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Facile Synthesis of Sulfate-Intercalated CoFe LDH Nanosheets Derived from Two-Dimensional ZIF-9(III) for Promoted Oxygen Evolution Reaction

Guolei Xiao,Weibin Chen,Yaming Cai,Shifan Zhang,Di Wang,Dandan Cai

Layered double hydroxide (LDH) has emerged as a promising electrocatalyst; however, the synthetic method usually requires high temperature and high pressure, and sulfate-intercalated LDH is rarely reported. Herein, the sulfate-intercalated CoFe LDH nanosheets were successfully fabricated at ambient temperature via a facile strategy, using two-dimensional ZIF-9(III) as a template and FeSO4as both etchant and iron source. When the as-prepared sulfate-intercalated CoFe LDH acts as an electrocatalyst, it presents superior electrocatalytic performance for the oxygen evolution reaction (OER), requiring low overpotential (η@10 mA cm−2= 218 mV) with a small Tafel slope of 59.9 mV dec−1in 1.0 M KOH, which compares favorably with commercial RuO2and most reported transition-metal electrocatalysts. The high catalytic activity of CoFe LDH might be ascribed to the large interlayer space distance originating from special SO42−ions and the strong synergistic effects between Fe and Co. This work provides a novel and feasible approach to designing highly efficient electrocatalysts based on advanced LDH materials for OER.Keywords:facile synthesis;sulfate-intercalated CoFe LDH;two-dimensional ZIF-9(III);electrocatalysts;oxygen evolution reaction