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化学和生化试剂
配体
膦配体
三(3,5-二甲苯基)膦

三(3,5-二甲苯基)膦

规格或纯度: 96%

CAS编号: 69227-47-0
分子式: [(CH₃)₂C₆H₃]₃P
分子量: 346.44
MDL号: MFCD03094579
PubChem编号: 112263

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货号 (SKU)	包装规格	是否现货	价格	数量
T123980-1g	1g	现货
T123980-5g	5g	现货

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基本描述

英文别名	Tris(3,5-dimethylphenyl)phosphine\|69227-47-0\|tris(3,5-dimethylphenyl)phosphane\|Tri-3,5-xylylphosphine\|Phosphine, tris(3,5-dimethylphenyl)-\|p(3,5-xylyl)3\|tris(3,5-xylyl) phosphine\|SCHEMBL503226\|DTXSID5071969\|XRALRSQLQXKXKP-UHFFFAOYSA-N\|MFCD03094579\|AKOS015
规格或纯度	96%
英文名称	Tris(3,5-dimethylphenyl)phosphine
应用	Catalyst for: 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.
运输条件	常规运输
产品介绍	Catalyst for: 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis. Catalyst for: 1Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones 2Highly selective rhodium-catalyzed hydrogenation reactions 3 Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes. Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes. Used for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis.

名称和标识符

IUPAC Name	tris(3,5-dimethylphenyl)phosphane
INCHI	InChI=1S/C24H27P/c1-16-7-17(2)11-22(10-16)25(23-12-18(3)8-19(4)13-23)24-14-20(5)9-21(6)15-24/h7-15H,1-6H3
InChi Key	XRALRSQLQXKXKP-UHFFFAOYSA-N
Canonical SMILES	CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=CC(=C3)C)C)C
Isomeric SMILES	CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=CC(=C3)C)C)C
WGK Germany	3
PubChem CID	112263
分子量	346.44

化学和物理性质

熔点	160-165°C

安全和危险性（GHS）

象形图	Harmful
信号词	Warning
危险声明	H302: Harmful if swallowed
预防措施声明	P501,P264,P270,P330,P301+P317
WGK Germany	3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

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