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A synergistic coordination-reduction interface for electrochemical reductive extraction of uranium with low impurities from seawater

Guo Hongliang,Hu Enmin,Wang Yihao,Ou Zhenhong,Huang Bichu,Lei Jia,Liu Huanhuan,He Rong,Zhu Wenkun

Electrochemical extraction of uranium from seawater is a promising strategy for the sustainable supply of nuclear fuel, whereas the current progress suffers from the co-deposition of impurities. Herein, we construct a synergistic coordination-reduction interface in CMOS@NSF, achieving electrochemical extraction of black UO 2 product from seawater. The internal sulfur of CoMoOS tailors the electron distribution, resulting in the electron accumulation of terminal O sites for strong uranyl binding. Meanwhile, the interfacial connection of CoMoOS with Ni 3 S 2 accelerates the electron transfer and promoted the reductive properties. Such synergistic coordination-reduction interface ensures the formation and preservation of tetravalent uranium, preventing the co-deposition of alkalis in crystalline transformation. From natural seawater, CMOS@NSF exhibits an electrochemical extraction capacity of 2.65 mg g −1  d −1 with black UO 2 solid products as final products. This work provides an efficient strategy for the electrochemical uranium extraction from seawater with low impurities.