基本描述

英文别名	Lithium hydroborate \| Lithium boron hydride
规格或纯度	2.0M in THF
英文名称	Lithium borohydride
储存温度	充氩
运输条件	常规运输
产品介绍	在约275℃分解。有吸湿性。在干空气中稳定，在湿空气中分解。在pH值大于7时，能溶于水，且水溶液缓慢分解，加酸则较剧烈分解。溶于乙醚、四氢呋喃、脂肪胺类。与氯化氢作用，生成氢、乙硼烷和氯化锂。常配置成THF溶液使用。用作强还原剂，能还原醛类、酮类和酯类等。 Lithium borohydride solution (2M in THF) has been used for the reduction of 5-benzylidene-2,4-thiazolidinediones and 5-benzylidene-4-oxo-2-thiazolidinethiones to form 5-benzyl-2,4-thiazolidinediones and 5-benzyl-4-oxo-2-thiazolidinethiones, respectively. Reactant for: · Preparation of gallium, indium, rhenium and zinc tris(mercaptoimidazolyl)hydroborato complexes · Mechano-chemical metathesis reactions · Noncatalytic hydrolysis for hydrogen generation · Growth of large gold monolayer protected-clusters · Anion substitution reactions · Dehydrogenation reactions

AI解读

名称和识别符

EC号	241-021-7
IUPAC Name	lithium;boron(1-)
INCHI	InChI=1S/B.Li/q-1;+1
InChi Key	NZTNZPDOBQDOSO-UHFFFAOYSA-N
Canonical SMILES	[Li+].[B-]
Isomeric SMILES	[Li+].[B-]
WGK Germany	2
RTECS	ED2725000
PubChem CID	20722760
UN Number	1413
Packing Group	I
分子量	21.78

化学和物理性质

密度	0.896
敏感性	对湿度敏感
闪点(℃)	-18℃
熔点	275°C
分子量	17.800 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	18.0253 Da
单同位素质量Monoisotopic Mass	18.0253 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	2
形式电荷Formal Charge	0
复杂度Complexity	2.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	2

安全和危险性（GHS）

一般危化品	一般危化品,易制爆
象形图	GHS06, GHS05, GHS02
信号词	Danger
危险声明	H301: 吞咽会中毒 H260: 与水接触会释放出可自燃的易燃气体 H314: 造成严重的皮肤灼伤和眼睛损伤
预防措施声明	P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P310: 立即致电解毒中心或医生。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P271: 仅在室外或通风良好的地方使用。 P331: 不要催吐 P270: 使用本产品时，请勿进食、饮水或吸烟。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P330: 漱口 P402+P404: 存放于干燥处。存放于密闭的容器中。
WGK Germany	2
RTECS	ED2725000
Class	4.3
个人防护装备	Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

技术规格说明书

Concentration	1.9-2.1（mol/L）
Appearance（L107012)	Colorless or Grey Liquid(With a small of precipitation)
Solvent(THF)	Conform

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

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找到53个结果

批号(Lot Number)	证书类型	日期	货号
L2419724	分析证书	24-12-06	L107012
L2419721	分析证书	24-12-06	L107012
L2419719	分析证书	24-12-06	L107012
L2419685	分析证书	24-12-06	L107012
K2412443	分析证书	24-11-04	L107012
K2412444	分析证书	24-11-04	L107012
K2412445	分析证书	24-11-04	L107012
H2405259	分析证书	24-07-20	L107012
H2412538	分析证书	24-07-20	L107012
J2408243	分析证书	24-07-18	L107012
H2405258	分析证书	24-07-18	L107012
H2405260	分析证书	24-07-18	L107012
D2425381	分析证书	24-03-29	L107012
D2425385	分析证书	24-03-29	L107012
D2425383	分析证书	24-03-29	L107012
B2422224	分析证书	24-01-31	L107012
B2422192	分析证书	24-01-31	L107012
B2422191	分析证书	24-01-31	L107012
B2422173	分析证书	24-01-31	L107012
A2402434	分析证书	23-12-20	L107012
A2402433	分析证书	23-12-20	L107012
K2330119	分析证书	23-11-20	L107012
K2330117	分析证书	23-11-20	L107012
J2323720	分析证书	23-10-16	L107012
J2323721	分析证书	23-10-16	L107012
J2323735	分析证书	23-10-16	L107012
H2309397	分析证书	23-07-31	L107012
H2309398	分析证书	23-07-31	L107012
H2309399	分析证书	23-07-31	L107012
H2309400	分析证书	23-07-31	L107012
E2330963	分析证书	23-05-15	L107012
E2330962	分析证书	23-05-15	L107012
E2330960	分析证书	23-05-15	L107012
E2330953	分析证书	23-05-15	L107012
C23181150	分析证书	23-03-13	L107012
C23181138	分析证书	23-03-13	L107012
C23181136	分析证书	23-03-13	L107012
A2329356	分析证书	23-01-06	L107012
A2329500	分析证书	23-01-06	L107012
A2329498	分析证书	23-01-06	L107012
A2329322	分析证书	23-01-06	L107012
J2228692	分析证书	22-10-11	L107012
J2228701	分析证书	22-10-11	L107012
J2228691	分析证书	22-10-11	L107012
J2228675	分析证书	22-10-11	L107012
G2216357	分析证书	22-06-30	L107012
G2216356	分析证书	22-06-30	L107012
G2216355	分析证书	22-06-30	L107012
G2216354	分析证书	22-06-30	L107012
F2201043	分析证书	22-03-22	L107012
F2201042	分析证书	22-03-22	L107012
F2201036	分析证书	22-03-22	L107012
F2201034	分析证书	22-03-22	L107012

