基本描述

别名	过氧化铅
英文别名	Bleisuperoxyd \| LEAD DIOXIDE \| Lead peroxide (PbO2) \| CCRIS 6254 \| Lead(IV) oxide, ACS reagent, >=97.0% \| Lead(IV) oxide, 99.998% trace metals basis \| Lead(IV) oxide, LR, >=94% \| HSDB 4335 \| AKOS015904093 \| Lead Brown \| Lead dioxide [UN1872] [Oxidizer] \|
规格或纯度	≥97%
英文名称	Lead oxide
运输条件	常规运输
产品介绍	不溶于水、醇，溶于乙酸、氢氧化钠水溶液。用作氧化剂、电极、蓄电池、分析试剂、火柴等。

AI解读

名称和识别符

PubChem SID	504752591
EC号	215-174-5
分子类型	小分子
IUPAC Name	dioxolead
INCHI	InChI=1S/2O.Pb
InChi Key	YADSGOSSYOOKMP-UHFFFAOYSA-N
Canonical SMILES	O=[Pb]=O
Isomeric SMILES	O=[Pb]=O
WGK Germany	3
RTECS	OG0700000
PubChem CID	14793
UN Number	1872
Packing Group	III
分子量	239.2

化学和物理性质

密度	9.36
熔点	290°C
分子量	239.000 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	2
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	239.966 Da
单同位素质量Monoisotopic Mass	239.966 Da
拓扑极表面积Topological Polar Surface Area	34.100 Å²
重原子数Heavy Atom Count	3
形式电荷Formal Charge	0
复杂度Complexity	18.300
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS08, GHS09, GHS07, GHS03
信号词	Danger
危险声明	H341: 怀疑引起遗传缺陷 H351: 怀疑引起遗传缺陷 H373: 通过长时间或反复暴露对器官造成损害 H302: 吞食有害 H400: 对水生生物有剧毒 H332: 吸入有害 H272: 可能加剧火灾；氧化剂 H410: 对水生生物有剧毒并具有长期持续影响 H372: 通过长时间或反复暴露对器官造成损害 H360: 可能损害生育力或未出生的孩子 H302+H332: 吞咽或吸入有害。
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P220: 远离衣物和其他可燃物。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P281: 根据需要使用个人防护设备。 P271: 仅在室外或通风良好的地方使用。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P391: 收集溢出物 P330: 漱口 P203: 使用前，获取、阅读并遵守所有安全说明。 P301+P317: 如果被吞咽：请寻求医疗帮助。 P318: 如果暴露或担心，请就医。 P317: 寻求紧急医疗救助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
RTECS	OG0700000
Class	5.1
个人防护装备	Eyeshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

技术规格说明书

Purity	97-100（%）
Appearance（L131585)	black powder
ICP:Confirms Lead Component	Confirmed
X-Ray Diffraction	Conforms to Structure

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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找到10个结果

批号(Lot Number)	证书类型	日期	货号
B2321899	分析证书	23-01-11	L131585
B2321946	分析证书	23-01-11	L131585
B2321913	分析证书	23-01-05	L131585
B2321930	分析证书	23-01-05	L131585
B2506041	分析证书	23-01-05	L131585
H2430019	分析证书	23-01-05	L131585
D2422045	分析证书	22-06-06	L131585
F2228373	分析证书	22-06-06	L131585
F2228374	分析证书	22-06-06	L131585
F2228375	分析证书	22-06-06	L131585

