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二乙二醇二甲醚

产品编号 M104417 | CAS号 111-96-6 | Aladdin
2-Methoxyethyl ether
≥99.5%(GC)
组合的产品项目
货号 规格 库存 价格 数量
M104417-2.5L ≥99.5%(GC) 上海(8)
北方(预计3-5个工作日)
 
M104417-500ml ≥99.5%(GC) 上海(>10)
北方(预计3-5个工作日)
 
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属性

敏感性 对湿度和空气敏感
折光率 1.4097
密度 0.9500
熔点 -68°C
沸点 162°C
溶解性 与水、烃类混溶。

描述

产品介绍 能与水、乙醇、乙醚和烃类溶剂混溶。
别名 二甘醇二甲醚; 双(2-甲氧基乙基)醚; 二甲基卡必醇; 2-甲氧基乙基醚;Diethyleneglycol dimethyl ether; Bis(2-methoxyethyl) ether; Diglyme; Dimethyldiglycol; 1-Methoxy-2-(2-methoxyethoxy)ethane
应用 本品为非质子极性溶剂,可用于极性有机反应,阴离子聚合、配位离子聚合反应的溶剂,可作还原烷基化和缩合等反应溶剂,还可作为格氏和类似合成的介质,也用作无污染清洗剂、萃取剂、稀释剂、医药助剂及树脂溶剂。
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标识符号 GHS02 GHS02, GHS08 GHS08
信号词 Danger
风险声明 (欧洲) R10;R19;R60;R61
安全声明(欧洲) S45;S53
警示性声明 P201,P308+P313
危害码(欧洲) T
危害声明 H226,H360
个人防护设备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter
RTECS KN3339000
WGK德国 1
Merck Index 3165
闪点(摄氏) (开杯)70℃
UN代码 3271
参考文献
Erik N K Cressman, David A Jahangir
This study aimed to investigate two readily available electrophilic reagents, acetyl chloride (AcCl), and acetic anhydride (Ac(2)O), for their potential in tissue ablation.Reagents were diluted in dig...Read More
Bruce A BA Kowert, Ann B J AB Stemmler, Timothy L TL Stemmler, Steven J SJ Gentemann, Michael B MB Watson, Vanessa S VS Goodwill
Electron spin resonance (ESR) has been used to study the reorientational motion of the bis(maleonitriledithiolato)nickel trianion, [Ni(mnt)(2)](3-), in diethylene glycol dimethyl ether (diglyme). [Ni(...Read More
Nenad N Mara?, Slovenko S Polanc, Marijan M Ko?evar
1,4-Diazabicyclo[2.2.2]octane (DABCO) has been evaluated as a starting material for the synthesis of 1-alkyl-4-(2-phenoxyethyl)piperazines and related derivatives. We found that 1-alkyl-1,4-diazabicyc...Read More
Donna J Menzies, Andrew Nelson, Hsin-Hui Shen, Keith M McLean, John S Forsythe, Thomas Gengenbach, Celesta Fong, Benjamin W Muir
Plasma-enhanced chemical vapour-deposited films of di(ethylene glycol) dimethyl ether were analysed by a combination of X-ray photoelectron spectroscopy, atomic force microscopy, quartz crystal microb...Read More
Johansson
The conformational states of diglyme in both the solid and liquid states have been determined by an integrated use of both IR and Raman spectroscopy together with ab initio/density functional theory (...Read More
R R Jolanki, K K Tarvainen, T T Tatar, T T Estlander, M L ML Henriks-Eckerman, K K KK Mustakallio, L L Kanerva
Of 22 workers in a ski factory, occupational allergic contact dermatitis was found in 8. 6 were sensitive to epoxy resin compounds, i.e., epoxy resins, hardeners or diluents, 1 to cobalt in glass-fibe...Read More
P J PJ Catalano, D O DO Scharfstein, L M LM Ryan, C A CA Kimmel, G L GL Kimmel
The purpose of this paper is to present a statistical model for analyzing the joint effects of exposure on fetal death, fetal weight, and malformation in a developmental toxicity study. In addition to...Read More
G M GM Paddle, A J AJ Osborn, G D GD Parker
A historical-prospective cohort study was conducted of 729 male employees of plants manufacturing 4,4'-bipyridyl. The cohort was studied because employment in some of the plants had been linked t...Read More
B A BA Schwetz, C J CJ Price, J D JD George, C A CA Kimmel, R E RE Morrissey, M C MC Marr
Diethylene glycol dimethyl ether (diEGdiME) and triethylene glycol dimethyl ether (triEGdiME), widely used organic solvents, are structurally related to several compounds that produce reproductive and...Read More
Adriana Valore, Elena Cariati, Stefania Righetto, Dominique Roberto, Francesca Tessore, Renato Ugo, Ignazio L Fragalà, Maria Elena Fragalà, Graziella Malandrino, Filippo De Angelis, Leonardo Belpassi, Isabelle Ledoux-Rak, Khuyen Hoang Thi, Joseph Zyss
