三氟甲烷磺酸

规格或纯度: 98%

CAS编号: 1493-13-6
分子式: CF₃SO₃H
分子量: 150.08
Beilstein号: 3693487
EC号: 216-087-5
MDL号: MFCD00007514
PubChem编号: 62406

有货

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭

货号 (SKU)	包装规格	是否现货
T104298-5g	5g	现货
T104298-25g	25g	现货
T104298-100g	100g	现货
T104298-500g	500g	现货
T104298-2.5kg	2.5kg	现货

Skip to the end of the images gallery

Skip to the beginning of the images gallery

基本描述

别名	三氟甲磺酸 \| 三氟甲基磺酸 \| 全氟甲磺酸
英文别名	Triflic acid \| Perfluoromethanesulfonic acid \| TFMSA
规格或纯度	98%
英文名称	Trifluoromethanesulfonic acid
应用	异构化和烷基化的催化剂。制备2，3-二氢-2-茚酮、四氢萘酮。去除糖蛋白中糖苷。
储存温度	室温,充氩
运输条件	常规运输
产品介绍	三氟甲磺酸是最强的单质子有机酸。它是通过双（三氟甲硫基）汞与过氧化氢水溶液的氧化反应进行合成的。它在二甲亚砜、二甲基乙酰胺和二甲基甲酰胺等碱性溶剂中完全解离。已通过电导法研究了其在非水溶剂中的解离。通过混合三氟甲磺酸与HNO3，可形成三氟甲烷磺酸硝鎓，这是一种出色的硝化试剂。应用三氟甲磺酸可用作苯乙烯、六甲基环三硅氧烷和 L,L-丙交酯的阳离子聚合的引发剂；三氟甲磺酸是一种通用试剂，可用作以下研究的催化剂：芳香族化合物与苯甲酸甲酯的Friedel-Crafts酰化反应；二烷基二硫化物与末端炔烃的加成反应；合成含有三氟甲磺酸丙基铵和甲基侧链基团的单环四硅氧烷（Am-CyTS）；制备用于合成氟化2,5-取代的1-乙基-1H-苯并咪唑衍生物的起始试剂；三氟甲磺酸芳基酯的合成、链烯酸的内酯化和 E-烯烃的形成去糖基化剂 Trifluoromethanesulfonic acid, or triflic acid, is one of the strongest monoprotic acids available. It can be used as a precursor and a catalyst in organic chemistry. It is useful in the deglycosylation of glycoproteins. A versatile reagent employed in the synthesis of aryl triflates, the lactonization of alkenoic acids, and the formation of E-alkenes. Deglycosylation agent

名称和标识符

EC号	216-087-5
IUPAC Name	trifluoromethanesulfonic acid
INCHI	InChI=1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)
InChi Key	ITMCEJHCFYSIIV-UHFFFAOYSA-N
Canonical SMILES	C(F)(F)(F)S(=O)(=O)O
Isomeric SMILES	C(F)(F)(F)S(=O)(=O)O
WGK Germany	2
PubChem CID	62406
UN Number	3265
Packing Group	II
分子量	150.08
Beilstein号	3693487
Reaxy-Rn	1812100

化学和物理性质

溶解性	可溶于水、DMSO、DMF 和丙酮三叶。
密度	1.71
敏感性	空气及湿度敏感
折光率	1.326-1.33
闪点(℉)	332.1 °F
闪点(℃)	> 166.7 °C
沸点	162°C
熔点	-40°C

安全和危险性（GHS）

象形图	Corrosive Harmful
信号词	Danger
危险声明	H335: May cause respiratory irritation H314: Causes severe skin burns and eye damage H302: Harmful if swallowed H290: May be corrosive to metals
预防措施声明	P261,P280,P321,P405,P501,P264,P260,P271,P270,P301+P330+P331,P304+P340,P363,P403+P233,P330,P234,P390,P406,P301+P317,P305+P354+P338,P302+P361+P354,P316,P319
WGK Germany	2
Reaxy-Rn	1812100
Class	8
Merck Index	9676
个人防护装备	Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

质检证书(COA)

质检报告(COA)

输入批号以搜索COA:

