基本描述

别名	硼氢化锂
英文别名	Lithium boron hydride \| Lithium hydroborate
规格或纯度	≥95%
英文名称	Lithium borohydride
储存温度	充氩
运输条件	常规运输
产品介绍	在约275℃分解。有吸湿性。在干空气中稳定，在湿空气中分解。在pH值大于7时，能溶于水，且水溶液缓慢分解，加酸则较剧烈分解。溶于乙醚、四氢呋喃、脂肪胺类。与氯化氢作用，生成氢、乙硼烷和氯化锂。常配置成THF溶液使用。用作强还原剂，能还原醛类、酮类和酯类等。 Lithium borohydride is a general reducing agent commonly used to reduce aldehydes, ketones esters, lactones, and epoxides. It catalyzes hydroboration of alkenes. It is also used in the preparation of other borohydrides such as aluminum borohydride. Lithium borohydride is a general reducing agent commonly used to reduce aldehydes, ketones esters, lactones, and epoxides. It catalyzes hydroboration of alkenes. It is also used in the preparation of other borohydrides such as aluminum borohydride.

AI解读

名称和识别符

PubChem SID	504768936
EC号	241-021-7
IUPAC Name	lithium;boron(1-)
INCHI	InChI=1S/B.Li/q-1;+1
InChi Key	NZTNZPDOBQDOSO-UHFFFAOYSA-N
Canonical SMILES	[Li+].[B-]
Isomeric SMILES	[Li+].[B-]
WGK Germany	2
RTECS	ED2725000
PubChem CID	20722760
UN Number	1413
Packing Group	I
分子量	21.78

化学和物理性质

溶解性	Soluble in ether, THF, and aliphatic aminesSoluble in ether, tetrahydrofuran, aliphatic amines and ethanol.
密度	0.66
敏感性	对湿度敏感
闪点(℃)	-18℃
熔点	275°C
分子量	17.800 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	18.0253 Da
单同位素质量Monoisotopic Mass	18.0253 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	2
形式电荷Formal Charge	0
复杂度Complexity	2.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	2

安全和危险性（GHS）

一般危化品	一般危化品,易制爆
象形图	GHS06, GHS05, GHS02
信号词	Danger
危险声明	H301: 吞咽会中毒 H260: 与水接触会释放出可自燃的易燃气体 H314: 造成严重的皮肤灼伤和眼睛损伤
预防措施声明	P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P310: 立即致电解毒中心或医生。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P271: 仅在室外或通风良好的地方使用。 P331: 不要催吐 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P330: 漱口 P402+P404: 存放于干燥处。存放于密闭的容器中。
WGK Germany	2
RTECS	ED2725000
Class	4.3
个人防护装备	Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

技术规格说明书

Purity(Gas Volumetric)	95-100（%）
Appearance（L107011)	white to grey powder or crystals
X-Ray Diffraction	Conforms to Structure

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

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找到32个结果

批号(Lot Number)	证书类型	日期	货号
C2517269	分析证书	25-02-12	L107011
C2517313	分析证书	25-02-12	L107011
C2529028	分析证书	25-02-12	L107011
K2420557	分析证书	24-11-13	L107011
K2420546	分析证书	24-11-13	L107011
K2420545	分析证书	24-11-13	L107011
J2411544	分析证书	24-09-26	L107011
J2411543	分析证书	24-09-26	L107011
J2411542	分析证书	24-09-26	L107011
H2405563	分析证书	24-07-20	L107011
H2405562	分析证书	24-07-20	L107011
H2405561	分析证书	24-07-20	L107011
E2408443	分析证书	24-04-25	L107011
E2408441	分析证书	24-04-25	L107011
B24231038	分析证书	24-02-01	L107011
B24231039	分析证书	24-02-01	L107011
B24231040	分析证书	24-02-01	L107011
D2417023	分析证书	24-02-01	L107011
J2327655	分析证书	23-10-16	L107011
J2327623	分析证书	23-10-16	L107011
J2327622	分析证书	23-10-16	L107011
E2318528	分析证书	23-05-06	L107011
E2318540	分析证书	23-05-06	L107011
B2311066	分析证书	22-12-06	L107011
B2311115	分析证书	22-12-06	L107011
I2202441	分析证书	22-08-16	L107011
I2202440	分析证书	22-08-16	L107011
I2202370	分析证书	22-08-16	L107011
E2227183	分析证书	22-05-22	L107011
E2227187	分析证书	22-05-22	L107011
E2227188	分析证书	22-05-22	L107011
C2204008	分析证书	22-03-07	L107011

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此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站?

1. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li. (2023) Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption. Inorganics, 11 (5): (216). [10.3390/inorganics11050216]
2. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang. (2023) Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2. CHEMICAL ENGINEERING JOURNAL, 454 (140205). [10.1016/j.cej.2022.140205]
3. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu. (2022) Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range. JOURNAL OF ALLOYS AND COMPOUNDS, 905 (164030). [10.1016/j.jallcom.2022.164030]
4. Kang Chen, Hao Zhong, Liuzhang Ouyang, Fen Liu, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2023) Achieving a novel solvent-free regeneration of LiBH4 combining hydrogen storage and production in a closed material cycle. Journal of Magnesium and Alloys, 11 (1697). [10.1016/j.jma.2021.08.005]
5. Kang Chen, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2020) A high-performance hydrogen generation system: Hydrolysis of LiBH4-based materials catalyzed by transition metal chlorides. RENEWABLE ENERGY, 156 (655). [10.1016/j.renene.2020.04.030]
6. Fan Yanping, Chen Dandan, Yuan Zhenluo, Chen Qiang, Fan Guangxin, Zhao Dan, Liu Baozhong. (2020) Flexible, Water-Resistant and Air-Stable LiBH4 Nanoparticles Loaded Melamine Foam With Improved Dehydrogenation. Frontiers in Chemistry, 8 [PMID:32117873] [10.3389/fchem.2020.00045]
7. Wei Zhu, Juan Zhao, Lu Wang, Yun-Lei Teng, Bao-Xia Dong. (2019) Mechanochemical reactions of alkali borohydride with CO2 under ambient temperature. JOURNAL OF SOLID STATE CHEMISTRY, 277 (828). [10.1016/j.jssc.2019.07.037]
8. Kang Chen, Liuzhang Ouyang, Hao Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu. (2019) Converting H+ from coordinated water into H− enables super facile synthesis of LiBH4. GREEN CHEMISTRY, 21 (16): (4380-4387). [10.1039/C9GC01897B]
9. Yanping Fan, Dandan Chen, Xianyun Liu, Guangxin Fan, Baozhong Liu. (2019) Improving the hydrogen storage performance of lithium borohydride by Ti3C2 MXene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 44 (29297). [10.1016/j.ijhydene.2019.01.011]
10. Wei Zhang, Guang Xu, Lingjuan Chen, Shuyi Pan, Xu Jing, Jiasheng Wang, Shumin Han. (2017) Enhanced hydrogen storage performances of LiBH4 modified with three-dimensional porous fluorinated graphene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 42 (15262). [10.1016/j.ijhydene.2017.05.018]
11. Xiaofeng Sun, Keyang Yin, Baoyong Liu, Shengju Zhou, Jiamei Cao, Geping Zhang, Hongguang Li. (2017) Carbon quantum dots in ionic liquids: a new generation of environmentally benign photoluminescent inks. Journal of Materials Chemistry C, 5 (20): (4951-4958). [10.1039/C7TC00543A]
12. Yingying Zhu, Jianxin Zou, Xiaoqin Zeng. (2015) Study on reversible hydrogen sorption behaviors of 3LiBH4/graphene and 3LiBH4/graphene–10 wt% CeF3 composites. RSC Advances, 5 (101): (82916-82923). [10.1039/C5RA13737C]