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2. Fenglai Mo, Zihan Su, Boxun Liu, Lingyu Wan, Yongsheng Li, Jiayu Li, Xinli Liu, Guanlin Liu, Devki N. Talwar, Huilu Yao, Xiaolong Hu, Zhiyuan Zhou. (2024) Impact of annealing process on the properties of 0.85Pb(Sc0.5Ta0.5)O3-0.15PbTiO3 ceramics. JOURNAL OF ALLOYS AND COMPOUNDS, 972 (172834). [PMID:19177349] [10.1016/j.jallcom.2023.172834]
3. Tianyu Tai, Huazhen Cao, Wenyu Feng, Zedong Yin, Huibin Zhang, Guoqu Zheng. (2024) High-efficient synthesis of NaBH4 by solid-phase electrolysis process on a core-shell-type cathode. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 51 (172). [PMID:16287874] [10.1016/j.ijhydene.2023.11.043]
4. He Jungang, Ge You, Wang Ya, Yuan Mohan, Xia Hang, Zhang Xingchen, Chen Xiao, Wang Xia, Zhou Xianchang, Li Kanghua, Chen Chao, Tang Jiang. (2023) Fluoride passivation of ZnO electron transport layers for efficient PbSe colloidal quantum dot photovoltaics. Frontiers of Optoelectronics, 16 (1): (1-11). [PMID:37889375] [10.1007/s12200-023-00082-3]
5. Xuechen Liu, Mingwen Wang, Yuanyi Zhou, Tao Li, Hongxu Duan, Jinglei Li, Linghang Wang, Yang Li, Shuai Yang, Jie Wu, Chao Wang, Xinya Feng, Fei Li. (2023) Ultrahigh Piezocatalytic Performance of Perovskite Ferroelectric Powder via Oxygen Vacancy Engineering. Small, 19 (49): (2303129). [PMID:37616518] [10.1002/smll.202303129]
6. Jungang He, Xianchang Zhou, Ya Wang, Mohan Yuan, Hang Xia, Xiao Chen, You Ge, Xia Wang, Liang Gao, Jiang Tang. (2023) Mid-infrared response of PbS colloidal quantum dot solids. Journal of Materials Chemistry C, 11 (29): (10033-10042). [10.1039/D3TC01698F]
7. Zihan Su, Lingyu Wan, Fenglai Mo, Jiayu Li, Boxun Liu, Chuangjian Liang, Jinsong Xu, Devki N. Talwar, Hang Li, Huilu Yao. (2023) Performance Optimization of Pb0.97La0.03Sc0.45Ta0.45Ti0.1O3 Ceramics by Annealing Process. Materials, 16 (12): (4479). [PMID:37374662] [10.3390/ma16124479]
8. Qiang-Qiang Jia, Meng-Meng Lun, Gele Teri, Li-Yan Xie, Da-Wei Fu, Qiang Guo. (2023) Fluorescence Emission Is Highly Structure-Dependent in Hybrid Lead Halides. INORGANIC CHEMISTRY, 62 (19): (7186–7194). [PMID:37128761] [10.1021/acs.inorgchem.2c04267]
9. Wang Junyao, Hu Xialin, Liu Meichuan, Yin Daqiang. (2023) Formation of Iodinated Trihalomethane Disinfection By-products by Co-oxidation of Natural Organic Matter with Sodium Hypochlorite and Lead Dioxide. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 39 (3): (449-454). [10.1007/s40242-023-3042-0]
10. Zhixiang Hu, Licheng Zhou, Long Li, Binzhou Ying, Yunong Zhao, Peng Wang, Huayao Li, Yang Zhang, Huan Liu. (2023) Quantum Dots-Sensitized High Electron Mobility Transistor (HEMT) for Sensitive NO2 Detection. Chemosensors, 11 (4): (252). [10.3390/chemosensors11040252]
11. Xiao-Bao Li, Chun-Li Hu, Fang Kong, Jiang-Gao Mao. (2023) Structure and optical property evolution in PbM(PO4)X (M = Zn, Sn; X = halogen): SHG effect and birefringence. Inorganic Chemistry Frontiers, 10 (8): (2268-2275). [10.1039/D3QI00230F]