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此产品的引用文献

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1. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li. (2023) Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption. Inorganics, 11 (5): (216). [10.3390/inorganics11050216]
2. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang. (2023) Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2. CHEMICAL ENGINEERING JOURNAL, 454 (140205). [10.1016/j.cej.2022.140205]
3. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu. (2022) Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range. JOURNAL OF ALLOYS AND COMPOUNDS, 905 (164030). [10.1016/j.jallcom.2022.164030]
4. Kang Chen, Hao Zhong, Liuzhang Ouyang, Fen Liu, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2023) Achieving a novel solvent-free regeneration of LiBH4 combining hydrogen storage and production in a closed material cycle. Journal of Magnesium and Alloys, 11 (1697). [10.1016/j.jma.2021.08.005]
5. Kang Chen, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2020) A high-performance hydrogen generation system: Hydrolysis of LiBH4-based materials catalyzed by transition metal chlorides. RENEWABLE ENERGY, 156 (655). [10.1016/j.renene.2020.04.030]
6. Fan Yanping, Chen Dandan, Yuan Zhenluo, Chen Qiang, Fan Guangxin, Zhao Dan, Liu Baozhong. (2020) Flexible, Water-Resistant and Air-Stable LiBH4 Nanoparticles Loaded Melamine Foam With Improved Dehydrogenation. Frontiers in Chemistry, 8 [PMID:32117873] [10.3389/fchem.2020.00045]
7. Wei Zhu, Juan Zhao, Lu Wang, Yun-Lei Teng, Bao-Xia Dong. (2019) Mechanochemical reactions of alkali borohydride with CO2 under ambient temperature. JOURNAL OF SOLID STATE CHEMISTRY, 277 (828). [10.1016/j.jssc.2019.07.037]
8. Kang Chen, Liuzhang Ouyang, Hao Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu. (2019) Converting H+ from coordinated water into H− enables super facile synthesis of LiBH4. GREEN CHEMISTRY, 21 (16): (4380-4387). [10.1039/C9GC01897B]
9. Yanping Fan, Dandan Chen, Xianyun Liu, Guangxin Fan, Baozhong Liu. (2019) Improving the hydrogen storage performance of lithium borohydride by Ti3C2 MXene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 44 (29297). [10.1016/j.ijhydene.2019.01.011]
10. Wei Zhang, Guang Xu, Lingjuan Chen, Shuyi Pan, Xu Jing, Jiasheng Wang, Shumin Han. (2017) Enhanced hydrogen storage performances of LiBH4 modified with three-dimensional porous fluorinated graphene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 42 (15262). [10.1016/j.ijhydene.2017.05.018]
11. Xiaofeng Sun, Keyang Yin, Baoyong Liu, Shengju Zhou, Jiamei Cao, Geping Zhang, Hongguang Li. (2017) Carbon quantum dots in ionic liquids: a new generation of environmentally benign photoluminescent inks. Journal of Materials Chemistry C, 5 (20): (4951-4958). [10.1039/C7TC00543A]
12. Yingying Zhu, Jianxin Zou, Xiaoqin Zeng. (2015) Study on reversible hydrogen sorption behaviors of 3LiBH4/graphene and 3LiBH4/graphene–10 wt% CeF3 composites. RSC Advances, 5 (101): (82916-82923). [10.1039/C5RA13737C]

