A new strategy for efficient detection of triflumuron residues in food: An electrochemical sensor derived from a Cu/Fe-BTC MOF-polymer
Triflumuron is an insect growth regulator belonging to the class of insecticides. It finds its primary application in the agricultural sector for the control of various pests, particularly certain beetles, aphids, locusts, and mites. In this paper, a Cu/Fe-BTC composite was synthesized through a straightforward solvothermal approach, subsequently employed as a precursor for the fabrication of an electrochemical sensor denoted as CuFe 2 O 4 @C . The latter exhibited a distinctive core-shell architecture achieved through annealing, and its application was focused on the sensitive detection of triflumuron. The electrochemical behaviour of CuFe 2 O 4 @C for the detection of triflumuron was evaluated by differential pulse voltammetry (DPV) under optimal conditions in wide concentrations from 1.0 × 10 −4 to 1.0 × 10 −12 mol·L −1 , where there existed a superior linear relationship between the current and the concentration of triflumuron with R 2 being 0.995. Meanwhile, CuFe 2 O 4 @C had a low limit of detection (LOD) of 922 fM for triflumuron. The CuFe 2 O 4 @C/GCE exhibited remarkable sensitivity, long-term stability, excellent reproducibility, and repeatability, as well as effective anti-interference capabilities. Additionally, CuFe 2 O 4 @C demonstrated its applicability for the quantitative determination of triflumuron in diverse real samples with commendable recovery rates. In conclusion, the electrochemical sensor not only displayed exceptional performance in terms of stability, reproducibility, and anti-interference, but also showcased its practical utility in quantifying triflumuron across various real-world samples.
危险品化学品经营许可证（带存储）