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23. Jihong Zheng, Fumin Li, Chong Chen, Qing Du, Mengqi Jin, Huilin Li, Mingxing Ji, Zhitao Shen. (2022) Perovskite Solar Cells Employing a PbSO4(PbO)4 Quantum Dot-Doped Spiro-OMeTAD Hole Transport Layer with an Efficiency over 22%. ACS Applied Materials & Interfaces, 14 (2): (2989–2999). [PMID:34981934] [10.1021/acsami.1c23118]
24. Yan-Bing TAO, Jing HUANG, Yu-Nong ZHAO, Yan CHEN, Qing HUANG, Bo-Xiang SONG, Jian-Jun CHEN, Huan LIU. (2022) Electrochemical sensor for the detection of eosinophil cationic protein as a marker of allergic rhinitis based on colloidal quantum dots. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 50 (53). [10.1016/j.cjac.2021.11.007]
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27. Feiyi Lyu, Xiaoqi Zheng, Ziyue Li, Zhuo Chen, Ruowen Shi, Zefeng Wang, Haiming Liu, Bo-Lin Lin. (2021) Spatiodynamics, Photodynamics, and Their Correlation in Hybrid Perovskites. CHEMISTRY OF MATERIALS, 33 (10): (3524–3533). [10.1021/acs.chemmater.0c04500]
28. Qirui Shui, Ruibiao Fu, Hongxin Tang, Yuanbin Fang, Zuju Ma, Xintao Wu. (2021) Two Lead Halides with Strong SHG Response Obtained by the Isovalent Substitutions of Alkali Metal Cation and Halogen Anion. INORGANIC CHEMISTRY, 60 (7): (5290–5296). [PMID:33729802] [10.1021/acs.inorgchem.1c00264]
29. Jiajun Li, Ming Guo, Yan Shao, Hongwei Yu, Kaijie Ni. (2021) Electrocatalytic Properties of a Novel β-PbO2/Halloysite Nanotube Composite Electrode. ACS Omega, 6 (8): (5436–5444). [PMID:33681583] [10.1021/acsomega.0c05651]
30. Xiaowei Liu, Yuan Ai, Qian Chen, Sheng Liu. (2021) Lead sulfide nanoparticles synthesized on general protein-based materials. MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 121 (105365). [10.1016/j.mssp.2020.105365]
31. Dong Li, Xiaoli Zhang, Muhammad Ramzan, Kai Gu, Yu Chen, Jiatao Zhang, Bingsuo Zou, Haizheng Zhong. (2020) Colloidal Synthesis of Giant Shell PbSe-Based Core/Shell Quantum Dots in Polar Solvent: Cation Exchange versus Epitaxial Growth. CHEMISTRY OF MATERIALS, 32 (15): (6650–6656). [10.1021/acs.chemmater.0c02059]
32. Yanan Liu, Zhijun Luo, Changsheng Xie, Zongsong Gan. (2020) General and fast patterning of semiconductor nanocrystals by femtosecond laser direct writing. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 53 (12): (125105). [10.1088/1361-6463/ab6623]
33. Pan Yufu, Luo Yanfang, Li Chengcheng, Wang Rongjing, Yuan Yihao, Li Meng, Na Ping. (2020) Preparation and characterization of Ti/SnO2-Sb2O3/α-PbO2/Ce-Nd-β-PbO2 composite electrode for methyl orange degradation. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 24 (3): (545-555). [10.1007/s10008-019-04468-2]
34. Chong Chen, Fumin Li, Liangxin Zhu, Zhitao Shen, Yujuan Weng, Qiang Lou, Furui Tan, Gentian Yue, Qingsong Huang, Mingtai Wang. (2020) Efficient and stable perovskite solar cells thanks to dual functions of oleyl amine-coated PbSO4(PbO)4 quantum dots: Defect passivation and moisture/oxygen blocking. Nano Energy, 68 (104313). [10.1016/j.nanoen.2019.104313]