可替换产品

产品问答

登录提交问题

查看全部

您提交该产品问题后,我们会在1-2个工作日内给您答复,您可以登录"我的账号",然后点击"我的产品问答"查看答案

参考文献

1. Sandro Keller,Carolyn Vargas,Huaying Zhao,Grzegorz Piszczek,Chad A Brautigam,Peter Schuck. (2012-04-26) High-precision isothermal titration calorimetry with automated peak-shape analysis.. Analytical chemistry, 84 ((11)): (5066-5073). [PMID:22530732]
2. Dennis M Whitfield. (2012-05-01) Complications of modeling glycosylation reactions: can the anomeric conformation of a donor determine the glycopyranosyl oxacarbenium ring conformation?. Carbohydrate research, 356 (): (191-195). [PMID:22542073]
3. Shiqiang Yan,Ning Ding,Wei Zhang,Peng Wang,Yingxia Li,Ming Li. (2012-05-09) An efficient and recyclable catalyst for the cleavage of tert-butyldiphenylsilyl ethers.. Carbohydrate research, 354 (): (6-20). [PMID:22565030]
4. Danqing Zheng,Shaoyu Li,Jie Wu. (2012-05-24) An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate.. Organic letters, 14 ((11)): (2655-2657). [PMID:22616758]
5. Yu Liu,Michael P Doyle. (2012-06-27) Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.. Organic & biomolecular chemistry, 10 ((31)): (6388-6394). [PMID:22733346]
6. Luka S Kovacevic,Christopher Idziak,Augustinas Markevicius,Callum Scullion,Michael J Corr,Alan R Kennedy,Tell Tuttle,John A Murphy. (2012-07-19) Superelectrophilic amidine dications: dealkylation by triflate anion.. Angewandte Chemie (International ed. in English), 51 ((34)): (8516-8519). [PMID:22807275]
7. Dominika Bratkowska,Núria Fontanals,Sylwia Ronka,Andrzej W Trochimczuk,Francesc Borrull,Rosa M Marcé. (2012-08-07) Comparison of different imidazolium supported ionic liquid polymeric phases with strong anion-exchange character for the extraction of acidic pharmaceuticals from complex environmental samples.. Journal of separation science, 35 ((15)): (1953-1958). [PMID:22865758]
8. Akio Saito,Nao Hyodo,Yuji Hanzawa. (2012-09-15) Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.. Molecules (Basel, Switzerland), 17 ((9)): (11046-11055). [PMID:22976468]
9. Atsushi Kinbara,Takehiro Yamagishi,Naoko Hanzawa,Etsuko Kawashima,Hiroaki Miyaoka. (2012-09-26) Synthesis of phenol derivatives from cyclohex-2-enones bearing an alkyne through Lewis acid-catalyzed enolization and intramolecular Alder-Rickert reaction.. The Journal of organic chemistry, 77 ((20)): (8999-9005). [PMID:23003109]
10. Yu Hsien Lin,Bhaswati Ghosh,Kwok-Kong Tony Mong. (2012-10-02) In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.. Chemical communications (Cambridge, England), 48 ((88)): (10910-10912). [PMID:23023321]
11. Dahan Eom,Sangjune Park,Youngchul Park,Taekyu Ryu,Phil Ho Lee. (2012-10-26) Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.. Organic letters, 14 ((21)): (5392-5395). [PMID:23094690]
12. Yasuyuki Muto,Yuta Murai,Yasuko Sakihama,Yasuyuki Hashidoko,Makoto Hashimoto. (2012-11-08) Effective Friedel-Crafts acylation of biotin acid chloride in trifluoromethanesulfonic acid.. Bioscience, biotechnology, and biochemistry, 76 ((11)): (2162-2164). [PMID:23132579]
13. Fergus R Knight,Rebecca A M Randall,Lucy Wakefield,Alexandra M Z Slawin,J Derek Woollins. (2012-11-10) Investigating silver coordination to mixed chalcogen ligands.. Molecules (Basel, Switzerland), 17 ((11)): (13307-13329). [PMID:23138535]
14. Su-Xia Xu,Lu Hao,Tao Wang,Zong-Cang Ding,Zhuang-Ping Zhan. (2012-11-29) Chemoselective synthesis of substituted pyrazoles through AgOTf-catalyzed cascade propargylic substitution-cyclization-aromatization.. Organic & biomolecular chemistry, 11 ((2)): (294-298). [PMID:23188378]
15. B V Subba Reddy,M Ramana Reddy,Y Gopal Rao,J S Yadav,B Sridhar. (2013-01-18) Cu(OTf)2-catalyzed synthesis of 2,3-disubstituted indoles and 2,4,5-trisubstituted pyrroles from α-diazoketones.. Organic letters, 15 ((3)): (464-467). [PMID:23323540]
16. Krystyna Poreba,Joanna Wietrzyk. (2013-01-30) The synthesis of 3,5,6,7-tetrasubstituted isoxazolo[4,5-b]pyridines and an evaluation of their in vitro antiproliferative activity.. Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 21 ((5)): (563-571). [PMID:23356192]
17. Jeong Hyeon Park,Chan Yi Park,Hyun Seung Song,Yun Suk Huh,Geon Hee Kim,Chan Pil Park. (2013-02-05) Green diacetoxylation of alkenes in a microchemical system.. Organic letters, 15 ((4)): (752-755). [PMID:23373522]
