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氯化钯

¥ 198.00

产品编号 P105196 | CAS号 7647-10-1 | Aladdin
Palladium chloride
Pd 59-60%
组合的产品项目
货号 规格 库存 价格 数量
P105196-1g Pd 59-60% 上海(>10)
北方(预计3-5个工作日)
 
P105196-25g Pd 59-60% 上海(预计3-5个工作日)
北方(预计3-5个工作日)
 
P105196-5g Pd 59-60% 上海(预计3-5个工作日)
北方(预计3-5个工作日)
 
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属性

敏感性 易吸潮
密度 1.0600
熔点 678-680°C
溶解性 Soluble in dilute mineral acids, aqueous metal halides
存贮条件 储存温度2-8℃,充氩保存

描述

产品介绍 有潮解性,易溶于稀盐酸,能溶于水、乙醇、丙酮和氢溴酸。
别名 氯化钯(II);二氯化钯;Palladium(II) chloride
应用 1、点滴测定钯、汞、铊和碘,提纯稀有气味,氯化钯试纸检验一氧化碳、检定钴。
2、催化剂,末端烯径(α-烯径)生成甲基酮的氧化催化。
3、通过Wacker反应,在水溶液中用空气作氧化剂,使烯径氧化成醛。
4、用于合成半导体含金属聚合体,该聚合体具有聚吡咯骨架,符合能量最小且接近平面。
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标识符号 GHS06 GHS06
信号词 Danger
风险声明 (欧洲) R41;R43;R37/38;
安全声明(欧洲) S26;S36/37/39/;
警示性声明 P280,P301+P310
危害码(欧洲) C
危害声明 H301,H317
Merck Index 6990
UN代码 1789
参考文献
Hiromitsu H Nonaka, Tokio T Nakada, Masafumi M Iijima, Howard I HI Maibach
Although metals are common contact allergens, clinical findings of metal contact dermatitis have varied. Such patients have subsequently become rare in Japan as gold dermatitis caused by ear piercing ...Read More
Beata B Krecisz, Dorota D Chomiczewska, Cezary C Palczynski, Marta M Kiec-Swierczynska
Contact allergy among adolescents is an important issue....Read More
Malin M Engfeldt, Cecilia C Tillman, Monica M Hindsén, Magnus M Bruze
We're sorry this abstract is currently not available....Read More
Po-Yuan Chen, Keng-Shiang Huang, Chin-Chuan Tsai, Tzu-Pin Wang, Eng-Chi Wang
A novel, concise and efficient synthesis of substituted isocoumarins is disclosed. o-Allylbenzaldehydes prepared from isovanillin were mediated by PdCl(2)-CuCl(2) in water to undergo a domino reaction...Read More
Huanfeng H Jiang, Xiaoyan X Pan, Liangbin L Huang, Jian J Zhao, Dabin D Shi
We have discovered a novel PdCl(2)-FeCl(2) catalyzed cascade cyclization reaction, which involves a novel acyl rearrangement process. This reaction affords a diverse set of poly-substituted 4H-cyclope...Read More
A comparative study on the genotoxic activity of cisplatin versus morfozol, the first representative of a new class of cation-anion complexes of palladium [AH]2[PdCl4] (where A-methylmorpholine) has b...Read More
Yoshikazu Y Mori, Masahiko M Seki
Treatment of thiol esters 1 with zinc reagent 2 in the presence of a small amount (<ca. 1 mol %) of nonpyrophoric Pd(OH)(2)/C (Pearlman's catalyst) provided functionalized asymmetrical ketones...Read More
Farnaz Jafarpour, Soraya Rahiminejadan, Hamideh Hazrati
An atom-economical phosphane-free palladium-catalyzed direct C-2 arylation of unactivated free NH-pyrroles is devised. This method provides a straightforward route to a wide variety of substituted 2-a...Read More
Maria Elisabete Machado, Lucas Panizzi Bregles, Eliana Weber de Menezes, Elina Bastos Caram?o, Edilson Valmir Benvenutti, Cláudia Alcaraz Zini
The separation of the organic sulfur compounds (OSC) of petroleum or its heavy fractions is a critical step and is essential for the correct characterization of these compounds, especially due to simi...Read More
Ingmar Bürstel, Philipp Hummel, Elisabeth Siebert, Nattawadee Wisitruangsakul, Ingo Zebger, B?rbel Friedrich, Oliver Lenz
The O(2)-tolerant [NiFe] hydrogenases of Ralstonia eutropha are capable of H(2) conversion in the presence of ambient O(2). Oxygen represents not only a challenge for catalysis but also for the comple...Read More
Emily H P EH Tan, Guy C GC Lloyd-Jones, Jeremy N JN Harvey, Alastair J J AJ Lennox, Benjamin M BM Mills
We're sorry this abstract is currently not available....Read More
Renata R Kontek, Ksenia K Mat?awska-Wasowska, Urszula U Kalinowska-Lis, Bogdan B Kontek, Justyn J Ochocki
Studies of cytotoxicity allow to elucidate the mechanisms by which chemical compounds influence cells and tissues. On the basis of the structural analogy between platinum(II) and palladium(II) complex...Read More
Feng-Quan Yuan, Lian-Xun Gao, Fu-She Han
We present a PdCl(2)-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions...Read More
