L-(-)樟脑磺酸

货号 (SKU)	包装规格	是否现货
C100499-5g	5g	现货
C100499-25g	25g	现货
C100499-100g	100g	现货
C100499-250g	250g	现货
C100499-500g	500g	现货
C100499-2.5kg	2.5kg	现货

基本描述

别名	(-)-樟脑-10-磺酸, (1R)-(-)-樟脑-10-磺酸, (1R)-樟脑-10-磺酸\|(-)-10-樟脑磺酸\|樟脑磺酸
英文别名	35963-20-3\|((1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid\|(1R)-(-)-Camphor-10-sulfonic acid\|(-)-10-Camphorsulfonic Acid\|L(-)-Camphorsulfonic acid\|Camphorsulfonic acid, (-)-\|(-)-camphorsulfonic acid\|(1R)-(-)-10-Camphorsulfonic ac
规格或纯度	99%
英文名称	(1R)-(-)-10-Camphorsulfonic acid
应用	有机合成中间体，拆分剂。
储存温度	充氩
运输条件	常规运输
产品介绍	不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。 (1R)-(-)-10-樟脑磺酸是一种用于紫外/可见检测的高效液相色谱衍生试剂。它主要用于基底的解析。 (1R)-(-)-10-樟脑磺酸可作为手性构件用于通过对映选择性碳芳基化合成五价有机铋衍生物。基于光学活性聚苯胺膜的电位传感器可以将它作为手性单体用于手性氨基酸的对映选择性传感。 Insoluble in ether, slightly soluble in glacial acetic acid and ethyl acetate, and easily deliquescent in humid air. (1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases. (1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

名称和标识符

EC号	252-817-9
IUPAC Name	[(1R,4S)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonic acid
INCHI	InChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
InChi Key	MIOPJNTWMNEORI-XVKPBYJWSA-N
Canonical SMILES	CC1(C2CCC1(C(=O)C2)CS(=O)(=O)O)C
Isomeric SMILES	CC1([C@H]2CC[C@@]1(C(=O)C2)CS(=O)(=O)O)C
WGK Germany	3
PubChem CID	5771688
UN Number	3261
分子量	232.3
Beilstein号	2809676
Reaxy-Rn	2809676

化学和物理性质

溶解性	Soluble in water, and a wide variety of organic substances.
密度	1.331
敏感性	对湿度敏感
比旋光度	-21.5 ° (C=5, H2O)
熔点	198°C

安全和危险性（GHS）

象形图	Corrosive
信号词	Danger
危险声明	H314: Causes severe skin burns and eye damage H318: Causes serious eye damage
预防措施声明	P280,P321,P405,P501,P264,P260,P301+P330+P331,P304+P340,P363,P264+P265,P305+P354+P338,P317,P302+P361+P354,P316
WGK Germany	3
Reaxy-Rn	2809676
个人防护装备	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

质检证书(COA)

质检报告(COA)

输入批号以搜索COA:

产品问答

登录提交问题

查看全部

您提交该产品问题后,我们会在1-2个工作日内给您答复,您可以登录"我的账号",然后点击"我的产品问答"查看答案

参考文献

1. C Pierron,J M Panas,M F Etcheverry,G Ledouble. (1990-07-06) Determination of 10-camphorsulphonates in pharmaceutical formulations by high-performance liquid chromatography.. Journal of chromatography, 511 (): (367-372). [PMID:2211919]
2. X R Xu,Q M Tang,Y H Yao. (1987-03-01) [D-camphor-beta-sulfonic acid as an ion-pair reagent for the determination of biogenic amines and their metabolites in the rat brain by reverse phase high performance liquid chromatography].. Zhongguo yao li xue bao = Acta pharmacologica Sinica, 8 ((2)): (113-117). [PMID:2958994]
3. J A Nakhosteen,J Vieira. (1983-03-31) [The expectorant Solucampher: effect on the tracheal clearing velocity in chronic bronchitis].. ZFA. Zeitschrift fur Allgemeinmedizin, 59 ((9)): (36-38). [PMID:6858351]
4. Per J Garegg,Karl-Jonas Johansson,Peter Konradsson,Bengt Lindberg,Zygmunt Trumpakaj. (2002-03-14) Transglucosidation of methyl and ethyl D-glucopyranosides by alcoholysis.. Carbohydrate research, 337 ((6)): (517-521). [PMID:11890889]
5. G Li,M Huang,G Yang,G Wu,A Du,Y Su. (2003-01-29) [The enantiomeric separation of aromatic alcohol amino drugs by thin-layer chromatography].. Se pu = Chinese journal of chromatography, 17 ((2)): (215-216). [PMID:12549175]
6. Anne-Catherine Servais,Marianne Fillet,Patrice Chiap,Walthère Dewé,Philippe Hubert,Jacques Crommen. (2004-09-08) Enantiomeric separation of basic compounds using heptakis(2,3-di-O-methyl-6-O-sulfo)-beta-cyclodextrin in combination with potassium camphorsulfonate in nonaqueous capillary electrophoresis: optimization by means of an experimental design.. Electrophoresis, 25 ((16)): (2701-2710). [PMID:15352001]
7. Andrew J Miles,Frank Wien,B A Wallace. (2004-11-24) Redetermination of the extinction coefficient of camphor-10-sulfonic acid, a calibration standard for circular dichroism spectroscopy.. Analytical biochemistry, 335 ((2)): (338-339). [PMID:15556575]
8. A Bielejewska,K Duszczyk,J Zukowski. (2005-08-05) Effect of (+) or (-) camphorsulfonic acid additives to the mobile phase on enantioseparations of some basic drugs on a Chiralcel OD column.. Journal of chromatography. A, 1083 ((1-2)): (133-140). [PMID:16078699]
9. Alexei V Caramyshev,Vladimir M Lobachov,Daniel V Selivanov,Eugene V Sheval,Andrei Kh Vorobiev,Olesja N Katasova,Vladimir Y Polyakov,Alexander A Makarov,Ivan Yu Sakharov. (2007-07-17) Micellar peroxidase-catalyzed synthesis of chiral polyaniline.. Biomacromolecules, 8 ((8)): (2549-2555). [PMID:17630690]
10. Kaoru Nobuoka,Satoshi Kitaoka,Masashi Iio,Thomas Harran,Yuichi Ishikawa. (2007-11-09) Solute-solvent interactions in imidazolium camphorsulfonate ionic liquids.. Physical chemistry chemical physics : PCCP, 9 ((44)): (5891-5896). [PMID:17989797]
11. Bala Kishan Gorityala,Shuting Cai,Jimei Ma,Xue-Wei Liu. (2009-04-29) (S)-Camphorsulfonic acid catalyzed highly stereoselective synthesis of pseudoglycosides.. Bioorganic & medicinal chemistry letters, 19 ((11)): (3093-3095). [PMID:19398332]
12. A Kumar,Somik Banerjee,Jyoti P Saikia,B K Konwar. (2010-04-02) Swift heavy ion irradiation induced enhancement in the antioxidant activity and biocompatibility of polyaniline nanofibers.. Nanotechnology, 21 ((17)): (175102-175102). [PMID:20357408]
13. Chen Liu,Yixin Lu. (2010-04-24) Primary amine/(+)-CSA salt-promoted organocatalytic conjugate addition of nitro esters to enones.. Organic letters, 12 ((10)): (2278-2281). [PMID:20411973]
14. Szu Heng Liu,Yi Hung Lin,Liang Jen Huang,Shiang Wen Luo,Wan Lin Tsai,Su Yu Chiang,Hok Sum Fung. (2010-10-27) Design and construction of a compact end-station at NSRRC for circular-dichroism spectra in the vacuum-ultraviolet region.. Journal of synchrotron radiation, 17 ((6)): (761-768). [PMID:20975221]
15. Yimin Hua,Shai Dagan,Samanthi Wickramasekara,Dylan J Boday,Vicki H Wysocki. (2010-11-03) Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.. Journal of mass spectrometry : JMS, 45 ((12)): (1394-1401). [PMID:21038364]
16. Suh-Jen Jane Tsai,Yao-Shen Zhong,Jen-Feng Weng,Hsiu-Hua Huang,Pei-Yin Hsieh. (2010-12-24) Determination of bile acids in pig liver, pig kidney and bovine liver by gas chromatography-chemical ionization tandem mass spectrometry with total ion chromatograms and extraction ion chromatograms.. Journal of chromatography. A, 1218 ((3)): (524-533). [PMID:21176836]
17. Chen Liu,Qiang Zhu,Kuo-Wei Huang,Yixin Lu. (2011-04-23) Primary amine/CSA ion pair: a powerful catalytic system for the asymmetric enamine catalysis.. Organic letters, 13 ((10)): (2638-2641). [PMID:21510614]
18. Nidhin Paul,Muthuchamy Murugavel,Shanmugam Muthusubramanian,Dharmarajan Sriram. (2012-01-27) Camphorsulfonic acid catalysed facile tandem double Friedlander annulation protocol for the synthesis of phenoxy linked bisquinoline derivatives and discovery of antitubercular agents.. Bioorganic & medicinal chemistry letters, 22 ((4)): (1643-1648). [PMID:22277278]
19. Ruizhi Pang,Kaisong Zhang. (2017-09-25) Fabrication of hydrophobic fluorinated silica-polyamide thin film nanocomposite reverse osmosis membranes with dramatically improved salt rejection.. Journal of colloid and interface science, 510 (): (127-132). [PMID:28942162]
20. Katarzyna Jankowska,Jakub Zdarta,Adam Grzywaczyk,Ewa Kijeńska-Gawrońska,Andrzej Biadasz,Teofil Jesionowski. (2020-03-11) Electrospun poly(methyl methacrylate)/polyaniline fibres as a support for laccase immobilisation and use in dye decolourisation.. Environmental research, 184 (): (109332-109332). [PMID:32151845]
21. Soyoung Noh,Hye Yeon Gong,Hyun Jong Lee,Won-Gun Koh. (2021-01-14) Electrically Conductive Micropatterned Polyaniline-Poly(ethylene glycol) Composite Hydrogel.. Materials (Basel, Switzerland), 14 ((2)): (). [PMID:33435614]

L-(-)樟脑磺酸

库存信息

库存信息

库存信息

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全和危险性（GHS）

质检证书(COA)

质检报告(COA)

相关文档

质检报告COA

相关技术文章

产品问答

产品问答

参考文献