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PRECISION ENGINEERING-JOURNAL OF THE INTERNATIONAL SOCIETIES FOR PRECISION ENGINEERING AND NANOTECHNOLOGY · 2014 · IF 1.403

Electrogenerated chemical polishing of copper

Kun Shan,Ping Zhou,Jiqing Cai,Renke Kang,Kang Shi,Dongming Guo

Stress free polishing method is preferred for a damage free surface of copper with ultra-flatness and ultra-smoothness. Such a surface offers a perfect substrate for integrated circuits and micro-electromechanical systems fabrication. A new polishing method, called electrogenerated chemical polishing (EGCP), is proposed based on the principle of the scanning electrochemical microscope (SECM) and the diffusion controlled chemical reaction. Roughness of a Cu surface is reduced from 100.5   nm to 3.6   nm by the proposed method. To demonstrate the planarization capability of this new method, a patterned Cu surface with an array of micro-columns is planarized with a peak-valley (PV) value from 4.7   μm to 0.059   μm.

研究领域: 材料科学 · 表面工程 · 微纳加工 · 半导体制造 · 电化学
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RSC Advances · 2014 ·Vol. 4 ·期 40 ·21093-21100 · IF 3.708

The preparation of a novel polymeric sulfonium salt photoacid generator and its application for advanced photoresists

Juan Liu,Yu Qiao,Zhengping Liu,Liyuan Wang

With poly(4-hydroxylstyrene) (PHS) as a raw material, a new type of polymeric photoacid generator (PAG) is synthesized with sulfonium perfluoroalkyl sulfonate groups bonded onto part of the benzene rings. The phenolic hydroxyl groups are esterified to increase the solubilities of the polymeric sulfonium salts in organic solvents. Upon irradiation to 254 nm light, the sulfonium units in the polymer effectively decompose to generate sulfonic acid. The photolysis is confirmed by UV spectroscopy and the generation of sulfonic acids which catalyze the decomposition of the t-BOC protection group of the polymeric PAGs. Making use of the polymeric PAGs, positive-tone chemically amplified 248-nm photoresists can be formed by them and ester acetal polymer with high acidolytic activity. The photolithography performance of the photoresist was evaluated using a KrF laser exposure system with high photosensitivity and resolution. This novel kind of polymeric sulfonium salt PAG is applicable for advanced chemically amplified resist materials.

研究领域: 高分子化学 · 光刻技术 · 材料科学 · 半导体制造 · 有机电子学
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