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1,4-双(二苯膦基)丁烷

1,4-双(二苯膦基)丁烷

规格或纯度: 96%

CAS编号: 7688-25-7
分子式: C₂₈H₂₈P₂
分子量: 426.47
Beilstein号: 706446
EC号: 231-698-7
MDL号: MFCD00003051
PubChem编号: 82124

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货号 (SKU)	包装规格	是否现货	价格	数量
B106731-1g	1g	现货
B106731-5g	5g	现货
B106731-10g	10g	现货
B106731-25g	25g	现货
B106731-100g	100g	现货
B106731-500g	500g	现货

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元素分类的化合物磷化合物

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基本描述

别名	1,4-双(二苯基膦)丁烷\|1,4-丁二酰双 (二苯基膦)\|1,4-丁烯双(二苯基膦)\|四甲基双(二苯基膦)\|dppb
英文别名	1,4-Bis(diphenylphosphino)butane\|7688-25-7\|dppb\|Phosphine, 1,4-butanediylbis[diphenyl-\|4-diphenylphosphanylbutyl(diphenyl)phosphane\|MFCD00003051\|1,4-Bis(diphenylphosphino)butane (DPPB)\|Tetramethylenebis(diphenylphosphine)\|[4-(diphenylphosphanyl)butyl]diph
规格或纯度	96%
英文名称	1,4-Bis(diphenylphosphino)butane
储存温度	充氩
运输条件	常规运输
备注	1g/5g卖完停产，不再备货

名称和标识符

PubChem SID	488186053
PubChem SID url	https://pubchem.ncbi.nlm.nih.gov/substance/488186053
EC号	231-698-7
IUPAC Name	4-diphenylphosphanylbutyl(diphenyl)phosphane
INCHI	InChI=1S/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2
InChi Key	BCJVBDBJSMFBRW-UHFFFAOYSA-N
Canonical SMILES	C1=CC=C(C=C1)P(CCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
Isomeric SMILES	C1=CC=C(C=C1)P(CCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
WGK Germany	3
PubChem CID	82124
分子量	426.47
Beilstein号	706446
Reaxy-Rn	706446

数据库链接

PubChem SID	488186053

化学和物理性质

敏感性	对空气敏感
熔点	130-137°C

安全和危险性（GHS）

象形图	Harmful
信号词	Warning
危险声明	H315: Causes skin irritation H319: Causes serious eye irritation H335: May cause respiratory irritation
预防措施声明	P261,P305+P351+P338,P273,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319
WGK Germany	3
Reaxy-Rn	706446
个人防护装备	dust mask type N95 (US),Eyeshields,Gloves