参考文献

1. L M Likhosherstov,O S Novikova,V A Derevitskaia,N K Kochetkov. (1984-01-01) [New method of cleaving the N-linked carbohydrate chains of glycoproteins using alkaline lithium borohydride].. Doklady Akademii nauk SSSR, 274 ((1)): (222-225). [PMID:6705674]
2. N P Arbatskiĭ,L M Likhosherstov,M V Serebriakova,O S Brusov,V N Shibaev,V A Derevitskaia,N K Kochetkov. (2000-05-12) [The degradation of glycoproteins with lithium borohydride. Isolation and analysis of O-glycopeptides with reduced C-terminal amino acid residue].. Bioorganicheskaia khimiia, 26 ((1)): (51-60). [PMID:10806552]
3. David A Evans,George Borg,Karl A Scheidt. (2002-10-09) Remarkably stable tetrahedral intermediates: carbinols from nucleophilic additions to N-acylpyrroles.. Angewandte Chemie (International ed. in English), 41 ((17)): (3188-3191). [PMID:12207385]
4. G Erfurt,M R Krbetschek. (2002-10-18) A radioluminescence study of spectral and dose characteristics of common luminophors.. Radiation protection dosimetry, 100 ((1-4)): (403-406). [PMID:12382908]
5. Mark R Biscoe,Ronald Breslow. (2003-10-16) Hydrophobically directed selective reduction of ketones.. Journal of the American Chemical Society, 125 ((42)): (12718-12719). [PMID:14558814]
6. Prabhat Arya,Patricia Durieux,Zai-Xin Chen,Reni Joseph,Donald M Leek. (2004-01-13) Stereoselective diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based polycyclic derivatives.. Journal of combinatorial chemistry, 6 ((1)): (54-64). [PMID:14714985]
7. Sumalee Supothina,Masahiko Isaka,Kanyawim Kirtikara,Morakot Tanticharoen,Yodhathai Thebtaranonth. (2005-02-17) Enniatin production by the entomopathogenic fungus Verticillium hemipterigenum BCC 1449.. The Journal of antibiotics, 57 ((11)): (732-738). [PMID:15712668]
8. Barbara Milani,Corrado Crottib,Erica Farnetti. (2008-11-26) Hydrogen transfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials.. Dalton transactions (Cambridge, England : 2003), ((34)): (4659-4663). [PMID:19024366]
9. Hui Wu,Wei Zhou,Ke Wang,Terrence J Udovic,John J Rush,Taner Yildirim,Leonid A Bendersky,Adam F Gross,Sky L Van Atta,John J Vajo,Frederick E Pinkerton,Martin S Meyer. (2009-05-08) Size effects on the hydrogen storage properties of nanoscaffolded Li3BN2H8.. Nanotechnology, 20 ((20)): (204002-204002). [PMID:19420650]
10. Matthew S Wellons,Polly A Berseth,Ragaiy Zidan. (2009-05-08) Novel catalytic effects of fullerene for LiBH4 hydrogen uptake and release.. Nanotechnology, 20 ((20)): (204022-204022). [PMID:19420670]
11. S M Opalka,X Tang,B L Laube,T H Vanderspurt. (2009-05-08) Experimental and theoretical screening of nanoscale oxide reactivity with LiBH4.. Nanotechnology, 20 ((20)): (204024-204024). [PMID:19420672]
12. Pascal Martelli,Arndt Remhof,Andreas Borgschulte,Philippe Mauron,Dirk Wallacher,Ewout Kemner,Margarita Russina,Flavio Pendolino,Andreas Züttel. (2010-09-03) BH4− self-diffusion in liquid LiBH4.. The journal of physical chemistry. A, 114 ((37)): (10117-10121). [PMID:20806929]
13. Meganne Christian,Kondo-Francois Aguey-Zinsou. (2010-10-05) Destabilisation of complex hydrides through size effects.. Nanoscale, 2 ((12)): (2587-2590). [PMID:20886168]
14. Roger Domènech-Ferrer,Frank Ziegs,Sabrina Klod,Inge Lindemann,Ralf Voigtländer,Lothar Dunsch,Oliver Gutfleisch. (2011-03-18) In situ Raman cell for high pressure and temperature studies of metal and complex hydrides.. Analytical chemistry, 83 ((8)): (3199-3204). [PMID:21410226]
15. Xinyi Chen,Shaofeng Li,Yanhui Guo,Xuebin Yu. (2011-08-19) Promoted dehydrogenation in ammine lithium borohydride supported by carbon nanotubes.. Dalton transactions (Cambridge, England : 2003), 40 ((38)): (9679-9689). [PMID:21850349]
16. Piter S Miedema,Peter Ngene,Ad M J van der Eerden,Tsu-Chien Weng,Dennis Nordlund,Dimosthenis Sokaras,Roberto Alonso-Mori,Amélie Juhin,Petra E de Jongh,Frank M F de Groot. (2012-03-20) In situ X-ray Raman spectroscopy of LiBH4.. Physical chemistry chemical physics : PCCP, 14 ((16)): (5581-5587). [PMID:22428166]
17. David J Timson,Steffen Lindert. (2013-06-05) Comparison of dynamics of wildtype and V94M human UDP-galactose 4-epimerase-A computational perspective on severe epimerase-deficiency galactosemia.. Gene, 526 ((2)): (318-324). [PMID:23732289]
