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TALANTA · 2024 · IF 5.6

Hydrophobic carbon quantum dots with red fluorescence: An optical dual-mode and smartphone imaging sensor for identifying Chinese Baijiu quality

Zihan Wang,Yang Liu,Meiqi Liang,Yihong Chen,Wenjuan Dong,Qin Hu,Shengmei Song,Shaomin Shuang,Chuan Dong,Xiaojuan Gong

Chinese Baijiu (Liquor) is a popular alcoholic beverage , and the ethanol content in Baijiu is closely related to its quality; therefore, it is of great significance to explore a facile, sensitive, and rapid method to detect ethanol content in Baijiu. Hydrophobic carbon quantum dots (H-CQDs) with bright red fluorescence (24.14 %) were fabricated by hydrothermal method using o -phenylenediamine, p -aminobenzoic acid, manganese chloride, and hydrochloric acid as reaction precursors. After the introduction of ultrapure water into the ethanol solution dissolved with H-CQDs, the aggregated H-CQDs resulted in significant changes in fluorescence intensity and absorbance. On this basis, a sensor for detecting ethanol by optical dual-mode and smartphone imaging was constructed. More importantly, the sensor can be used for detecting ethanol content in Chinese Baijiu with satisfactory results. This sensing platform has great potential for quality identification in Chinese Baijiu, broadening the application scope of CQDs in food safety detection.

研究领域: 食品安全检测 · 化学传感器 · 纳米材料
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Analytical Methods · 2022 ·Vol. 14 ·期 41 ·4122-4126 · IF 3.532

Rapid determination of ethanol content based on an optical fiber-device and R6G-indicator

Mingming Yan,Minglu Li,Dongning Wang,Huifang Chen

A rapid method for the determination of ethanol content is proposed and tested. A fluorescence detecting system, with a multimode fiber (MMF) sensing head, is employed. Rhodamine 6G (R6G) is applied as the fluorescent indicator. In the R6G aqueous solution, the molecules aggregate at high concentration, causing fluorescence quenching. Nevertheless, aggregation and quenching rarely occur in ethanol. Taking an ethanol and water mixture as the solvent, the photoluminescence (PL) intensity reflects the aggregation degree and the ethanol content. Based on this phenomenon, the contents of the ethanol–water mixture were measured through PL intensity detection. A limit of detection (LOD) at ∼0.1 vol% level was obtained in the range of 0–100%. Commercial Chinese baijiu and rubbing alcohol were tested and the results obtained were consistent with the label values. The detecting system is compact and of low-cost, and the detecting method is rapid, accurate and repeatable. There is good prospect of applications for the determination of ethanol content on-site.

CAS / MDL: 989-38-8 1310-73-2
研究领域: 分析化学 · 光学工程
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FOOD CHEMISTRY · 2019 · IF 5.399

Chemical composition, sensorial properties, and aroma-active compounds of ciders fermented with Hanseniaspora osmophila and Torulaspora quercuum in co- and sequential fermentations

Jianping Wei,Yuxiang Zhang,Yue Qiu,Hong Guo,Hongmei Ju,Yuwei Wang,Yahong Yuan,Tianli Yue

In this study, apple juice was fermented using Hanseniaspora osmophila X25-5 in pure culture as well as mixed culture with Torulaspora quercuum X24-4, which was inoculated simultaneously or sequentially. H. osmophila inhibited the growth of T. quercuum , while T. quercuum had little effect on the growth of H. osmophila. The simultaneous fermentation consumed relatively more sugar and resulted in the highest ethanol content. The production of organic acids varied depending on the yeast species employed and inoculation modality. Esters and alcohols were the main volatile families produced during fermentation, while ethyl esters and terpenes contributed most to the temperate fruity aroma. Gas chromatography-olfactometry (GC–O) showed that 3-methyl-1-butanol, ethyl 2-methylbutanoate, phenylethyl alcohol, β-phenethyl acetate, and β-damascenone were the most potent odorants in all samples. This study suggested that simultaneous fermentation with H. osmophila and T. quercuum might represent a novel strategy for the future production of cider.

研究领域: 食品科学 · 微生物学 · 化学
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MATERIALS SCIENCE FORUM · 2015 · IF 0

Polymerization of Dicyclopentadiene/Styrene in PolyHIPE

Wang Fa Xu,Fa Meng Sun,Jing Bo Liu,Xiao Fang Li,Fa Ai Zhang

A series of porous poly(styrene-divinylbenzene) monoliths (polyHIPE) was synthesized by high internal phase emulsions (HIPE). The effects of the ethanol contents on the microstructure of the polyHIPE were characterized by scanning electron microscopy and mercury intrusion porosimeter. The adsorption and release behaviors of the polyHIPE for a monomer mixture consisting of dicyclopentadiene (DCPD) /styrene (St) (DS, mass ratio of 9/1) were investigated. The polymerization of the mixture DS within pores of the polyHIPE was studied. The results showed that the microstructure of the polyHIPE was significantly influenced by the ethanol content. The increase of ethanol in the HIPE increased the internal pore diameter and decreased the pore volume of the polyHIPE, thus decreased the DS absorption and increased the release rate. The DS monomer can enter the pores(cavities, windows) and fill the original holes after the polymerization. Compared with conventional polymerization of DCPD/St, the poly(DCPD/St) (pDS) obtained from confined spaces possess higher molecular weight, broader molecular weight distribution, and higher Tg. As the pore diameter increased, the effect of space confinement reduced, and the performances of pDS were closed to that prepared by conventional polymerization.

研究领域: 材料科学 · 化学工程 · 高分子化学
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