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JOURNAL OF NANOPARTICLE RESEARCH · 2022 ·Vol. 24 ·期 3 ·69 · IF 2.533

Macro-prepared Cs4PbBr6/CsPbBr3 perovskite screen printing inks

Song Rong,Li Ying,Qian Jun

Perovskite has shown attractive optoelectronic performances and is a potential material in lighting, anti-counterfeiting, sensor, and other optoelectronic devices. Recently, spin-coating has been widely used in fabricating high-performance perovskite films, but it is difficult to process and apply in practice. In this paper, the CsPbBr 3 /Cs 4 PbBr 6 composite perovskite quantum dots with photoluminescence quantum yield of 36% and high storage stability were prepared by using room temperature ligand-assisted precipitation method and controlling the proportion of CsBr/PbBr 2 . In addition, the composite perovskite was ground and dispersed in the inks system. After adjusting the composition and ratio of the resin components, the inks were suitable for screen printing with a viscosity of 2439 mPa•s, an initial dryness of 25 mm/30 s, and a thorough dryness of 100 s/100 μm. By printing, the perovskite films exhibited high coverage, strong green emission, and outstanding fluorescence recovery ability after exposure to water. Screen printing perovskite inks have the characteristic of being patternable, which provides a solution for preparing a perovskite film in the application.

研究领域: 材料科学 · 纳米科技 · 光电子学 · 印刷电子 · 荧光材料
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Science China-Materials · 2019 ·Vol. 63 ·期 3 ·392-402 · IF 5.636

One-pot ball-milling preparation of graphene/carbon black aqueous inks for highly conductive and flexible printed electronics

Yang Xiao,Li Xiao-Ming,Kong Qing-Qiang,Liu Zhuo,Chen Jing-Peng,Jia Hui,Liu Yan-Zhen,Xie Li-Jing,Chen Cheng-Meng

Stable aqueous carbon inks, with graphene sheets (GSs) and carbon black (CB) as conductive fillers, are prepared by a simple one-pot ball-milling method. The as-prepared composite ink with 10 wt% GSs shows optimized rheological properties (viscosity and thixotropy) for screen printing. The as-printed coatings based on the above ink are uniform and dense on a polyimide substrate, and exhibit a sandwich-type conductive three dimensional network at the microscale. The resistivity of the typical composite coating is as low as 0.23±0.01 Ω cm (92±4 Ω sq −1 , 25 µm), which is 30% as that of a pure CB coating (0.77±0.01 Ω cm). It is noteworthy that the resistivity decreases to 0.18±0.01 Ω cm (72±4 Ω sq −1 , 25 µm) after a further rolling compression. The coating exhibits good mechanical flexibility, and the resistance slightly increases by 12% after 3000 bending cycles. With the CB/GSs composite coatings as a flexible conductor, fascinating luminescent bookmarks and membrane switches were fabricated, demonstrating the tremendous potential of these coatings in the commercial production of flexible electronics and devices.

研究领域: 材料科学 · 纳米技术 · 电子工程 · 印刷电子 · 复合材料
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