reported that the diisobutylaluminum hydride (DIBALH) reduction of inosine and adenosine deriv...Read More
Facile reductive cleavage of purine nucleosides to acyclonucleosides using diisobutylaluminium hydride (DIBAL): a new synthetic method for the preparation of 9-ribitylpurine derivatives.
Reaction of purine nucleosides, such as 2',3'-isopropylideneinosine (1a) and 2',3...Read More
Reversible cyclopropane ring-cleavage reactions within etheno-bridged [4.3.1]propelladiene frameworks leading to aza- and oxa-[188.8.131.52]fenestratetraenes.
Opening and closing a chemical window: oxidation of the etheno-bridged [4.3.1]propelladienol 1 with ...Read More
Oxabicyclo[3.2.1]octenes in organic synthesis: direct ring opening of oxabicyclo[3.2.1] ring systems with diisobutylaluminum hydride and a silyl ketene acetal--synthesis of the chiral C(19)-C(26) and C(27)-C(32) fragments of Scytophycin C.
[reaction: see text] An efficient strategy for transforming meso-oxabicyclo[3.2.1]octenone 1 into op...Read More