参考文献

1. L M Likhosherstov,O S Novikova,V A Derevitskaia,N K Kochetkov. (1984-01-01) [New method of cleaving the N-linked carbohydrate chains of glycoproteins using alkaline lithium borohydride].. Doklady Akademii nauk SSSR, 274 ((1)): (222-225). [PMID:6705674]
2. N P Arbatskiĭ,L M Likhosherstov,M V Serebriakova,O S Brusov,V N Shibaev,V A Derevitskaia,N K Kochetkov. (2000-05-12) [The degradation of glycoproteins with lithium borohydride. Isolation and analysis of O-glycopeptides with reduced C-terminal amino acid residue].. Bioorganicheskaia khimiia, 26 ((1)): (51-60). [PMID:10806552]
3. David A Evans,George Borg,Karl A Scheidt. (2002-10-09) Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles.. Angewandte Chemie (International ed. in English), 41 ((17)): (3188-3191). [PMID:12207385]
4. G Erfurt,M R Krbetschek. (2002-10-18) A radioluminescence study of spectral and dose characteristics of common luminophors.. Radiation protection dosimetry, 100 ((1-4)): (403-406). [PMID:12382908]
5. Mark R Biscoe,Ronald Breslow. (2003-10-16) Hydrophobically directed selective reduction of ketones.. Journal of the American Chemical Society, 125 ((42)): (12718-12719). [PMID:14558814]
6. Prabhat Arya,Patricia Durieux,Zai-Xin Chen,Reni Joseph,Donald M Leek. (2004-01-13) Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives.. Journal of combinatorial chemistry, 6 ((1)): (54-64). [PMID:14714985]
7. Sumalee Supothina,Masahiko Isaka,Kanyawim Kirtikara,Morakot Tanticharoen,Yodhathai Thebtaranonth. (2005-02-17) Enniatin production by the entomopathogenic fungus Verticillium hemipterigenum BCC 1449.. The Journal of antibiotics, 57 ((11)): (732-738). [PMID:15712668]
8. Barbara Milani,Corrado Crottib,Erica Farnetti. (2008-11-26) Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials.. Dalton transactions (Cambridge, England : 2003), ((34)): (4659-4663). [PMID:19024366]
9. Hui Wu,Wei Zhou,Ke Wang,Terrence J Udovic,John J Rush,Taner Yildirim,Leonid A Bendersky,Adam F Gross,Sky L Van Atta,John J Vajo,Frederick E Pinkerton,Martin S Meyer. (2009-05-08) Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8.. Nanotechnology, 20 ((20)): (204002-204002). [PMID:19420650]
10. Matthew S Wellons,Polly A Berseth,Ragaiy Zidan. (2009-05-08) Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release.. Nanotechnology, 20 ((20)): (204022-204022). [PMID:19420670]
11. S M Opalka,X Tang,B L Laube,T H Vanderspurt. (2009-05-08) Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4.. Nanotechnology, 20 ((20)): (204024-204024). [PMID:19420672]
12. Pascal Martelli,Arndt Remhof,Andreas Borgschulte,Philippe Mauron,Dirk Wallacher,Ewout Kemner,Margarita Russina,Flavio Pendolino,Andreas Züttel. (2010-09-03) BH4− self-diffusion in liquid LiBH4.. The journal of physical chemistry. A, 114 ((37)): (10117-10121). [PMID:20806929]
13. Meganne Christian,Kondo-Francois Aguey-Zinsou. (2010-10-05) Destabilisation of complex hydrides through size effects.. Nanoscale, 2 ((12)): (2587-2590). [PMID:20886168]
14. Roger Domènech-Ferrer,Frank Ziegs,Sabrina Klod,Inge Lindemann,Ralf Voigtländer,Lothar Dunsch,Oliver Gutfleisch. (2011-03-18) In situ Raman cell for high pressure and temperature studies of metal and complex hydrides.. Analytical chemistry, 83 ((8)): (3199-3204). [PMID:21410226]
15. Mita Dasog,Wenbo Hou,Robert W J Scott. (2011-06-28) Controlled growth and catalytic activity of gold monolayer protected clusters in presence of borohydride salts.. Chemical communications (Cambridge, England), 47 ((30)): (8569-8571). [PMID:21706115]
16. Xinyi Chen,Shaofeng Li,Yanhui Guo,Xuebin Yu. (2011-08-19) Promoted dehydrogenation in ammine lithium borohydride supported by carbon nanotubes.. Dalton transactions (Cambridge, England : 2003), 40 ((38)): (9679-9689). [PMID:21850349]
17. Piter S Miedema,Peter Ngene,Ad M J van der Eerden,Tsu-Chien Weng,Dennis Nordlund,Dimosthenis Sokaras,Roberto Alonso-Mori,Amélie Juhin,Petra E de Jongh,Frank M F de Groot. (2012-03-20) In situ X-ray Raman spectroscopy of LiBH4.. Physical chemistry chemical physics : PCCP, 14 ((16)): (5581-5587). [PMID:22428166]
