ENERGY & FUELS
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2022
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IF 4.654
Shenglong Shi,Jinsheng Sun,Kaihe Lv,Qingzhi Wen,Yingrui Bai,Jingping Liu,Xianbin Huang,Jintang Wang,Jiafeng Jin,Jian Li
In view of challenges such as the long dissolution time of powder friction reducers in high-salinity water, poor environmental friendliness of water-in-oil (W/O) emulsion friction reducers, and the poor proppant-carrying capacity of conventional slickwater, a novel variable viscosity friction reducer suspension (EACM) with high salt tolerance, low damage, and strong proppant-carrying capacity was prepared by dispersing salt-tolerant polymer powder in alcohol solvents. The solubility, drag reduction ability, viscoelasticity, proppant-carrying capacity, temperature and shear resistance, and gel breaking ability of EACM were investigated. The results showed that the best solvent for the friction reducer suspension was polyethylene glycol 400, in which EACM exhibited a rapid dissolution rate with a thickening rate of 89.5% within 2 min. Due to the synergic effect between fumed silica and polyamide wax as antisedimentation agents, both at a concentration of 2.0 wt %, the EACM could remain stable for 60 days. EACM showed an excellent drag reduction performance at both low and high viscosities in 100 000 mg/L salt brine. Specifically, a drag reduction of up to 72.4% was obtained using 0.21 wt % EACM (4.65 mPa s), and a 60.8% drag reduction was achieved using 1.0 wt % EACM (35.5 mPa s). When the concentration increased from 0.13 to 1.0 wt %, the EACM solution changed from viscous to elastic; the spatial network structure of the solution became more compact, and the proppant-carrying capacity was enhanced. The viscosity of 1.6 wt % EACM solution could be maintained at 55.9 mPa s after shearing at 90 °C for 120 min at a shear rate of 100 s–1. EACM solution also exhibited the advantages of easy breaking and low residue. This paper provides guidance for the design and selection of a novel friction reducer suspension in the oil and gas industry.
研究领域:
石油工程
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材料科学
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化学工程
✓ 已验证
产品关联
DOI
高影响因子
Gels
·
2025
·Vol. 11
·期 5
·344
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IF 5.3
Shenglong Shi,Jinsheng Sun,Shanbo Mu,Kaihe Lv,Yingrui Bai,Jian Li
Aiming at the problem that conventional friction reducers used in fracturing cannot simultaneously possess properties such as temperature resistance, salt resistance, shear resistance, rapid dissolution, and low damage. Under the design concept of “medium-low molecular weight, salt-resistant functional monomer, supramolecular physical crosslinking aggregation, and enhanced chain mechanical strength”, acrylamide, sulfonic acid salt-resistant monomer 2-acrylamide-2-methylpropanesulfonic acid, hydrophobic association monomer, and rigid skeleton functional monomer acryloyl morpholine were introduced into the friction reducer molecular chain by free radical polymerization, and combined with the compound suspension technology to develop a new type of multi-functional viscous friction reducer suspension (SAMD), the comprehensive performance of SAMD was investigated. The results indicated that the critical micelle concentration of SAMD was 0.33 wt%, SAMD could be dissolved in 80,000 mg/L brine within 3.0 min, and the viscosity loss of 0.5 wt% SAMD solution was 24.1% after 10 min of dissolution in 80,000 mg/L brine compared with that in deionized water, the drag reduction rate of 0.1 wt% SAMD solution could exceed 70% at 120 °C and still maintained good drag reduction performance in brine with a salinity of 100,000 mg/L. After three cycles of 170 s −1 and 1022 s −1 variable shear, the SAMD solution restored viscosity quickly and exhibited good shear resistance. The Tan δ (a parameter characterizing the viscoelasticity of the system) of 1.0 wt% SAMD solution was 0.52, which showed a good sand-carrying capacity, and the proppant settling velocity in it could be as low as 0.147 mm/s at 120 °C, achieving the function of high drag reduction at low concentrations and strong sand transportation at high concentrations. The viscosity of 1.4 wt% SAMD was 95.5 mPa s after shearing for 120 min at 140 °C and at 170 s −1 . After breaking a gel, the SAMD solution system had a core permeability harm rate of less than 15%, while the SAMD solution also possessed the performance of enhancing oil recovery. Compared with common friction reducers, SAMD simultaneously possessed the properties of temperature resistance, salt resistance, shear resistance, rapid dissolution, low damage, and enhanced oil recovery. Therefore, the use of this multi-effect friction reducer is suitable for the development of unconventional oil reservoirs with a temperature lower than 140 °C and a salinity of less than 100,000 mg/L.
研究领域:
石油工程
·
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子