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氢化铝锂

产品编号 L130047 | CAS号 16853-85-3 | 阿拉丁
Lithium Aluminium Hydride
2.5 M四氢呋喃溶液
组合的产品项目
货号 规格 库存 价格 数量
L130047-100ml 2.5 M四氢呋喃溶液 上海(1)
北方(预计3-5个工作日)
 
L130047-1l 2.5 M四氢呋喃溶液 上海(预计3-7周)
北方(预计3-7周)
 
L130047-500ml 2.5 M四氢呋喃溶液 上海(预计3-7周)
北方(预计3-7周)
 
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属性

敏感性 对空气和水分敏感
密度 0.9000
存贮条件 充氩储存

描述

产品介绍 Lithium aluminum hydride can be used as a reactant or a reagent for a variety of experiments. For instance, it has been used for the preparation of thermoplastic polyester polyamides from oleic acid, Lithium-polymer batteries, hydrodefluorination of gem-difluoromethylene derivatives, asymmetric aldol reactions and synthesis of Li-Al-N-H composites with hydrogen absorption/ desorption properties. Additionally, Lithium aluminum hydride is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols.
别名 四氢铝锂;四氢锂铝;四氢化锂铝;氢化锂铝;LAH; Lithium alanate; Lithium tetrahydroaluminate; Lithium tetrahydridoaluminate
应用 Reactant or reagent for:
&bull The preparation of thermoplastic polyester polyamides from oleic acid
&bull Lithium-polymer batteries
&bull Hydrodefluorination of gem-difluoromethylene derivatives
&bull Asymmetric aldol reactions
&bull Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
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标识符号 GHS02 GHS02, GHS05 GHS05, GHS07 GHS07
信号词 Danger
风险声明 (欧洲) R11;R15;R19;R34;R37
安全声明(欧洲) S16;S26;S36/37/39;S43;S45
警示性声明 P210,P223,P231+P232,P261,P370+P378,P422
危害码(欧洲) F,C
危害声明 H225,H260,H314,H335
个人防护设备 Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
WGK德国 1
是否危化品 一般危险品
参考文献
Seiji Takeda, Shu-Ping Hui, Hirotoshi Fuda, Shigeki Jin, Toshihiro Sakurai, Atsushi Ishii, Koichi Mukasa, Kazuhisa Sueoka, Hitoshi Chiba
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode mate...Read More
Carlo Cassani, Rafael Martín-Rapún, Elena Arceo, Fernando Bravo, Paolo Melchiorre
We describe two procedures for the synthesis of primary amines derived from 9-amino(9-deoxy)epi cinchona alkaloids, valuable catalysts used in the asymmetric functionalization of carbonyl compounds. T...Read More
Hao H Yao, Shigehito S Isobe, Yongming Y Wang, Naoyuki N Hashimoto, Somei S Ohnuki
A plastic bag method was developed to observe air-sensitive samples on microstructure and phase distribution without exposure to air during the holder transfer process into the transmission electron m...Read More
Sonja Stankovi?, Matthias D'hooghe, Norbert De Kimpe
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corres...Read More
Frédéric F Hild, Pierre P Haquette, Lydia L Brelot, Samuel S Dagorne
The tridentate proligands (RNH-o-C6H4)2O (1a, R = C5H9; 1b, R = Cy) were found to readily react with LiAlH4 to yield the corresponding lithium aluminium dihydrido salt species [eta(2)-N,N-{(RN-o-C6H4)...Read More
Krishnananda K Samanta, Bandana B Chakravarti, Jitendra Kumar JK Mishra, Shailendra Kumar Dhar SK Dwivedi, Lakshma Vadithe LV Nayak, Preeti P Choudhry, Hemant Kumar HK Bid, Rituraj R Konwar, Naibedya N Chattopadhyay, Gautam G Panda
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reductio...Read More
Byung-Hoon Jeong, Nam-Ho Kim, Jae-Kwang Jin, Jin-Kyu Choi, Yun-Jung Lee, Jae-Il Kim, Eun-Kyoung Choi, Richard I Carp, Yong-Sun Kim
Previous studies indicate that RNA may be required for proteinase-resistant prion protein (PrP) amplification and for infectious prion formation in vitro, suggesting that RNA molecules may function as...Read More
Andreas Grubelnik, Luzia Wiesli, Patrick Furrer, Daniel Rentsch, Roland Hany, Veronika R Meyer
Bacterial poly(hydroxyalkanoates) (PHAs) vary in the composition of their monomeric units. Besides saturated side-chains, unsaturated ones can also be found. The latter leads to unwanted by-products (...Read More
