产品编号 L130047 | CAS号 16853-85-3 | 阿拉丁
Lithium Aluminium Hydride
2.5 M四氢呋喃溶液
货号 规格 库存 价格 数量
L130047-100ml 2.5 M四氢呋喃溶液 上海(1)
L130047-1l 2.5 M四氢呋喃溶液 上海(预计3-7周)
L130047-500ml 2.5 M四氢呋喃溶液 上海(预计3-7周)


敏感性 对空气和水分敏感
密度 0.9000
存贮条件 充氩储存


产品介绍 Lithium aluminum hydride can be used as a reactant or a reagent for a variety of experiments. For instance, it has been used for the preparation of thermoplastic polyester polyamides from oleic acid, Lithium-polymer batteries, hydrodefluorination of gem-difluoromethylene derivatives, asymmetric aldol reactions and synthesis of Li-Al-N-H composites with hydrogen absorption/ desorption properties. Additionally, Lithium aluminum hydride is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols.
别名 四氢铝锂;四氢锂铝;四氢化锂铝;氢化锂铝;LAH; Lithium alanate; Lithium tetrahydroaluminate; Lithium tetrahydridoaluminate
应用 Reactant or reagent for:
&bull The preparation of thermoplastic polyester polyamides from oleic acid
&bull Lithium-polymer batteries
&bull Hydrodefluorination of gem-difluoromethylene derivatives
&bull Asymmetric aldol reactions
&bull Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties
LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols
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标识符号 GHS02 GHS02, GHS05 GHS05, GHS07 GHS07
信号词 Danger
风险声明 (欧洲) R11;R15;R19;R34;R37
安全声明(欧洲) S16;S26;S36/37/39;S43;S45
警示性声明 P210,P223,P231+P232,P261,P370+P378,P422
危害码(欧洲) F,C
危害声明 H225,H260,H314,H335
个人防护设备 Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
WGK德国 1
是否危化品 一般危险品
Seiji Takeda, Shu-Ping Hui, Hirotoshi Fuda, Shigeki Jin, Toshihiro Sakurai, Atsushi Ishii, Koichi Mukasa, Kazuhisa Sueoka, Hitoshi Chiba
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode mate...Read More
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We describe two procedures for the synthesis of primary amines derived from 9-amino(9-deoxy)epi cinchona alkaloids, valuable catalysts used in the asymmetric functionalization of carbonyl compounds. T...Read More
Hao H Yao, Shigehito S Isobe, Yongming Y Wang, Naoyuki N Hashimoto, Somei S Ohnuki
A plastic bag method was developed to observe air-sensitive samples on microstructure and phase distribution without exposure to air during the holder transfer process into the transmission electron m...Read More
Sonja Stankovi?, Matthias D'hooghe, Norbert De Kimpe
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corres...Read More
Frédéric F Hild, Pierre P Haquette, Lydia L Brelot, Samuel S Dagorne
The tridentate proligands (RNH-o-C6H4)2O (1a, R = C5H9; 1b, R = Cy) were found to readily react with LiAlH4 to yield the corresponding lithium aluminium dihydrido salt species [eta(2)-N,N-{(RN-o-C6H4)...Read More
Krishnananda K Samanta, Bandana B Chakravarti, Jitendra Kumar JK Mishra, Shailendra Kumar Dhar SK Dwivedi, Lakshma Vadithe LV Nayak, Preeti P Choudhry, Hemant Kumar HK Bid, Rituraj R Konwar, Naibedya N Chattopadhyay, Gautam G Panda
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reductio...Read More
Byung-Hoon Jeong, Nam-Ho Kim, Jae-Kwang Jin, Jin-Kyu Choi, Yun-Jung Lee, Jae-Il Kim, Eun-Kyoung Choi, Richard I Carp, Yong-Sun Kim
Previous studies indicate that RNA may be required for proteinase-resistant prion protein (PrP) amplification and for infectious prion formation in vitro, suggesting that RNA molecules may function as...Read More
Andreas Grubelnik, Luzia Wiesli, Patrick Furrer, Daniel Rentsch, Roland Hany, Veronika R Meyer
Bacterial poly(hydroxyalkanoates) (PHAs) vary in the composition of their monomeric units. Besides saturated side-chains, unsaturated ones can also be found. The latter leads to unwanted by-products (...Read More
Matthias M D'hooghe, Stijn S Dekeukeleire, Norbert N De Kimpe
The reactivity of 4-aryl-1-(2-chloroethyl)azetidin-2-ones and 4-aryl-1-(3-bromopropyl)azetidin-2-ones with regard to lithium aluminium hydride has been evaluated for the first time. 4-Aryl-1-(2-chloro...Read More
M Brett MB Runge, Martin T MT Mwangi, A Lee AL Miller, Mathew M Perring, Ned B NB Bowden
We're sorry this abstract is currently not available....Read More
José M JM Concellón, Pablo L PL Bernad, Virginia V del Solar, José Ramón JR Suárez, Santiago S García-Granda, M Rosario MR Díaz
The reaction of chiral (2R,1'S)- or (2S,1'S)-2-(1-aminoalkyl)epoxides, 1 or 2 with a variety of organolithium compounds to obtain the corresponding (alphaS,betaS)- or (alphaR,betaS)- beta-am...Read More
Jungseok Heo, Chad A Mirkin
We're sorry this abstract is currently not available....Read More
Damián E DE Bikiel, Florencia F Di Salvo, Mariano C MC González Lebrero, Fabio F Doctorovich, Darío A DA Estrin
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4...Read More
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Hideki H Hashizume, Sehei S Hirosawa, Ryuichi R Sawa, Yasuhiko Y Muraoka, Daishiro D Ikeda, Hiroshi H Naganawa, Masayuki M Igarashi
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I-Chi IC Lee, Medel Manuel L MM Zulueta, Chi-Rung CR Shie, Susan D SD Arco, Shang-Cheng SC Hung
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Meganne M Christian, Kondo-Francois KF Aguey-Zinsou
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Matthias D'hooghe, Karen Mollet, Stijn Dekeukeleire, Norbert De Kimpe
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D A DA Stringfellow
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Haruki Sashida, Kazuo Ohyanagi
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Vito Capriati, Saverio Florio, Renzo Luisi, Antonio Salomone
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