Free radical mechanism investigation of the side-chain alkylation of toluene with methanol on basic zeolites X
The side-chain alkylation of toluene represents a novel, environmentally friendly, and low cost route for the production of styrene . However, the yield of styrene produced in this way is currently low, and the mechanism responsible for the side-chain alkylation of toluene is poorly understood. Furthermore, the reason for the higher catalytic efficiency of CsX over NaX and KX remains unclear. In this work, the free radical mechanism of the side-chain alkylation of toluene over basic zeolite X has been elucidated using quantum chemical calculations , together with isotope tracing experiments and the reaction between p -nitrotoluene and methanol. The adsorption isotherm of methanol showed that Cs + ions could block methanol from accessing the β-cage, which is where the side-chain alkylation reaction occurred. Furthermore, the H–D exchange results between toluene and deuterated toluene (C 6 D 5 CD 3 ) showed that CsX was more efficient as a catalyst than KX for the conversion of toluene to the corresponding benzyl radical (C 6 H 5 CH 2 • ). These two results therefore explain the higher catalytic activity of CsX towards side-chain alkylation than KX. Based on the free radical mechanism, the selectivity of styrene could be increased from 17.4% to 59.4% using CO 2 as carrier gas instead of N 2 .
危险品化学品经营许可证（带存储）