35. Xuan Lu, Yang Hu, Jiazhuang Guo, Cai-Feng Wang, Su Chen. (2019) Fiber-Spinning-Chemistry Method toward In Situ Generation of Highly Stable Halide Perovskite Nanocrystals. Advanced Science, 6 (22): (1901694). [PMID:31763152] [10.1002/advs.201901694]
36. Huilin Li, Xiantao Jiang, Wenbin Ye, Han Zhang, Li Zhou, Feng Zhang, Donghong She, Ye Zhou, Su-Ting Han. (2019) Fully photon modulated heterostructure for neuromorphic computing. Nano Energy, 65 (104000). [10.1016/j.nanoen.2019.104000]
37. Shuaipu Zang, Yinglin Wang, Meiying Li, Wei Su, Hancheng Zhu, Xintong Zhang, Yichun Liu. (2017) Fabrication of efficient PbS colloidal quantum dot solar cell with low temperature sputter-deposited ZnO electron transport layer. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 169 (264). [10.1016/j.solmat.2017.05.026]
38. Haiting Zhang, Yating Zhang, Xiaoxian Song, Yu Yu, Mingxuan Cao, Yongli Che, Zhang Zhang, Haitao Dai, Junbo Yang, Guizhong Zhang, Jianquan Yao. (2017) Highly Photosensitive Vertical Phototransistors Based on a Poly(3-hexylthiophene) and PbS Quantum Dot Layered Heterojunction. ACS Photonics, 4 (3): (584–592). [10.1021/acsphotonics.6b00896]
39. Shaolei Xie, Shuangbin Li, Jiang Xiao, Ying Yao, Yongzhong Jia. (2017) Phase formation and microstructure of PbTiO3 and CaTiO3 ceramics prepared by a direct current arc discharge technique. FERROELECTRICS, [10.1080/00150193.2017.1282295]
40. Min Li, Wenkai Zhang, Gang Shao, Hao Kan, Zhilong Song, Songman Xu, Haoxiong Yu, Shenglin Jiang, Jingting Luo, Huan Liu. (2016) Sensitive NO2 gas sensors employing spray-coated colloidal quantum dots. THIN SOLID FILMS, 618 (271). [10.1016/j.tsf.2016.08.023]
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42. Pengran Gao, Yi Liu, Weixin Lv, Rui Zhang, Wei Liu, Xianfu Bu, Guanghua Li, Lixu Lei. (2014) Methanothermal reduction of mixtures of PbSO4 and PbO2 to synthesize ultrafine α-PbO powders for lead acid batteries. JOURNAL OF POWER SOURCES, 265 (192). [10.1016/j.jpowsour.2014.04.045]
43. Pengran Gao, Weixin Lv, Rui Zhang, Yi Liu, Guanghua Li, Xianfu Bu, Lixu Lei. (2014) Methanothermal treatment of carbonated mixtures of PbSO4 and PbO2 to synthesize α-PbO for lead acid batteries. JOURNAL OF POWER SOURCES, 248 (363). [10.1016/j.jpowsour.2013.09.104]
44. Pengran Gao, Yi Liu, Xianfu Bu, Meng Hu, Yuan Dai, Xiaorui Gao, Lixu Lei. (2013) Solvothermal synthesis of α-PbO from lead dioxide and its electrochemical performance as a positive electrode material. JOURNAL OF POWER SOURCES, 242 (299). [10.1016/j.jpowsour.2013.05.077]
45. Hao Wei, Shangzhi Chen, Xinglong Ren, Bingjian Qian, Yanjie Su, Zhi Yang, Yafei Zhang. (2012) Band gap tunable Sn-doped PbSe nanocrystals: solvothermal synthesis and first-principles calculations. CRYSTENGCOMM, 14 (21): (7408-7414). [10.1039/C2CE25905B]

