Zhao Cui,Meng Zhang,Yang Yuan,Hui Jia,Huu Hao Ngo,Jie Wang
The focus of this study is on the enhanced concentration effect of the pump effect in forward osmosis (FO) and electroosmotic integrated chip. The study investigates the strengthening effect of the FO process, driven by the pump effect, on the electroosmotic flow process under the same energy consumption, using low-concentration heavy metal ions (Cr 3+ ) as the target enrichment. In the chip system, the pump effect, caused by capillary pressure difference, successfully replaces the osmotic pressure of the draw solution as a new driving force for the FO process. By adjusting the size and number of channels and avoiding errors, the study achieves the highest efficiency of the FO process in the chip, concentrating Cr 3+ from 1.26 × 10 −4 mol/L to 8.01 × 10 −4 mol/L (6.4 times) within 32 min. Excluding the influence of the electrokinetic (EK) limit of low-concentration samples, the concentration efficiency of an individual electroosmotic chip in this study is positively correlated with cross-nanochannel voltage (V cn ). The integrated FO and electroosmosis chip reduce the duration required to concentrate 50 mL Cr 3+ sample to the limit from 90 min to 16 min (5.6 times) compared to the single electroosmotic process. Furthermore, a series of Cr 3+ samples with concentrations below the detection limit of the UV–vis spectrophotometer were concentrated and detected by the integrated chip. The results indicate that the concentration limit of the FO-electroosmotic integrated chip for samples can increase the detection limit of Cr 3+ from 1.37 × 10 −4 mol/L to 3.67 × 10 −6 mol/L.
In the present study, a poly(butyl methacrylate-co-ethylene dimethacrylate) (poly(BMA–EDMA)) monolithic column modified with allyloxy-cucurbit[6]uril (ACB[6]) was prepared with an in situ polymerization process. A polymer monolith microextraction method was developed with the modified monolithic column for the preconcentration of estrogen combined with high performance liquid chromatography. The various experimental parameters affecting the extraction capacity were investigated and optimized with an orthogonal experiment design, L16(45). Under the optimum conditions, we obtained acceptable linearities, low limits of detection, and good intra-day/inter-day relative standard deviations. Hydrophobic interactions, π–π stacking, and hydrogen bonding interactions contributed to the extraction efficiency of the ACB[6]@poly(BMA–EDMA) monolithic column. The present method was employed to determine estrogens in cosmetic samples and the accuracy was assessed through recovery experiments. The obtained recovery values were in the range of 80.1–109.4% with relative standard deviations less than 9.9%.
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