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CARBON · 2021 · IF 9.594

Crumpled particles of ethanol-wetted graphene oxide for medium-temperature nanofluidic solar-thermal energy harvesting

Jingyi Zhang,Lei Shu,Chao Chang,Xiaoxiang Li,Ruiming Lin,Benwei Fu,Chengyi Song,Wen Shang,Peng Tao,Tao Deng

Direct absorption of sunlight with carbon nanofluids is a facile way to efficiently harvest solar-thermal energy, but poor dispersion stability of nanofluids under elevated temperatures severely limits their applications. Herein, we report a general strategy to prepare stably-dispersed medium-temperature solar-thermal nanofluids by employing crumpled particles of ethanol-wetted graphene oxide sheets as the self-dispersible photothermal converters. The crumpled particles simultaneously possess intensively-deformed surface structure, a low density and a small particle size. Such features weaken the inter-particle van der Waals attraction and gravitational sedimentation of the crumpled particles, thereby enabling their long-term stable dispersion within commercial thermal storage oils. Uniform dispersion of nanofluids was maintained after continuous heating for 2 weeks under a heating temperature up to 200 °C. The homogenously dispersed nanofluids also achieved high solar absorptance with low particle loadings, and retained the large heat capacity and suitable viscosity. These combined advantageous thermophysical properties enabled consistent high-performance medium-temperature direct absorption-based nanofluidic solar-thermal energy harvesting under large-flux solar illumination.

CAS / MDL: 63148-62-9 7722-84-1
研究领域: 材料科学 · 纳米技术 · 太阳能 · 热能工程
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