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β-PbO2-WC复合涂层
International Journal of Electrochemical Science · 2023 · IF 1.5

Coating Electrode for Oxygen Evolution Reaction

Shiwei He,Ruidong Xu,Bohao Yu,Yuqing Guo,Zhongsheng Hua,Fuyuan Zhang,Huihong Lv

In this study, β-PbO2-WC composite coatings were synthesized on a substrate using the electrodeposition method in an electrolyte containing Pb 2+ and WC particles. The preparation process study shows that the β-PbO2 bath containing WC particles becomes more stable for an ultrasonic dispersion time within 30 minutes. WC particles in the β-PbO2 bath are positively charged, with anions being adsorbed onto the particles. Compared to the β-PbO2 composite electrode, the oxygen evolution overpotentials for the P-PbO2-WC electrode are decreased, which demonstrates an energy-saving effect. The nucleation behavior study shows that the co-deposition of WC particles into the layer has little effect on the crystal growth of P-PbO2. The main process during the deposition time of 0~5 min were the nucleation of the β-PbO2 grains, the adsorption of WC particles, growth of β-PbO2 grains, and WC particles coated.

研究领域: 材料科学 · 电化学
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