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NEW JOURNAL OF CHEMISTRY · 2018 ·Vol. 42 ·期 6 ·4432-4442 · IF 3.201

Porous nanocomposite membranes based on functional GO with selective function for lithium adsorption

Dongshu Sun,Minjia Meng,Yao Lu,Bo Hu,Yongsheng Yan,Chunxiang Li

An hybrid membranes based on functional GO nanosheet for selective adsorption lithium from compound was great potential. Here, a simple and efficient methodology was reported to obtain high stability, selectivity, and antifouling properties. More importantly, we studied the selective adsorption capacity of the fabricated membranes to lithium under a high magnesium and low lithium environment. The results showed that the fabricated membrane exhibited excellent lithium adsorption and highly selective adsorption efficiency. The fabricated membranes presented a relatively lower contact angle (67.226°) and a higher membrane flux (13.62 mL cm−2 min−1), which indicated that the fabricated membrane had a high hydrophilicity because the presence of carboxylic and hydroxyl groups of GO could enhance the interaction between the membrane and water. Moreover, the perm-selectivity results (β values were greater than 7) and regeneration ability (90.9% of the maximum adsorption capacity was retained after 10 cycles) were shown. The overall results suggested that functional GO can be considered as an effective additive for inorganic–organic composite membranes for the selective adsorption of lithium. It is worth mentioning that this methodology can be applied to selectively identify and adsorb lithium and is environmentally friendly, as it does not lead to secondary pollution.

研究领域: 材料科学 · 环境科学
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JOURNAL OF APPLIED POLYMER SCIENCE · 2019 ·Vol. 136 ·期 32 ·47842 · IF 2.188

Investigation of covalently grafted polyacrylate chains onto graphene oxide for epoxy composites with reinforced mechanical performance

Yankun Xie,Weiqu Liu,Chunhua Liu,Sha He,Fengyuan Zhang,Hongyi Shi,Maiping Yang,Zhengfang Wang

To enhance the dispersion and interfacial interaction of graphene–epoxy matrix, polyacrylate chains grafted graphene oxide (PA-GO) was manufactured with A-174 functionalized GO (A-GO), methyl acrylate, and glycidyl methacrylate via free-radical random copolymerization technique. Fourier transform infrared, thermogravimetric analysis, X-ray photoelectron spectrum, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and nuclear magnetic resonance were performed to investigate the structure of A-GO and PA-GO. Then, the PA-GO was incorporated into epoxy resin via in situ solution intercalation dispersion method in order to form an interpenetrating network structure with epoxy resin. Field emission scanning electron microscope results indicate that the PA-GO exhibits excellent dispersion and interfacial compatibility in the epoxy matrix. In compared with pure epoxy, the tensile strength and impact strength of the epoxy composite with 1 wt % PA-GO were shifted from 62.78 ± 2.54 to 70.68 ± 2.02 MPa (about 12.6%) and 3.55 ± 0.41 to 4.98 ± 0.33 kJ m −2 (about 40.3%), respectively. Moreover, increased storage modulus is also observed in the dynamic mechanical analysis measurements compared with that of neat epoxy resin. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47842.

研究领域: 材料科学 · 高分子科学 · 复合材料 · 机械工程
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