基本描述

英文别名	HSDB 5847 \| metyl tert-butyl ether \| tert. butyl-methylether \| tert. butyl-methyl-ether \| tert.-butyl methylether \| CHEBI:27642 \| tertbutylmethylether \| tert-butylmethylether \| tert-butyl-methylether \| tert-butyl-methyl-ether \| 2-Methoxy-2-methylpropane \|
规格或纯度	UltraPureChrom™, for gas chromatography ECD and FID
英文名称	tert-Butyl methyl ether
储存温度	室温
运输条件	常规运输
产品介绍	叔丁基甲基醚（甲基叔丁醚，MTBE）是一种汽油添加剂。丙烷氧化细菌菌株对其进行氧化降解已经过测定。其热介导的生物降解的动力学已经在多种反应条件下进行了研究。其生物降解遵循伪一级衰变模型，并且其伪一级速率常数已经过测定。其水中的提取物已通过使用有机聚合化合物Nafion进行研究。MTBE可以通过甲醇和异丁烯之间的酸催化反应合成。一项研究表明，MTBE的加入通过停流法增加了丙烯聚合过程中活性位点的数量。该溶剂符合ACS（美国化学学会）规范，可用于需要严格质量条件的工艺，如分析测试。应用叔甲基醚（甲基叔丁醚，MTBE）可用于：作为混合微生物菌群中的唯一碳和能量来源。从生物液体中提取脂质用于鸟枪法谱分析。在超临界条件下，在不存在催化剂的情况下通过菜籽油的酯交换，合成脂肪酸甲酯（FAME）和甘油叔丁醚。 General Description SupraSolv ECD and FID is specially developed for gas chromatography in combination with ECD (Electron Capture Detetor) and FID (Flame Ionization detector). SupraSolv solvents offer the largest specified retention time range, a clear baseline and a minimal signal-to-noise ratio leading to reliable and reproducible analysis results.

AI解读

作用机制

作用机制	Action Type	target ID	Target Name	Target Type	Target Organism	Binding Site Name	参考文献

名称和识别符

EC号	216-653-1
分子类型	小分子
IUPAC Name	2-methoxy-2-methylpropane
INCHI	InChI=1S/C5H12O/c1-5(2,3)6-4/h1-4H3
InChi Key	BZLVMXJERCGZMT-UHFFFAOYSA-N
Canonical SMILES	CC(C)(C)OC
Isomeric SMILES	CC(C)(C)OC
WGK Germany	1
RTECS	KN5250000
PubChem CID	15413
UN Number	2398
Packing Group	II
分子量	88.15
Beilstein号	1730942
Reaxy-Rn	1730942

化学和物理性质

密度	0.74g/cm3at 20°C
折光率	1.3689
闪点(℉)	-18.4℉
闪点(℃)	-28℃
沸点	55.2°C
熔点	-109°C
分子量	88.150 g/mol
XLogP3	0.900
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	88.0888 Da
单同位素质量Monoisotopic Mass	88.0888 Da
拓扑极表面积Topological Polar Surface Area	9.200 Å²
重原子数Heavy Atom Count	6
形式电荷Formal Charge	0
复杂度Complexity	33.700
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS07, GHS02
信号词	Danger
危险声明	H315: 引起皮肤刺激 H225: 高度易燃的液体和蒸气
预防措施声明	P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。
WGK Germany	1
RTECS	KN5250000
Reaxy-Rn	1730942
Class	3
Merck Index	6032
个人防护装备	Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US)

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