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Advanced Electronic Materials · 2021 ·Vol. 8 ·期 4 ·2100997 · IF 7.295

Combustion Synthesized Electrospun InZnO Nanowires for Ultraviolet Photodetectors

Junyu He,Peilong Xu,Ruifu Zhou,Hao Li,Hongliang Zu,Jun Zhang,Yuanbin Qin,Xuhai Liu,Fengyun Wang

Ultraviolet (UV) photodetectors play an important role in numerous commercial and scientific applications. The UV photodetectors based on binary-cation indium zinc oxide (InZnO) thin films exhibit great performance enhancement, compared with their single-cation counterparts. However, UV photodetectors based on 1D InZnO nanowires could potentially exhibit more superior optoelectrical performance, due to the large surface-to-volume ratio and favorable carrier transport characteristics of nanowires. This work has combined combustion synthesis with electrospinning technique to efficiently fabricate InZnO nanowire-based UV photodetectors. At the annealing temperature of 375 °C, the newly designed InZnO nanowire photodetectors exhibit excellent photoelectric performance under the irradiation of 310 nm UV light, including a photo-to-dark current ratio of 1.2 × 10 4 , a photo responsivity of 2.8 × 10 3 A W –1 , and a high detectivity of 2.4 × 10 16 Jones. This study not only demonstrates the opportunity to construct new-generation transparent electronics based on 1D metal oxide nanowires but also sheds new light on how to further decrease the annealing temperature of metal oxide nanowire devices for low-temperature fabrication processes.

研究领域: 材料科学 · 纳米科技 · 光电子学 · 半导体器件 · 功能材料
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RSC Advances · 2019 ·Vol. 9 ·期 14 ·8039-8047 · IF 3.049

Structural, optical and photoelectric properties of Mn-doped ZnO films used for ultraviolet detectors

Peng Gu,Xinghua Zhu,Dingyu Yang

Mn-doped ZnO (MZO) films were prepared on glass substrates using sol–gel dip-coating technology. The microstructural, morphological, optical and photoelectric properties of MZO films were investigated at different withdrawal speeds (WS: 20, 40, 60 and 80 mm s−1). The X-ray diffraction (XRD) patterns showed that all the films obtained were polycrystalline with a hexagonal structure, and the highest crystallinity of MZO films was observed as films were deposited at 40 mm s−1. The UV-Vis spectra revealed that the average optical transmittance of all samples was over 60% and the energy band gap of films decreased from 3.616 to 3.254 eV with the increase in withdrawal speed. The formed Au/MZO/Au photodetectors (PDs) indicate that a device prepared at 40 mm s−1 shows superior properties both in response speed and detection capability, and the rise time is 1.871 s and fall time is 3.309 s at 365 nm for 3 V bias and the detectivity (D*) reaches ∼1.7 × 1010 Jones. Moreover, the responsivity of PDs is also affected by the distance between Au electrodes and external bias. This research provides a simple way to fabricate the UV PDs based on MZO films with faster response and higher detectivity.

研究领域: 材料科学 · 半导体物理 · 光电子学 · 薄膜技术 · 纳米材料
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JOURNAL OF ALLOYS AND COMPOUNDS · 2017 · IF 3.133

Synthesis of PbS-CH3NH3PbI3 core-shell nanoparticles with enhanced photoelectric properties

Ming Li,Xiaoqin Yuan,Haoran Ruan,Xiandong Wang,Yongping Liu,Zhenhuan Lu,Jiefeng Hai

A new method for synthesizing freestanding PbS-CH 3 NH 3 PbI 3 (MAPI) core-shell nanoparticles (NPs) with enhanced light absorption and photoelectric properties was reported. The transmission electron microscopy (TEM) and energy dispersive spectrometer (EDS) analysis confirmed the core-shell structure of the obtained sample. The Vis-NIR spectra proved the core-shell sample absorbed light both in visible and near infrared region . For comparison, oleic acid/oleylamine molecule capping PbS NPs, MAPI molecule capping PbS NPs, and PbS-MAPI core-shell NPs were used to fabricate Schottky solar cells. PbS-MAPI core-shell NPs based solar cells delivered a photocurrent response from both the PbS and MAPI, and achieved the highest overall PCE.

研究领域: 材料科学 · 纳米科技 · 光电子学 · 能源材料 · 半导体物理
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ELECTROCHIMICA ACTA · 2012 · IF 3.832

Coaxial electrospun TiO2/ZnO core–sheath nanofibers film: Novel structure for photoanode of dye-sensitized solar cells

Pingfan Du,Lixin Song,Jie Xiong,Ni Li,Zhenqiang Xi,Longcheng Wang,Dalai Jin,Shaoyi Guo,Yongfeng Yuan

Novel TiO 2 /ZnO core–sheath nanofibers (NFs) film was fabricated through an extraordinary coaxial electrospinning technique . Dye-sensitized solar cells (DSSCs) were assembled using the TiO 2 /ZnO NFs film as photoanode . FESEM , TEM, FTIR , XRD , XPS and UV–vis were used to characterize the NFs electrode film. Photocurrent–voltage ( I – V ) characteristic, incident photo-to-current conversion efficiency (IPCE) spectrum, and electrochemical impedance spectroscopy (EIS) measurements were performed to evaluate the DSSCs performance. The results reveal that the DSSCs based on the TiO 2 /ZnO core–sheath NFs are superior to their bare TiO 2 NFs-based counterparts. Compared with the latter, the overall energy conversion efficiency was enhanced from 4.47 to 5.17%. And the possible mechanism for this enhancement was discussed.

研究领域: 材料科学 · 纳米技术 · 能源材料 · 光电化学 · 半导体薄膜
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