18. Alyssa M Keil,Douglas M Frederick,Erina Y Jacinto,Erica L Kennedy,Randy J Zauhar,Nathan M West,Ruy Tchao,Peter J Harvison. (2015-07-21) Cytotoxicity of thiazolidinedione-, oxazolidinedione- and pyrrolidinedione-ring containing compounds in HepG2 cells.. Toxicology in vitro : an international journal published in association with BIBRA, 29 ((7)): (1887-1896). [PMID:26193171]
19. Zhi-Kang Qin, Li-Qing He, Xiao-Li Ding, Ting-Zhi Si, Ping Cui, Hai-Wen Li, Yong-Tao Li. (2023) Liquid Channels Built-In Solid Magnesium Hydrides for Boosting Hydrogen Sorption. Inorganics, 11 (5): (216). [10.3390/inorganics11050216]
20. Jiahui Li, Yangfeng Wang, Mengru Hu, Zhangze Ye, Xiaohua Zheng, Peng Li, Chu Liang. (2023) Self-templated synthesis of boron-doped porous carbon by chemical interaction of 2LiBH4·CO2 with CO2. CHEMICAL ENGINEERING JOURNAL, 454 (140205). [10.1016/j.cej.2022.140205]
21. Kang Chen, Mili Liu, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Min Zhu. (2022) Efficient hydrogen release from LiBH4 alcoholysis in methanol/ethylene glycol based solutions over a wide temperature range. JOURNAL OF ALLOYS AND COMPOUNDS, 905 (164030). [10.1016/j.jallcom.2022.164030]
22. Kang Chen, Hao Zhong, Liuzhang Ouyang, Fen Liu, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2023) Achieving a novel solvent-free regeneration of LiBH4 combining hydrogen storage and production in a closed material cycle. Journal of Magnesium and Alloys, 11 (1697). [10.1016/j.jma.2021.08.005]
23. Kang Chen, Liuzhang Ouyang, Hui Wang, Jiangwen Liu, Huaiyu Shao, Min Zhu. (2020) A high-performance hydrogen generation system: Hydrolysis of LiBH4-based materials catalyzed by transition metal chlorides. RENEWABLE ENERGY, 156 (655). [10.1016/j.renene.2020.04.030]
24. Fan Yanping, Chen Dandan, Yuan Zhenluo, Chen Qiang, Fan Guangxin, Zhao Dan, Liu Baozhong. (2020) Flexible, Water-Resistant and Air-Stable LiBH4 Nanoparticles Loaded Melamine Foam With Improved Dehydrogenation. Frontiers in Chemistry, 8 [PMID:32117873] [10.3389/fchem.2020.00045]
25. Wei Zhu, Juan Zhao, Lu Wang, Yun-Lei Teng, Bao-Xia Dong. (2019) Mechanochemical reactions of alkali borohydride with CO2 under ambient temperature. JOURNAL OF SOLID STATE CHEMISTRY, 277 (828). [10.1016/j.jssc.2019.07.037]
26. Kang Chen, Liuzhang Ouyang, Hao Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu. (2019) Converting H+ from coordinated water into H− enables super facile synthesis of LiBH4. GREEN CHEMISTRY, 21 (16): (4380-4387). [10.1039/C9GC01897B]
27. Yanping Fan, Dandan Chen, Xianyun Liu, Guangxin Fan, Baozhong Liu. (2019) Improving the hydrogen storage performance of lithium borohydride by Ti3C2 MXene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 44 (29297). [10.1016/j.ijhydene.2019.01.011]
28. Wei Zhang, Guang Xu, Lingjuan Chen, Shuyi Pan, Xu Jing, Jiasheng Wang, Shumin Han. (2017) Enhanced hydrogen storage performances of LiBH4 modified with three-dimensional porous fluorinated graphene. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 42 (15262). [10.1016/j.ijhydene.2017.05.018]
29. Xiaofeng Sun, Keyang Yin, Baoyong Liu, Shengju Zhou, Jiamei Cao, Geping Zhang, Hongguang Li. (2017) Carbon quantum dots in ionic liquids: a new generation of environmentally benign photoluminescent inks. Journal of Materials Chemistry C, 5 (20): (4951-4958). [10.1039/C7TC00543A]
30. Yingying Zhu, Jianxin Zou, Xiaoqin Zeng. (2015) Study on reversible hydrogen sorption behaviors of 3LiBH4/graphene and 3LiBH4/graphene–10 wt% CeF3 composites. RSC Advances, 5 (101): (82916-82923). [10.1039/C5RA13737C]

溶液计算器

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计算配制储备溶液所需的稀释度。

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所需的复溶浓度

货号 (SKU)	包装规格	是否现货
L107012-25ml	25ml	现货
L107012-100ml	100ml	现货
L107012-500ml	500ml	现货
L107012-800ml	800ml	期货

硼氢化锂四氢呋喃溶液(易制爆)

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基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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