Ziwei Z Hu, Dongdong D Liang, Jiaji J Zhao, Jinbo J Huang, Qiang Q Zhu
A base-controlled synthesis of 2-substituted secondary and tertiary 1H-indole-3-carboxamides through PdCl(2)-catalyzed cyclization of o-alkynyltrifluoroacetanilides followed by isocyanide insertion ha...Read More
Buyi B Li, Zhenhong Z Guan, Wei W Wang, Xinjia X Yang, Jianglin J Hu, Bien B Tan, Tao T Li
Highly dispersed palladium chloride catalysts locked in triphenylphosphine-functionalized knitting aryl network polymers (KAPs) are developed and exhibit excellent activity under mild conditions in th...Read More
Maozhong M Miao, Jian J Cao, Jingjing J Zhang, Xian X Huang, Luling L Wu
A novel PdCl(2)-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused ...Read More
Gábor G Kovács, András A Stirling, Agustí A Lledós, Gregori G Ujaque
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species....Read More
A A Bagheri Gh, A A Yosefi rad, M M Rezvani, S S Roshanzamir
The complexation reaction of cephalosporins namely cefotaxime (CTX), cefuroxime (CRX), and cefazolin (CEFAZ) with palladium (II) ions have been studied in water and DMF in 25 °C by the spectrophotome...Read More
Jianglin J Hu, Yanlong Y Gu, Zhenhong Z Guan, Jinjin J Li, Wanling W Mo, Tao T Li, Guangxing G Li
Glycerol carbonate can be readily synthesized from the oxidative carbonylation of glycerol catalyzed by PdCl(2)(phen) (phen=1,10-phenanthroline) with the aid of CuI. High conversion (95 %) and selecti...Read More
Agnieszka A Krogul, Jakub J Cedrowski, Katarzyna K Wiktorska, Wojciech P WP Ozimiński, Jadwiga J Skupińska, Grzegorz G Litwinienko
Palladium(II) complexes attract great attention due to their remarkable catalytic and biological activity. In the present study X-ray characterization, UV-Vis and Time-Dependent Density Functional The...Read More
Yves Y Canac, Nathalie N Debono, Christine C Lepetit, Carine C Duhayon, Remi R Chauvin
The influence of the formal electrostatic interaction on the cis/trans coordination mode at a PdCl(2) center is investigated in a family of isostructural flexible diphosphine ligands Ph(2)P-X-C(6)H(4)...Read More
Jason A JA Weeden, Rongcai R Huang, Kathryn D KD Galloway, Phillip W PW Gingrich, Brian J BJ Frost
The synthesis and structure of palladium complexes of trisubstituted PTA derivatives, PTA(R3), are described. Water-soluble phosphine ligands 1,3,5-triaza-7-phosphaadmantane (PTA), tris(aminomethyl)ph...Read More
Juraj J Velcicky, Arne A Soicke, Roland R Steiner, Hans-Günther HG Schmalz
A one-pot protocol for the cyanomethylation of aryl halides through a palladium-catalyzed reaction with isoxazole-4-boronic acid pinacol ester was developed. Mechanistically, the reaction proceeds thr...Read More
Annesofie Faurschou, Torkil Menné, Jeanne D Johansen, Jacob P Thyssen
Consumers are mainly exposed to palladium from jewellery and dental restorations. Palladium contact allergy is nearly always seen together with nickel allergy, as palladium and nickel tend to cross-re...Read More
Chun Liu, Qijian Ni, Pingping Hu, Jieshan Qiu
A simple and efficient protocol has been developed for the PdCl(2)-catalyzed ligand-free and aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with arylboronic acids in go...Read More
Anita Schnyder, Adriano F Indolese, Martin Studer, Hans-Ulrich Blaser
We're sorry this abstract is currently not available....Read More
Mihai S Viciu, Roy A Kelly, Edwin D Stevens, Frédéric Naud, Martin Studer, Steven P Nolan
Palladacycle dimers possessing bridging halides can be easily cleaved by using N-heterocyclic carbenes (NHCs) to generate novel monomeric complexes. The structure of one of these was determined by sin...Read More
Xiaobing X Wan, Dong D Xing, Zhao Z Fang, Bijie B Li, Fei F Zhao, Keya K Zhang, Liping L Yang, Zhangjie Z Shi
A unique method was discovered to construct polysubstituted pyrroles via an unprecedented multiple deprotonations/deaminations process from commercially available phenethylamines. During this transfor...Read More

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