The preparation of δ-FeOOH/γ-Al2O3 under mild conditions as an efficient heterogeneous Fenton catalyst for organic pollutants degradation
The δ-FeOOH/γ-Al 2 O 3 composite were prepared under mild conditions by the activated alumina absorption of Fe 2+ followed by rapid oxidation by H 2 O 2 . The δ-FeOOH growing on γ-Al 2 O 3 was composed of nanoneedles , forming a 3D flower-like morphology with a diameter of ~10 nm to provide a large number of active sites. The effects of Fenton reaction conditions, such as catalyst dosage, H 2 O 2 concentration, phenol concentration, initial pH value and temperature, on the catalytic activity of δ-FeOOH/γ-Al 2 O 3 were investigated. Under the optimal conditions, about 97.4% of phenol and 81.6% of total organic carbon (TOC) were removed in 5 min and 2 h, respectively. In addition, with γ-Al 2 O 3 as macroscopic size carrier (the diameter of 1–2 mm), the catalyst could be easily reused 10 runs with no significant reduction in catalytic activity. The possible mechanism was discussed, and it revealed that OH· was the main active species for degradation of phenol into intermediates and further into CO 2 and H 2 O. The δ-FeOOH/γ-Al 2 O 3 also showed high catalytic activity and reusability in the treatment of real industrial wastewater , making it a promising catalyst for industrial application.
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