Matthias M D'hooghe, Stijn S Dekeukeleire, Norbert N De Kimpe
The reactivity of 4-aryl-1-(2-chloroethyl)azetidin-2-ones and 4-aryl-1-(3-bromopropyl)azetidin-2-ones with regard to lithium aluminium hydride has been evaluated for the first time. 4-Aryl-1-(2-chloro...Read More
M Brett MB Runge, Martin T MT Mwangi, A Lee AL Miller, Mathew M Perring, Ned B NB Bowden
We're sorry this abstract is currently not available....Read More
José M JM Concellón, Pablo L PL Bernad, Virginia V del Solar, José Ramón JR Suárez, Santiago S García-Granda, M Rosario MR Díaz
The reaction of chiral (2R,1'S)- or (2S,1'S)-2-(1-aminoalkyl)epoxides, 1 or 2 with a variety of organolithium compounds to obtain the corresponding (alphaS,betaS)- or (alphaR,betaS)- beta-am...Read More
Jungseok Heo, Chad A Mirkin
We're sorry this abstract is currently not available....Read More
Damián E DE Bikiel, Florencia F Di Salvo, Mariano C MC González Lebrero, Fabio F Doctorovich, Darío A DA Estrin
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4...Read More
Masateru Nishihara, Hiroyuki Morii, Koji Matsuno, Mami Ohga, Karl O Stetter, Yosuke Koga
A choline-containing phospholipid (PL-4) in Methanopyrus kandleri cells was identified as archaetidylcholine, which has been described by Sprott et al. (1997). The PL-4 consisted of a variety of molec...Read More
Hideki H Hashizume, Sehei S Hirosawa, Ryuichi R Sawa, Yasuhiko Y Muraoka, Daishiro D Ikeda, Hiroshi H Naganawa, Masayuki M Igarashi
Planar structures of tripropeptins (TPPs) were elucidated by spectroscopic studies including various NMR measurements. Stereochemistry of constituent amino acids of tripropeptin C (TPPC) (3) was ident...Read More
I-Chi IC Lee, Medel Manuel L MM Zulueta, Chi-Rung CR Shie, Susan D SD Arco, Shang-Cheng SC Hung
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereosel...Read More
Meganne M Christian, Kondo-Francois KF Aguey-Zinsou
Nanoparticles of NaAlH4, LiAlH4 and LiBH4 were prepared by encapsulating their respective hydrides within carbon nanotubes by a wet chemical approach. The resulting confinement had a profound effect o...Read More
Matthias D'hooghe, Karen Mollet, Stijn Dekeukeleire, Norbert De Kimpe
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the correspondin...Read More
Greg G Hughes, Paul N PN Devine, John R JR Naber, Paul D PD O'shea, Bruce S BS Foster, Daniel J DJ McKay, R P RP Volante
We're sorry this abstract is currently not available....Read More
D A DA Stringfellow
Prostaglandins enhanced the interferon response and therapeutic activity of interferon inducers in Friend leukemia virus-infected mice. A similar enhancement in interfron responsiveness but not antivi...Read More
Takashi Ikegami, Woo-Sang Lee, Hiroyuki Nariai, Toshifumi Takeuchi
Bisphenol A (BPA) recognition materials were synthesized by a covalent imprinting technique using BPA-dimethacrylate or BPA-diacrylate as the template monomer. Binding sites in the polymers consisted ...Read More
Haruki Sashida, Kazuo Ohyanagi
The reactions of the 2-benzoselenopyrylium (1A) and 2-benzotelluropyrylium cations (1B) with a variety of nucleophiles have been investigated. LiAlH(4), sodium alkoxide (NaOMe, NaOi-Pr and NaOt-Bu), d...Read More
Vito Capriati, Saverio Florio, Renzo Luisi, Antonio Salomone
[reaction: see text] The stereospecific alpha-lithiation of optically active styrene oxides and the trapping reaction of the corresponding highly reactive intermediates with electrophiles to produce o...Read More
Shinya Tachibana, Takashi Gotou, Masato Nomura
The synthesis and physiological activity of thiophenes and furans with methoxyacetophenone derivatives were examined. 3-Methoxyacetophenone (1) and 4-methoxyacetophenone (2) were converted, respective...Read More

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