18. Xinxin Yu,Feixue Zou,Ying Li,Lu Lu,Xirong Huang,Yinbo Qu. (2013-02-14) Effect of three trifluoromethanesulfonate ionic liquids on the activity, stability and conformation of laccase.. International journal of biological macromolecules, 56 (): (62-68). [PMID:23403026]
19. Fumiya Urabe,Shunsuke Nagashima,Keisuke Takahashi,Jun Ishihara,Susumi Hatakeyama. (2013-04-13) Total synthesis of (-)-cinatrin C1 based on an In(OTf)3-catalyzed Conia-Ene reaction.. The Journal of organic chemistry, 78 ((8)): (3847-3857). [PMID:23578072]
20. Lihui Zhu,Zhi-Guo Xi,Jian Lv,Sanzhong Luo. (2013-08-21) In(III)/PhCO2H binary acid catalyzed tandem [2 + 2] cycloaddition and Nazarov reaction between alkynes and acetals.. Organic letters, 15 ((17)): (4496-4499). [PMID:23947688]
21. Chao Zhao,Travis Hoppe,Mohan Kumar Haleyur Giri Setty,Danielle Murray,Tae-Wook Chun,Indira Hewlett,Daniel H Appella. (2014-10-07) Quantification of plasma HIV RNA using chemically engineered peptide nucleic acids.. Nature communications, 5 (): (5079-5079). [PMID:25283173]
22. Adrian Najer,Dalin Wu,Andrej Bieri,Françoise Brand,Cornelia G Palivan,Hans-Peter Beck,Wolfgang Meier. (2014-12-02) Nanomimics of host cell membranes block invasion and expose invasive malaria parasites.. ACS nano, 8 ((12)): (12560-12571). [PMID:25435059]
23. Hua-Dong Xu,Zhi-Hong Jia,Ke Xu,Hao Zhou,Mei-Hua Shen. (2014-12-17) One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.. Organic letters, 17 ((1)): (66-69). [PMID:25496025]
24. Zoel Codolà,Laura Gómez,Scott T Kleespies,Lawrence Que,Miquel Costas,Julio Lloret-Fillol. (2015-01-23) Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.. Nature communications, 6 (): (5865-5865). [PMID:25609387]
25. Shota Kinoshita,Seiji Watase,Kimihiro Matsukawa,Yoshiro Kaneko. (2015-04-01) Selective Synthesis of cis-trans-cis Cyclic Tetrasiloxanes and the Formation of Their Two-Dimensional Layered Aggregates.. Journal of the American Chemical Society, 137 ((15)): (5061-5065). [PMID:25826426]
26. Yue Shen,Jian-Kui Sun,Yu-Xuan Yi,Bo Wang,Feng Xu,Run-Cang Sun. (2015-06-10) One-pot synthesis of levulinic acid from cellulose in ionic liquids.. Bioresource technology, 192 (): (812-816). [PMID:26055443]
27. Alexandra Malachová,Lenka Štočková,Astrid Wakker,Elisabeth Varga,Rudolf Krska,Herbert Michlmayr,Gerhard Adam,Franz Berthiller. (2015-06-13) Critical evaluation of indirect methods for the determination of deoxynivalenol and its conjugated forms in cereals.. Analytical and bioanalytical chemistry, 407 ((20)): (6009-6020). [PMID:26065425]
28. Lucas M S G A Applegarth,Christopher Alcorn,Katherine Bissonette,John Noël,Peter R Tremaine. (2015-07-15) Non-Complexing Anions for Quantitative Speciation Studies Using Raman Spectroscopy in Fused Silica High-Pressure Optical Cells Under Hydrothermal Conditions.. Applied spectroscopy, 69 ((8)): (972-983). [PMID:26162934]
29. Alexandra A Astafieva,Atim A Enyenihi,Eugene A Rogozhin,Sergey A Kozlov,Eugene V Grishin,Tatyana I Odintsova,Roman A Zubarev,Tsezi A Egorov. (2015-08-11) Novel proline-hydroxyproline glycopeptides from the dandelion (Taraxacum officinale Wigg.) flowers: de novo sequencing and biological activity.. Plant science : an international journal of experimental plant biology, 238 (): (323-329). [PMID:26259198]
30. M Arisawa,M Yamaguchi. (2001-03-22) Addition reaction of dialkyl disulfides to terminal alkynes catalyzed by a rhodium complex and trifluoromethanesulfonic acid.. Organic letters, 3 ((5)): (763-764). [PMID:11259056]
31. J Stuart Grossert,Lisandra Cubero Herrera,Louis Ramaley,Jeremy E Melanson. (2014-05-29) Studying the chemistry of cationized triacylglycerols using electrospray ionization mass spectrometry and density functional theory computations.. Journal of the American Society for Mass Spectrometry, 25 ((8)): (1421-1440). [PMID:24867430]
32. Meilin Li,Yujie Ren. (2015-04-01) Synthesis and Biological Evaluation of Some New 2,5-Substituted 1-Ethyl-1H-benzoimidazole Fluorinated Derivatives as Direct Thrombin Inhibitors.. Archiv der Pharmazie, 348 ((5)): (353-365). [PMID:25824648]

三氟甲烷磺酸

库存信息

库存信息

库存信息

库存信息

库存信息

基本描述

名称和标识符

化学和物理性质

安全和危险性（GHS）

质检证书(COA)

质检报告(COA)

相关文档

质检报告COA

可替换产品

相关技术文章

产品问答

产品问答

参考文献