18. Alyssa M Keil,Douglas M Frederick,Erina Y Jacinto,Erica L Kennedy,Randy J Zauhar,Nathan M West,Ruy Tchao,Peter J Harvison. (2015-07-21) Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells.. Toxicology in vitro : an international journal published in association with BIBRA, 29 ((7)): (1887-1896). [PMID:26193171]
19. Kostiantyn V Kravchyk,Laura Piveteau,Riccarda Caputo,Meng He,Nicholas P Stadie,Maryna I Bodnarchuk,Rainer T Lechner,Maksym V Kovalenko. (2018-08-09) Colloidal Bismuth Nanocrystals as a Model Anode Material for Rechargeable Mg-Ion Batteries: Atomistic and Mesoscale Insights.. ACS nano, 12 ((8)): (8297-8307). [PMID:30086624]
20. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li. (2023) Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption. Inorganics, 11 (5): (216). [10.3390/inorganics11050216]
21. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang. (2023) Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2. CHEMICAL ENGINEERING JOURNAL, 454 (140205). [10.1016/j.cej.2022.140205]
22. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu. (2022) Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range. JOURNAL OF ALLOYS AND COMPOUNDS, 905 (164030). [10.1016/j.jallcom.2022.164030]
23. Kang Chen, Hao Zhong, Liuzhang Ouyang, Fen Liu, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2023) Achieving a novel solvent-free regeneration of LiBH4 combining hydrogen storage and production in a closed material cycle. Journal of Magnesium and Alloys, 11 (1697). [10.1016/j.jma.2021.08.005]
24. Kang Chen, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2020) A high-performance hydrogen generation system: Hydrolysis of LiBH4-based materials catalyzed by transition metal chlorides. RENEWABLE ENERGY, 156 (655). [10.1016/j.renene.2020.04.030]
25. Fan Yanping, Chen Dandan, Yuan Zhenluo, Chen Qiang, Fan Guangxin, Zhao Dan, Liu Baozhong. (2020) Flexible, Water-Resistant and Air-Stable LiBH4 Nanoparticles Loaded Melamine Foam With Improved Dehydrogenation. Frontiers in Chemistry, 8 [PMID:32117873] [10.3389/fchem.2020.00045]
26. Wei Zhu, Juan Zhao, Lu Wang, Yun-Lei Teng, Bao-Xia Dong. (2019) Mechanochemical reactions of alkali borohydride with CO2 under ambient temperature. JOURNAL OF SOLID STATE CHEMISTRY, 277 (828). [10.1016/j.jssc.2019.07.037]
27. Kang Chen, Liuzhang Ouyang, Hao Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu. (2019) Converting H+ from coordinated water into H− enables super facile synthesis of LiBH4. GREEN CHEMISTRY, 21 (16): (4380-4387). [10.1039/C9GC01897B]
28. Yanping Fan, Dandan Chen, Xianyun Liu, Guangxin Fan, Baozhong Liu. (2019) Improving the hydrogen storage performance of lithium borohydride by Ti3C2 MXene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 44 (29297). [10.1016/j.ijhydene.2019.01.011]
29. Wei Zhang, Guang Xu, Lingjuan Chen, Shuyi Pan, Xu Jing, Jiasheng Wang, Shumin Han. (2017) Enhanced hydrogen storage performances of LiBH4 modified with three-dimensional porous fluorinated graphene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 42 (15262). [10.1016/j.ijhydene.2017.05.018]
30. Xiaofeng Sun, Keyang Yin, Baoyong Liu, Shengju Zhou, Jiamei Cao, Geping Zhang, Hongguang Li. (2017) Carbon quantum dots in ionic liquids: a new generation of environmentally benign photoluminescent inks. Journal of Materials Chemistry C, 5 (20): (4951-4958). [10.1039/C7TC00543A]
31. Yingying Zhu, Jianxin Zou, Xiaoqin Zeng. (2015) Study on reversible hydrogen sorption behaviors of 3LiBH4/graphene and 3LiBH4/graphene–10 wt% CeF3 composites. RSC Advances, 5 (101): (82916-82923). [10.1039/C5RA13737C]

溶液计算器

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货号 (SKU)	包装规格	是否现货
L107011-10g	10g	现货
L107011-50g	50g	现货
L107011-250g	250g	现货

硼氢化锂(易制爆)

库存信息

库存信息

库存信息

基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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此产品的引用文献

参考文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器

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