Hu Yue,Xu Zhenbo,Shi Haotian,Wang Benlong,Wang Liqiu,Zhang Lu-Wen
Rapid bubble capture is essential for collecting targeted gaseous media and eliminating floating impurities across aquatic environments. While the role of nanostructures during the collision of free-rising bubbles with super-aerophilic surfaces is well established, the fundamental contribution of microtextures in promoting initial capture, even before contact, has yet to be fully understood. We report the rising bubble-induced large deformation of the entrapped gas layer, rapidly thinning the liquid film to its rupture threshold and thus achieving an ultrafast bubble capture down to about 1 ms with an array of microcones, decorated with nanoparticles as a convenient example to obtain super-aerophilicity. This rapid capture is also very stable due to the hysteresis movement of three-phase contact lines that inspired a critical pressure criterion for ensuring gas-layer stability and capture efficacy. The present nano/microstructured surface supports prolonged, loss-free gas transport in challenging shear flow as well, providing robust bubble control strategies for diverse systems.
The flexible manipulation of underwater gas bubbles on solid substrates has attracted considerable research interest from scientists in the fields of water electrolysis, bubble microreactions, drug delivery, and heat transfer. Inspired by the oxygen-binding mechanisms of aquatic organisms, scientists have designed a series of interfacial materials for use in collecting gases, detecting and grading bubbles, and conducting microbubble reactions. Aerophilic surfaces are commonly used in underwater bubble manipulation platforms due to their excellent gas-trapping properties. However, during bubble transport, some of the bubbles are retained in the rough structure of the aerophilic surface and cause gas loss, which in the long run reduces the gas transport function. In addition, the aerophilic surface is prone to failure in high-humidity and high-pressure underwater environments. The lubricant-infused surface features an oil layer that remains stable on a rough substrate and is immiscible with water. Additionally, the bubbles are transported over the oil layer without causing losses other than those dissolved in water. These attributes make it more favorable than the aerophilic surface. Inspired by the unique properties of Nepenthes and cactus spines, we developed a patterned slippery surface [patterned lubricant-infused surface (PLIS)] through laser etching and ammonia etching that facilitates the coexistence of superaerophobic and aerophilic surfaces. The PLIS executes bubble capture utilizing a difference in wettability measuring 78°, transports bubbles through Laplace force and buoyancy, and regulates bubble release by restricting the contact area on the PLIS. The PLIS can be prepared rapidly and affordably in just about an hour, and its potential for large-scale production is high. Following tests for shear, acid and alkali resistance, and corrosion resistance, the PLIS exhibited impressive weathering resistance and appears to have potential for application in some extreme environments.
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