JOURNAL OF NANOPARTICLE RESEARCH
·
2019
·Vol. 21
·期 1
·1-11
·
IF 2.009
You Xiao,Feng Qian,Yang Jinshan,Huang Kai,Hu Jianbao,Dong Shaoming
Exploring the graphene material is premised on the graphene sheets being single-layer graphene (SG) or bi-layer graphene (BG) state, and graphene suspension keeps stably disperse are critical. Since graphene has a highly conjugated system, it is easy to conduct strong π-π interaction with conjugated structure. In this paper, by dispersing graphene powder at low boiling point solvent water or ethanol, ensuring the excellent properties of graphene are not affected by the solvent, which simultaneously solves the difficulty of removing organic solvents. On the basis the concentration of graphene suspension can be greatly improved and no damage to the graphene sheets in the presence of dispersant. This method allows us to prepare a large amount of excellent graphene dispersion, making it possible to obtain graphene-based materials through the low-cost technology, as well as opening up the opportunity for exploiting the application of this nanocarbon material with unique structure.
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研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
Journal of Water Process Engineering
·
2023
·
IF 7
Ce Wang,Yuling Lü,Chao Song,Jiakai Shi,Peng Zhang,Limin He
The poor adhesion of oil droplets and bubbles in the flotation process leads to inefficient separation of oil and water. In this paper, condensate bubbles were prepared by partial vaporization of low boiling point condensate to increase the oil removal effect. The purpose of partial vaporization was achieved by bringing emulsified condensate droplets into the produced water at different temperatures. The structure of the bubble is composed of condensate film wrapped around the gas core of the vaporized portion. The contact angle between condensate bubble and oil surface is >150°, which show great similarity-intermiscibility. The average bubble size prepared at 303 K - 318 K is 20 - 100 μm. The stability of bubbles decreased with an increase in temperature, the half-decay time decreased from 340 s to 110 s, and the zeta potential decreased from −31 mV to −12 mV. However, the gas hold-up of the bubbles first increased and then decreased with the increase in temperature, while the highest gas holdup was 21 % at 313 K. The rise of the condensate/water ratio (R con-wat ) did not increase the stability of the bubbles, but the gas holdup increase. The condensate bubble flotation experiment found that at the optimum temperature 313 K, the oil removal efficiency of 1.5 % R con-wat can reach 85 %. In contrast, the oil removal efficiency of the dissolved air flotation experiment is <75 %. Otherwise, with a smaller amount of flocculant (ferric chloride), the oil removal efficiency of condensate bubble flotation can reach >95 %.
研究领域:
石油工程
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
POLYMER JOURNAL
·
2015
·Vol. 48
·期 2
·169-175
·
IF 1.653
Wu Qi,Pan Lili,Wang Haijiang,Deng Wenxiu,Yang Guangjie,Liu Xikui
Polymeric aerogels have great potential in numerous fields because of their unique combination of thermal and electrical properties, and lightweight porous structures. However, the laborious supercritical CO 2 drying method required for making these aerogels limits their commercial availability. Here we demonstrate a green and scalable method for preparing high-performance polyimide (PI) aerogels using a low-boiling-point solvent mixture of tetrahydrofuran/methanol, and especially using sublimation drying instead of laborious supercritical CO 2 drying. The monolithic and powder polyamic acid aerogels can be prepared easily; after thermal imidization, PI aerogels with nanofibrous morphology, low density and high thermal stability can be obtained. This green, scalable and cost-effective process will facilitate the application of high-performance PI aerogel materials in many fields, in particular those in which high-temperature resistance is important.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Dan Li,Ying Zhao,Yunxiao Zhang,Jinliang An,Jiaqiang Huang,Jinglei Yang
The facile encapsulation of perfluoro liquids that are hydrophobic but not lipophilic into liposomes or microcapsules presents a significant challenge in the fields of biomedicine, dynamic optics, functional chemical applications, etc. This is due to their chemical inertness and physical immiscibility, particularly those with low boiling points. In this study, a novel strategy based on a double emulsion template via solvent evaporation is proposed after investigating the mechanism of three-phase emulsion systems. The perfluoro liquid droplets can be easily emulsified into a polymer solution as the second emulsion layer, where the polymer shell is formed during solvent evaporation in the continuum medium under proper processing controls. The morphology of particles is predictable and fits well with the linear model derived from Neumann’s triangle in three-phase systems. Furthermore, a comprehensive study on the encapsulation of perfluoro ketone, which is widely used as a green fire extinguisher agent, is conducted as an example. The encapsulated perfluoro ketone showed instant thermal response upon heating while maintaining a good shelf life at room temperature. The remarkable fire suppression performance exhibited great potential for practical applications. This work offers more insight into the encapsulation of “naughty” perfluorinated chemicals and provides more possibilities for extended applications.
研究领域:
生物医学
·
动态光学
·
功能化学
·
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）