基本描述

别名	醋酸锆,碱式乙酸锆
英文别名	EINECS 224-179-1 \| Q42414121 \| zirconium(4+);tetraacetate \| A865608 \| MFCD00054410 \| zirconium(iv) acetate \| Acetic acid, zirconium salt \| DTXSID20890586 \| Acetic acid, zirconium(4+) salt \| HSDB 2529 \| Acetic acid, zirconium(4+) salt (4:1) \| EC 231-492-7
规格或纯度	Zr,15.0 - 16.0 %
英文名称	Zirconium acetate
应用	催化剂，工程陶瓷领域。
储存温度	干燥
运输条件	常规运输
产品介绍	酸度较强，有腐蚀性。溶于水，在沸水中分解。催化剂，工程陶瓷领域。

AI解读

名称和识别符

PubChem SID	488182867
分子类型	未知
IUPAC Name	zirconium(4+);tetraacetate
INCHI	InChI=1S/4C2H4O2.Zr/c41-2(3)4;/h41H3,(H,3,4);/q;;;;+4/p-4
InChi Key	MFFVROSEPLMJAP-UHFFFAOYSA-J
Canonical SMILES	CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Zr+4]
Isomeric SMILES	CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Zr+4]
WGK Germany	1
PubChem CID	24237
UN Number	2790
分子量	327.4

化学和物理性质

密度	1.279
分子量	327.400 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	8
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	325.958 Da
单同位素质量Monoisotopic Mass	325.958 Da
拓扑极表面积Topological Polar Surface Area	161.000 Å²
重原子数Heavy Atom Count	17
形式电荷Formal Charge	0
复杂度Complexity	25.500
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	5

安全和危险性（GHS）

象形图	GHS05, GHS07
信号词	Danger
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H318: 造成严重的眼睛损伤
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	1

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批号(Lot Number)	证书类型	日期	货号
C2510383	分析证书	25-02-26	Z110957
C2510384	分析证书	25-02-26	Z110957
C2510385	分析证书	25-02-26	Z110957
C2510386	分析证书	25-02-26	Z110957
K2427723	分析证书	24-11-13	Z110957
K2427721	分析证书	24-11-13	Z110957
K2427720	分析证书	24-11-13	Z110957
B2520542	分析证书	24-07-08	Z110957
B2520543	分析证书	24-07-08	Z110957
F2405550	分析证书	24-03-22	Z110957
F2405555	分析证书	24-03-22	Z110957
F2405554	分析证书	24-03-22	Z110957
F2405549	分析证书	24-03-22	Z110957
K2309248	分析证书	23-10-26	Z110957
K2309292	分析证书	23-10-26	Z110957
K2309293	分析证书	23-10-26	Z110957
C2317377	分析证书	23-02-06	Z110957
J2317150	分析证书	23-02-06	Z110957
C2317376	分析证书	23-02-06	Z110957
B2302337	分析证书	22-07-16	Z110957
I2216625	分析证书	22-07-16	Z110957
I2216630	分析证书	22-07-16	Z110957
I2216636	分析证书	22-07-16	Z110957
I2216645	分析证书	22-07-16	Z110957
B2328259	分析证书	22-07-16	Z110957
B2302338	分析证书	22-07-16	Z110957
F2224181	分析证书	21-03-19	Z110957

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4. Li Cuiping, Zhang Lu, Zhang Shuai, Yu Qiqi, Li Dan, Zhang Lei, Gong Chunhong, Zhang Jingwei. (2023) Flexible regulation engineering of titanium nitride nanofibrous membranes for efficient electromagnetic microwave absorption in wide temperature spectrum. Nano Research, (1-10). [10.1007/s12274-023-6350-2]
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29. Jiaojiao Xia, Haoran Guo, Maozeng Cheng, Chuyan Chen, Minkang Wang, Yong Xiang, Tingshuai Li, Enrico Traversa. (2021) Electrospun zirconia nanofibers for enhancing the electrochemical synthesis of ammonia by artificial nitrogen fixation. Journal of Materials Chemistry A, 9 (4): (2145-2151). [10.1039/D0TA08089F]
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参考文献

