Fabricating controllable hierarchical pores on smooth carbon sheet for synthesis of supercapacitor materials
A smooth and defectless carbon sheet with thickness of 1–2 μm was prepared by loose medium component from coal. Then, porous carbon sheet materials were prepared by activation of the carbon sheet using KCl and KOH under 750 °C and N 2 atmosphere. Such materials have lattice defect and porous structure which were verified by emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman and N 2 adsorption-desorption. Their electrochemical performances were studied by cyclic voltammetry curves and constant current charge-discharge curves. The results showed that varing the content of KCl could control the distribution of the mesopore so as to change the specific capacitance. When carbon/KCl/KOH was at a mass ratio of 1:3:4, the specific capacitance reached up to 346 F g −1 at the current density of 0.1 A g −1 with high energy density and power density of 12 Wh kg −1 and 25 W kg −1 , respectively. The high specific capacitance of this material was corresponded to its porous structure with high specific surface area of 3627 m 2 g −1 . Based on the above structure features and performance results, this paper supplies a brand new and promising way for synthesis of supercapacitor materials .
危险品化学品经营许可证（带存储）