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iScience · 2024 · IF 4.6

Regulable crack patterns for the fabrication of high-performance transparent EMI shielding windows

Yongmao Guan,Liqing Yang,Chao Chen,Rui Wan,Chen Guo,Pengfei Wang

Crack pattern-based metal grid film is an ideal candidate material for transparent electromagnetic interference shielding optical windows. However, achieving crack patterns with narrow grid spacing, small wire width, and high connectivity remains challenging. Herein, an aqueous acrylic colloidal dispersion was developed as a crack precursor for preparing crack patterns. The ratio of hard monomers in the precursor, the coating thickness, and the drying mediation strategy were systematically varied to control the spacing and width of the crack patterns. The resulting dense and narrow crack patterns served as sacrificial templates for the fabrication of patterning metal grid films on transparent substrates, intended for optoelectronic applications. These films demonstrated excellent optoelectronic properties (82.7% transmission at 550 nm visible light, sheet resistance 4.1 Ω/sq) and strong EMI shielding effectiveness (average shielding effectiveness 33.6 dB at 1–18 GHz), showcasing their potential as a scalable and effective transparent EMI shielding solution.

CAS / MDL: 79-10-7 9041-29-6
研究领域: 材料科学 · 纳米技术
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS · 2021 · IF 4.539

Design of an efficient antifouling strategy for underwater optical window based on chlorine generation

Shudi Zhang,Juan Xi,Jiajia Wu,Peng Wang,Feng Lin,Dun Zhang

Underwater optical instruments are subjecting marine biofouling, which leads to inaccuracy of data acquisition. In order to solve the biofouling of the optical instrument, a specific electrochemical chlorination device with highly efficient chlorine evolution reaction (CER) catalyst prepared by potentiostatic electrodeposition was designed and utilized. The catalytic activity, CER selectivity , and durability of the as-prepared CER catalyst are better than the noble metal catalysts in near-neutral seawater . Compared with the common optical glass , the application of the chlorination instrument effectively inhibits the bacterial settlement, and helps to maintain high light transmittance of the optical window. This work offers a useful strategy for the antifouling of marine optical equipment .

CAS / MDL: 10026-22-9
研究领域: 材料科学 · 海洋科学 · 光学工程
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Journal of Materials Chemistry C · 2012 ·Vol. 1 ·期 6 ·1168-1173 · IF 0

Strong red and NIR emission in NaYF4:Yb3+,Tm3+/QDs nanoheterostructures

Jie Chang,Ye Liu,Jie Li,Suli Wu,Wenbin Niu,Shufen Zhang

Due to the strong tissue absorption of short-wave-length light below 600 nm, in vivo imaging based on UCNPs as luminescent probes is still limited. The NIR spectral range (700–1100 nm) and the red region (600–700 nm) are referred to as the “optical window” of the biological tissues because the light scattering, absorbance and autofluorescence of tissue are minimum in this range. Here we synthesized NaYF4:Yb3+,Tm3+/CdS nanoheterostructures. In the nanoheterostructures, the red (700 nm) and NIR (802 nm) emissions of NaYF4:Yb,Tm were enhanced by 7.3 times, while the blue emission peak at 476 nm nearly disappeared and no peak of CdS appeared. Transmission electron microscopy (TEM) images show that the morphology of the binary nanoparticles is predominantly peanut-like and the X-ray diffraction (XRD) patterns of the NaYF4:Yb3+,Tm3+/CdS nanoheterostructure were assignable to both wurtzite phase CdS and hexagonal phase NaYF4:Yb3+,Tm3+. In comparison, introducing Cd2+ ions or S2− ions or preparation of physical mixture of NaYF4:Yb3+,Tm3+ and CdS did not enhance the red (700 nm) and NIR (802 nm) emissions of NaYF4:Yb, Tm. These results indicated that the interactions in the NaYF4:Yb3+,Tm3+/CdS nanoheterostructure played a key role for enhancing the NIR emission of NaYF4:Yb3+,Tm3+ nanocrystals. QDs act as a sub energy level to mediate energy transfer of Tm3+. To evaluate the effect of other QDs on the upconverted fluorescence spectrum of NaYF4:Yb3+,Tm3+, NaYF4:Yb3+,Tm3+/CdSe nanoheterostructures were also prepared by a similar method. The upconverted fluorescence spectra indicated that by conjugation with CdSe, the NIR emission at 802 nm of NaYF4:Yb3+,Tm3+ was also enhanced greatly.

研究领域: 材料科学 · 生物医学工程 · 光学
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JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY · 2014 ·Vol. 14 ·期 6 ·4139-4146 · IF 1.339

Enhancement and Regulation of Fluorescence Emission from NaYF4:Yb3+, Er3+ Nanocrystals by Codoping Mn2+ Ions

He Enjie,Zheng Hairong,Gao Wei,Tu Yinxun,Lu Ying,Tian Huani,Li Guian

NaYF4:Yb3+, Er3+, Mn2+ nanocrystals with cubic crystal phase were obtained by a facile solvothermal method through doping a proper amount of Mn2+ ions to the nanocrystals. The results of XRD and TEM showed that the as-prepared samples were well crystallized and their average size was about 25 nm. Under excitations at 978.5 nm and at 532 nm, obvious enhancement and regulation of upconversion and downconversion fluorescence were obtained. Upconversion emission spectra indicate that these effects were independent of doped concentrations of Er3+ and Yb3+, excitation power, and the excitation wavelength in the current study. It is concluded that the enhancement of fluorescence emissions is mainly due to the change of local symmetry around Er3+ ions, while the regulation of red-to-green ratios was caused by efficient energy transfer between Er3+ and Mn2+ ions. This kind of upconversion material has a great potential in bioimaging and drug delivery since the excitation and emission falls into the region of “optical window” of biological tissues.

研究领域: 材料科学 · 纳米技术 · 生物医学工程 · 光学
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