1. Zhen Xu, Fan Wu, Kai Pan, Yalong Liao, Fei Wang, Longdi Cheng, Jianyong Yu, Yi-Tao Liu, Bin Ding. (2024) Ceramic aerogels constructed from dense, non-porous ceramic nanofibers with robust and elastic properties up to 1300 °C. CERAMICS INTERNATIONAL, 50 (6381). [PMID:16467868] [10.1016/j.ceramint.2023.11.373]
2. Mao Xue, Li Zhen-Zhen, Hao Dong-Lian, Han Wei-Dong, Li Gao-Peng, Wang Yao-Yu, Zhang Kun. (2023) Biomimetic design of highly flexible metal oxide nanofibrous membranes with exceptional mechanical performance for superior phosphopeptide enrichment. Nano Research, (17): (1-9). [PMID:20634291] [10.1007/s12274-023-6277-7]
3. Hongjie Liu, Minchen Hou, Hao Fu, Anjie Hu, Yanliang Zhai, Liwei Wang, Dong Zhai, Shaolong Zhang, Shaopeng Wang. (2024) 2D/1D BiOBr/TiO2 flexible nanofibrous film heterojunction photocatalyst for tetracycline degradation. Surfaces and Interfaces, 44 (103795). [10.1016/j.surfin.2023.103795]
4. Li Cuiping, Zhang Lu, Zhang Shuai, Yu Qiqi, Li Dan, Zhang Lei, Gong Chunhong, Zhang Jingwei. (2023) Flexible regulation engineering of titanium nitride nanofibrous membranes for efficient electromagnetic microwave absorption in wide temperature spectrum. Nano Research, (1-10). [10.1007/s12274-023-6350-2]
5. Wanying Zhang, Fengyue Shi, Jianwen Wang, Yang Yang, Guangdong Zhao, Dongyu Zhao. (2024) Preparation and properties of a porous ZrO2/SiZrBOC ceramic matrix composite with high temperature resistance and low thermal conductivity. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 44 (2329). [PMID:22314500] [10.1016/j.jeurceramsoc.2023.11.007]
6. Ze Zhu, Xiaoqian Zhang, Ying Peng, Zhenfeng Guo, Yongshuai Xie, Benxue Liu, Guanghui Zhang, Luyi Zhu, Xinqiang Wang, Yonggang Jiang, Jian Feng. (2023) Design and characterization of spinnable carboxylate-based La–Zr oxide precursor towards scalable preparation of micro/nano lanthanum zirconate fibers for thermal management. CERAMICS INTERNATIONAL, 49 (26359). [10.1016/j.ceramint.2023.05.172]
7. Qinhui Ren, Yufu Ma, Fuhua Wei, Lan Qin, Hongliang Chen, Zhao Liang, Siyuan Wang. (2023) Preparation of Zr-MOFs for the adsorption of doxycycline hydrochloride from wastewater. Green Processing and Synthesis, 12 (1): [10.1515/gps-2022-8127]
8. Fuhua Wei, Haiyan Liu, Qinhui Ren, Lu Yang, Lan Qin, Hongliang Chen, Yufu Ma, Zhao Liang, Siyuan Wang. (2023) Preparation of Zr-MOF for the removal of norfloxacin from an aqueous solution. INORGANIC CHEMISTRY COMMUNICATIONS, 153 (110819). [10.1016/j.inoche.2023.110819]
9. Haoru Shan, Wenqiang Wang, Zhirong Wang, Jianlong Ge, Qixia Liu, Wei Zhang, Qiuxia Fu. (2023) General synthesis of flexible CuO nanoparticles-anchored ZrO2 nanofibrous membranes for catalytic oxidation of tetracycline. CHEMICAL ENGINEERING JOURNAL, 466 (143063). [10.1016/j.cej.2023.143063]
10. Xiaopan Qiu, Haoran Kong, Yuting Li, Qinhuan Wang, Yu Wang. (2022) Interface Engineering of a Ti4O7 Nanofibrous Membrane for Efficient Solar-Driven Evaporation. ACS Applied Materials & Interfaces, 14 (49): (54855–54866). [PMID:36449984] [10.1021/acsami.2c15997]
11. Haoyang Jiang, Nanbin Bao, Jianguo Tang, Huanjun Li. (2023) Anomalous mechanical strengthening of nanocomposite hydrogels upon swelling. CHEMICAL ENGINEERING JOURNAL, 455 (140573). [10.1016/j.cej.2022.140573]
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