Peiyao Yan,Wei Zhao,Yanjun Wang,Yuanyuan Jiang,Changlin Zhou,Jingxin Lei
Welding technology of polymer materials, serving as an exceedingly good tactics to save materials, reduce cost, and reduce material loss, is only extensively applied in thermoplastic materials for the moment. Recently, a new class of polymer, known as vitrimer, has attracted the eye of researchers because it realizes the reprocessing and reshape of thermosets and possesses many excellent functions, such as multishape memory, healing, and surface welding. Among these, the vitrimer makes the surface welding of thermosetting material possible. In this paper, carbon nanotubes-polyurethane vitrimer nanocomposites with the capability of surface welding controlled by heat and near-infrared (NIR) light are successfully prepared. Here, the effects of surface welding are characterized by lap shear tests and optical microscope. In addition, from the control experiments, it is found that the shear strength of the light-welding sample under NIR illumination for 1 min is greater than that of the heat-welding sample at 110 °C for 10 min. Furthermore, thermosetting polyurethane has been applied in many fields, and it is hoped that the findings, especially near-infrared welding technology, will make some contributions for welding technology of polymer.
Significant advancements in flexible photoelectric devices have been achieved through extensive research on flexible transparent conductive electrodes (FTCEs) based on silver nanowires (AgNWs). However, two key challenges that need to be addressed are the high contact resistance of AgNWs and poor interface adhesion between AgNWs and the flexible substrate. In this study, we present a composite electrode comprising polydopamine-grafted cellulose nanofibers (PDA-TCNF) and AgNWs, fabricated through an interface customization strategy combined with UV-induced plasma welding. To enhance interfacial crosslinking, N , N -bis(acryloyl)cysteamine (BACA) was introduced as a surface adsorbate for AgNWs. The composite electrode exhibited rapid plasma welding of AgNWs under low-intensity UV irradiation. The optimized PDA-TCNF/AgNW-S/3 electrode demonstrated a sheet resistance of 7.26 Ω sq. −1 with a remarkable light transmittance of 85.7 %. The interface customization strategy facilitated enhanced diffusion of silver atoms at AgNW junctions during UV-induced heating, thereby strengthening their welding capability. These electrodes serve as high-performance FTCEs for electroluminescent devices and transparent electric heaters. Our work proposes a simple method to fabricate superior FTCEs by integrating nanocellulose with AgNWs, offering a promising environmentally friendly material for flexible optoelectronic applications.
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