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Frontiers in Chemistry · 2020 · IF 3.693

Aqueous Room Temperature Mono-Dehydration of Sugar Alcohols Using Functionalized Yttrium Oxide Nanocatalysts

Yang Juncheng,Jia Yihong,Fan Chao,Cheng Yu,Pan Cheng,Huang Benhua,Meng Xu,Zhang Junjie,Zheng Aqun,Ma Xiaomo,Li Xiaoyong,Luque Rafael,Sun Yang

The aqueous room temperature mono-dehydration of sugar alcohols (D-sorbitol and D-mannitol) was conducted using functionalized yttrium oxide nanocatalysts prepared via sol-gel methods. Materials exhibited high selectivity to mono-dehydration products. Solvent and catalyst effects were also investigated and discussed. The introduction of titanium into the yttrium oxide framework would decrease both substrate conversion and mono-dehydration efficiency. In addition, studies of the catalytic mechanism indicate high mono-dehydration efficiency may come from the stability of the formed intermediate during catalysis. This work provides a highly efficient and benign system for catalytic mono-dehydration of sugar alcohols.

研究领域: 化学工程 · 催化科学
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GREEN CHEMISTRY · 2020 ·Vol. 22 ·期 16 ·5333-5344 · IF 9.48

Efficient and selective aqueous photocatalytic mono-dehydration of sugar alcohols using functionalized yttrium oxide nanocatalysts

Juncheng Yang,Xiaoyong Li,Yu Cheng,Chao Fan,Cheng Pan,Benhua Huang,Xu Meng,Junjie Zhang,Aqun Zheng,Xiaomo Ma,Lina Guo,Rafael Luque,Weining Zhang,Yang Sun

The mono-dehydration of sugar alcohols such as D-sorbitol and D-mannitol generates 1,4-sorbitan and 1,4-mannitan, respectively, which are relevant platform molecules for the synthesis of detergents and pharmaceuticals. Most reported catalytic systems provided access to di-dehydrated products, while mono-dehydration required special efforts, particularly regarding selectivity and reaction temperature. A series of functionalized yttrium oxides were prepared via sol–gel synthesis in this work, which not only showed an interesting micropipe-like morphology, but also contained functional components. These materials were investigated as photocatalysts in the dehydration of D-sorbitol and D-mannitol, exhibiting high selectivity to mono-dehydration. The effects of solvent, temperature and catalyst were fully discussed. A catalytic mechanism was proposed based on the experimental results and calculations.

研究领域: 化学工程 · 催化科学
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