The second-order nonlinear optical (NLO) properties of [Ln(hfac)(3)(diglyme)] (hfac = hexafluoroacetylacetonate; diglyme = bis(2-methoxyethyl)ether; Ln = La, Ce, Pr, Sm, Eu, Gd, Er, Lu) complexes have...Read More
Sven S Lammers, Markus M Meuwly
The energetics, dynamics, and infrared spectroscopy of the shared proton in different chemical environments is investigated using molecular dynamics simulations. A three-dimensional potential energy s...Read More
D D Grossmann, H H K?ser, R R Kretschmer, M M Porobin
Diglyme (CAS No. 111-96-6), a biorefractive ether with teratogenic properties is of considerable importance as a solvent in the synthetic chemical industry. Results of lab-scale investigations into th...Read More
P J PJ Catalano
Simultaneous observation of continuous and ordered categorical outcomes for each subject is common in biomedical research but multivariate analysis of the data is complicated by the multiple data type...Read More
D E Richards, K B Begley, D G DeBord, K L Cheever, W W Weigel, M A Tirmenstein, R E Savage
The metabolism of the reproductive and developmental toxicant bis(2-methoxyethyl)ether (diglyme) was studied in isolated rat hepatocytes and in the intact rat. Male Sprague-Dawley rats (190-220 g) wer...Read More
Qian Cheng, Song Li, Kyriakos Komvopoulos
Polyethylene glycol (PEG)-like films were grafted onto various substrates by plasma polymerization of diethylene glycol dimethyl ether (diglyme). Low-power diglyme plasma conditions yielded PEG-like f...Read More
Rahul V RV Pinjari, Kaustubh A KA Joshi, Shridhar P SP Gejji
Electronic structure and the vibrational spectra of CH"3(OCH"2CH"2)"2OCH"3-M^+-AsF"6^- (M=Li, Na, K) have been obtained using the density functional theory. Lithium ion e...Read More
Martin M Schulz-Dobrick, K Vijaya KV Sarathy, Martin M Jansen
A new, facile and generally applicable synthesis of functionalized gold nanoparticles is presented. It is based on the surfactant-free generation of weakly stabilized nanoparticles by the reduction of...Read More
Louise E LE Cullen, Craig C Macfarlane
The Jayme-Wise and diglyme-HCl methods for extracting cellulose from plant material for stable-isotope analysis differ considerably in ease of use, with the latter requiring significantly less time an...Read More
Kikuko K Hayamizu, William S WS Price
Pulsed gradient spin-echo (PGSE) NMR measurements of the self-diffusion coefficients of low viscosity liquids are greatly hampered by the effects of convection especially away from ambient temperature...Read More
R R Valentine, A J AJ O'Neill, K P KP Lee, G L GL Kennedy
Diglyme [1,1'-oxybis(2-methoxyethane)] is an organic solvent belonging to the glycol ether class of compounds. To assess the inhalation toxicity of diglyme, groups of 20 male and 10 female rats w...Read More
C D CD Driscoll, R R Valentine, R E RE Staples, N C NC Chromey, G L GL Kennedy
Diglyme (Diethylene glycol dimethyl ether, CAS No. 111-96-6) is a glycol ether which has been used in solvent formulations. To assess the potential developmental toxicity of this chemical, groups of p...Read More
M M Corn, R R Cohen
Real-time mass spectroscopy (ICAMS) can provide hourly or daily estimates of employee exposure. Field calibration of the unit indicated essentially linear response from 0.01 (Cellosolve Acetate) and 0...Read More
Shashank S Mishra, Stéphane S Daniele, Gilles G Ledoux, Erwann E Jeanneau, Marie-France MF Joubert
We report synthesis of new single-source heterometallic precursors [NaLn(TFA)(4)(diglyme)] (Ln = Y, Er, Tm, Yb; TFA = trifluoroacetate), which decompose in 1-octadecene at significantly low temperatur...Read More

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