参考文献

1. Junyi Huang, Jianfeng Ding, Furui Tan, Yueyue Gao, Xiayao Lu, Chen Dong, Gentian Yue, Xiaobao Xu, Liming Ding. (2023) A hybrid quantum dot:MXene bulk heterojunction for an efficient infrared self-powered photodetector. Journal of Materials Chemistry C, 11 (48): (17106-17114). [PMID:12039962] [10.1039/D3TC03254J]
2. Fenglai Mo, Zihan Su, Boxun Liu, Lingyu Wan, Yongsheng Li, Jiayu Li, Xinli Liu, Guanlin Liu, Devki N. Talwar, Huilu Yao, Xiaolong Hu, Zhiyuan Zhou. (2024) Impact of annealing process on the properties of 0.85Pb(Sc0.5Ta0.5)O3-0.15PbTiO3 ceramics. JOURNAL OF ALLOYS AND COMPOUNDS, 972 (172834). [PMID:19177349] [10.1016/j.jallcom.2023.172834]
3. Tianyu Tai, Huazhen Cao, Wenyu Feng, Zedong Yin, Huibin Zhang, Guoqu Zheng. (2024) High-efficient synthesis of NaBH4 by solid-phase electrolysis process on a core-shell-type cathode. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 51 (172). [PMID:16287874] [10.1016/j.ijhydene.2023.11.043]
4. He Jungang, Ge You, Wang Ya, Yuan Mohan, Xia Hang, Zhang Xingchen, Chen Xiao, Wang Xia, Zhou Xianchang, Li Kanghua, Chen Chao, Tang Jiang. (2023) Fluoride passivation of ZnO electron transport layers for efficient PbSe colloidal quantum dot photovoltaics. Frontiers of Optoelectronics, 16 (1): (1-11). [PMID:37889375] [10.1007/s12200-023-00082-3]
5. Xuechen Liu, Mingwen Wang, Yuanyi Zhou, Tao Li, Hongxu Duan, Jinglei Li, Linghang Wang, Yang Li, Shuai Yang, Jie Wu, Chao Wang, Xinya Feng, Fei Li. (2023) Ultrahigh Piezocatalytic Performance of Perovskite Ferroelectric Powder via Oxygen Vacancy Engineering. Small, 19 (49): (2303129). [PMID:37616518] [10.1002/smll.202303129]
6. Jungang He, Xianchang Zhou, Ya Wang, Mohan Yuan, Hang Xia, Xiao Chen, You Ge, Xia Wang, Liang Gao, Jiang Tang. (2023) Mid-infrared response of PbS colloidal quantum dot solids. Journal of Materials Chemistry C, 11 (29): (10033-10042). [10.1039/D3TC01698F]
7. Zihan Su, Lingyu Wan, Fenglai Mo, Jiayu Li, Boxun Liu, Chuangjian Liang, Jinsong Xu, Devki N. Talwar, Hang Li, Huilu Yao. (2023) Performance Optimization of Pb0.97La0.03Sc0.45Ta0.45Ti0.1O3 Ceramics by Annealing Process. Materials, 16 (12): (4479). [PMID:37374662] [10.3390/ma16124479]
8. Qiang-Qiang Jia, Meng-Meng Lun, Gele Teri, Li-Yan Xie, Da-Wei Fu, Qiang Guo. (2023) Fluorescence Emission Is Highly Structure-Dependent in Hybrid Lead Halides. INORGANIC CHEMISTRY, 62 (19): (7186–7194). [PMID:37128761] [10.1021/acs.inorgchem.2c04267]
9. Wang Junyao, Hu Xialin, Liu Meichuan, Yin Daqiang. (2023) Formation of Iodinated Trihalomethane Disinfection By-products by Co-oxidation of Natural Organic Matter with Sodium Hypochlorite and Lead Dioxide. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 39 (3): (449-454). [10.1007/s40242-023-3042-0]
10. Zhixiang Hu, Licheng Zhou, Long Li, Binzhou Ying, Yunong Zhao, Peng Wang, Huayao Li, Yang Zhang, Huan Liu. (2023) Quantum Dots-Sensitized High Electron Mobility Transistor (HEMT) for Sensitive NO2 Detection. Chemosensors, 11 (4): (252). [10.3390/chemosensors11040252]
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