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参考文献

1. Aliny Pereira Lima,Flávia Castro Pereira,Marcio Aurelio Pinheiro Almeida,Francyelli Mariana Santos Mello,Wanessa Carvalho Pires,Thallita Monteiro Pinto,Flávia Karina Delella,Sérgio Luis Felisbino,Virtudes Moreno,Alzir Azevedo Batista,Elisângela de Paula Silveira-Lacerda. (2014-10-21) Cytoxicity and apoptotic mechanism of ruthenium(II) amino acid complexes in sarcoma-180 tumor cells.. PloS one, 9 ((10)): (e105865-e105865). [PMID:25329644]
2. Mohammed Zain Aldin,Anthony Maho,Guillermo Zaragoza,Albert Demonceau,Lionel Delaude. (2018-09-19) Synthesis, characterization, and catalytic evaluation of ruthenium-diphosphine complexes bearing xanthate ligands.. Dalton transactions (Cambridge, England : 2003), 47 ((39)): (13926-13938). [PMID:30226523]
3. Steven Giboulot,Clara Comuzzi,Alessandro Del Zotto,Rosario Figliolia,Giovanna Lippe,Denise Lovison,Paolo Strazzolini,Sabina Susmel,Ennio Zangrando,Daniele Zuccaccia,Salvatore Baldino,Maurizio Ballico,Walter Baratta. (2019-08-02) Preparation of monocarbonyl ruthenium complexes bearing bidentate nitrogen and phosphine ligands and their catalytic activity in carbonyl compound reduction.. Dalton transactions (Cambridge, England : 2003), 48 ((33)): (12560-12576). [PMID:31367714]
4. Helen Larson,Danielle Schultz,Dipannita Kalyani. (2019-09-25) Ni-Catalyzed C-H Arylation of Oxazoles and Benzoxazoles Using Pharmaceutically Relevant Aryl Chlorides and Bromides.. The Journal of organic chemistry, 84 ((20)): (13092-13103). [PMID:31550163]
5. Angelica E Graminha,João Honorato,Liany Luna Dulcey,Luani Rezende Godoy,Marília F Barbosa,Marcia R Cominetti,Antonio C Menezes,Alzir A Batista. (2020-03-13) Evaluation of the biological potential of ruthenium(II) complexes with cinnamic acid.. Journal of inorganic biochemistry, 206 (): (111021-111021). [PMID:32163810]
6. Celisnolia M Leite,João Honorato de Araujo-Neto,Rodrigo S Corrêa,Legna Colina-Vegas,Diego Martínez-Otero,Paulo R Martins,Cristiane G Silva,Alzir A Batista. (2020-08-26) On the Cytotoxicity of Chiral Ruthenium Complexes Containing Sulfur Amino Acids against Breast Tumor Cells (MDA-231 and MCF-7).. Anti-cancer agents in medicinal chemistry, 21 ((9)): (1172-1182). [PMID:32838726]
7. Araceli de Aquino,Francisco J Caparrós,Gabriel Aullón,Jas S Ward,Kari Rissanen,Yongsik Jung,Hyeonho Choi,João Carlos Lima,Laura Rodríguez. (2020-11-06) Effect of Gold(I) on the Room-Temperature Phosphorescence of Ethynylphenanthrene.. Chemistry (Weinheim an der Bergstrasse, Germany), 27 ((5)): (1810-1820). [PMID:33151003]
8. Inmaculada Mena,Pilar García-Orduña,Víctor Polo,Fernando J Lahoz,Miguel A Casado,Luis A Oro. (2017-08-19) Reactivity of the parent amido complexes of iridium with olefins: C-NH. Dalton transactions (Cambridge, England : 2003), 46 ((34)): (11459-11468). [PMID:28820211]
9. Rodrigo S Correa,Larissa M Bomfim,Katia M Oliveira,Diogo R M Moreira,Milena B P Soares,Javier Ellena,Daniel P Bezerra,Alzir A Batista. (2019-06-21) Ru(II) complexes containing uracil nucleobase analogs with cytotoxicity against tumor cells.. Journal of inorganic biochemistry, 198 (): (110751-110751). [PMID:31220757]
10. Pinjing He,Haowen Duan,Wenhao Han,Yang Liu,Liming Shao,Fan Lü. (2020-01-01) Responses of Methanosarcina barkeri to acetate stress.. Biotechnology for biofuels, 12 (): (289-289). [PMID:31890017]
11. Oliveira, et al.. (2020) Ru(II)-Naphthoquinone complexes with high selectivity for triple-negative breast cancer.. Dalton Transactions, 49 (): (16193-16203). [PMID:32329497]
12. Denise Lovison,Lorenzo Allegri,Federica Baldan,Maurizio Ballico,Giuseppe Damante,Christian Jandl,Walter Baratta. (2020-06-11) Cationic carboxylate and thioacetate ruthenium(ii) complexes: synthesis and cytotoxic activity against anaplastic thyroid cancer cells.. Dalton transactions (Cambridge, England : 2003), 49 ((24)): (8375-8388). [PMID:32520028]
13. Graminha, et al.. (2021) A novel ruthenium(ii) gallic acid complex disrupts the actin cytoskeleton and inhibits migration, invasion and adhesion of triple negative breast tumor cells.. Dalton Transactions, 50 (): (323-335). [PMID:33305766]

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