High-tear resistant gels crosslinked by DA@CNC for 3D printing flexible wearable devices
Photocurable gels have broad application prospects in biomedicine, bionics, flexible wearable devices and other fields. However, there are still some problems in the current photocurable gels, such as notch sensitivity, that is, poor tear resistance. In this study, we provided a photocurable gel with excellent tear resistance. The gel prepolymer is mainly composed of hydroxymethylacrylamide (NAM) and cellulose nanocrystals (CNC) modified with dopamine hydrochloride (DA), referred to as DA@CNC. After photocuring, the prepared gels show excellent mechanical properties such as tear resistance, elasticity and toughness. The introduction of DA@CNC not only endows gels with a large amount of energy dissipation through hydrogen bond crosslinking, but also effectively resists crack expansion as a nano-sized reinforcing phase, which greatly improves the tear resistance of the gels. Even at a 40 % gap, the elongation at break of the gel can still reach 1445 %. In addition, the DA can endow the gel with good electrical conductivity and excellent sensitivity (GF = 23.8). Some flexible wearable devices like finger sleeve and wristband can be customized by photocurable 3D printing using the gel with high toughness. This high-performance gel has great application potential in flexible wearable devices.
危险品化学品经营许可证（带存储）