Haodong Gu,Li Tian,Qiuqi Zhang,Xiao You,Mengmeng Wang,Shaoming Dong,Jinshan Yang
Electromagnetic protection in extreme environments requires materials with excellent thermal insulation capability and mechanical property to withstand severe temperature fluctuations and complex external stresses. Achieving strong electromagnetic wave absorption (EMA) while sustaining these exceptional properties remains a significant challenge. Herein, a facile approach is demonstrated to fabricate a biomimetic leaf-vein MXene/CNTs/PI (MCP) aerogel with parallel venations through bidirectional freeze-casting method. Due to its multi-arch lamellar structure and parallel venations within the aerogel layers, the ultralight MCP aerogel (16.9 mg·cm −3 ) achieves a minimum reflection loss (RL min ) of −75.8 dB and a maximum effective absorption bandwidth (EAB max ) of 7.14 GHz with an absorber content of only 2.4 wt%, which also exhibits superelasticity and structural stability over a wide temperature range from −196 to 400 °C. Moreover, this unique structure facilitates rapid heat dissipation within the layers, while significantly impeding heat transfer between adjacent layers, achieving an ultralow thermal conductivity of 15.3 mW·m −1 ·K −1 for thermal superinsulation. The combination of excellent EMA performance, robust structural stability, and thermal superinsulation provides a potential design scheme under extreme conditions, especially in aerospace applications.
Breathable and stretchable conductive materials are ideal for healthcare wearable electronic devices. However, the tradeoff between the sensitivity and detection range of electronic sensors and the challenge posed by simple-functional electronics limits their development. Here, inspired by the bionic-leaf vein conductive path, silver nanowires (AgNWs)-Ti 3 C 2 T x (MXene) hybrid structure assembled on the nonwoven fabrics (NWF) is well sandwiched between porous polyborosiloxane elastomer (PBSE) to construct the multifunctional breathable wearable electronics with both high anti-impact performance and good sensing behavior. Benefiting from the high conductive AgNWs-MXene hybrid structure, the NWF/AgNWs-MXene/PBSE nanocomposite exhibits high sensitivity (GF = 1158.1), wide monitoring range (57 %), controllable thermal management properties, and excellent electromagnetic interference shielding effect (SE T = 41.46 dB). Moreover, owing to the wonderful shear stiffening effect of PBSE, the NWF/AgNWs-MXene/PBSE possesses a high energy absorption performance. Combining with deep learning, this breathable electronic device can be further applied to wireless sensing gloves and multifunctional medical belts, which will drive the development of electronic skin, human-machine interaction, and personalized healthcare monitoring applications.
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