Preparation of primary amine-terminated polybutadiene from cis-polybutadiene
As a telechelic polymer, the primary amine-terminated cis -polybutadiene (AmTPB) has a wide application prospect due to its active hydrogens in both end groups and high cis 1,4-chain structure. In this work, the AmTPB with high cis -1,4 content (>96%) was prepared for the first time by taking cis -polybutadiene as a starting material. Firstly, the aldehyde-terminated polybutadiene (ATPB) in a molecular weight range of 600–8000 g/mol was successfully synthesized by oxidative degradation of epoxidized polybutadiene prepared by reaction-controlled phase-transfer catalysis. After a simple post-processing, the AmTPB was prepared via two steps, i.e. the efficient synthesis of oxime-terminated polybutadiene (OTPB) from ATPB and the subsequent selective reduction of OTPB. The results showed that the high cis 1,4-chain structure of polybutadiene did not change in all the reactions.
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